Tidal-cycle changes in oscillation ripples on the inner part of an estuarine sand flat

Oscillation ripples form on subaqueous sand beds when wave-generated, near-bottom water motions are strong enough to move sand grains. The threshold of grain motion is the lower bound of the regime of oscillation ripples and the onset of sheet flow is the upper bound. Based on the relation between ripple spacing and orbital diameter, three types of symmetrical ripples occur within the ripple regime. In the lower part of the ripple regime (orbital ripples), spacing is proportional to orbital diameter; in the upper part (anorbital ripples) spacing is independent of orbital diameter. Between these regions occurs a transitional region (suborbital ripples).

Oscillation ripples develop on a sandy tidal flat in Willapa Bay, Washington, as a result of waves traversing the area when it is submerged. Because wave energy is usually low within the bay, the ripples are primarily orbital in type. This means that their spacing should respond in a systematic way to changes in wave conditions. During the high-water parts of some tidal cycles, ripples near the beach decrease in spacing during the latter stage of the ebb tide while ripples farther offshore do not change. Observations made over several tidal cycles show that the zone of active ripples shifts on- or offshore in response to different wave conditions.

Detailed bed profiles and current measurements taken during the high-water part of spring tides show the manner in which the oscillation ripples change with changes in orbital diameter. Changes in ripple spacing at the study site could be correlated with changes in orbital diameter in the manner suggested by the criterion for orbital ripples. However, there appeared to be a lag time between a decrease in orbital diameter and the corresponding decrease in ripple spacing. Absence of change during a tidal cycle could be attributed to orbital velocities below the threshold for grain motion that negated the effects of changes in orbital diameter.

Because changes in sand-flat ripples depend both upon changes in orbital diameter and upon the magnitude of the orbital velocity, exposed ripples were not necessarily produced during the preceding high tide. In fact, some ripples may have been just produced, while others, farther offshore, may have been produced an unknown number of tides earlier. Therefore, when interpreting past wave conditions over tidal flats from low-tide ripples, one must remember that wave periods have to be short enough to produce velocities greater than the threshold velocity for the orbital diameters calculated from the observed ripple spacings.     

“Of outstanding universal value”: The challenge of scale in applying the World Heritage Convention at national parks in the US

This paper explores the operation of the international World Heritage Convention in the national context of the United States. Although an early advocate of the national park idea and among the earliest proponents of the Convention, the US has shown increasing ambivalence towards the World Heritage Program since the mid-1990s. Through in-depth interviews with expert informants and a questionnaire survey of 406 visitors at four US World Heritage Sites, this study considers whether combining national and international conservation designations provides valuable reinforcement of conservation goals, or leads to unnecessary overlap and even challenges to sovereignty. The majority of my expert informants were supportive of the Convention, related to philosophical and practical benefits that they believed to be associated with the World Heritage label, although most identified few tangible influences of the World Heritage Program itself. Several noted hostility to the Program from a nationalist fringe, which fears international involvement in land use decisions. Such concerns were reflected in questionnaire responses, which revealed some distrust of the Convention and misunderstandings of its operation. I conclude that the scalar mismatch of implementing an international convention at the national scale inevitably involves challenges, but that country-specific factors are important in explaining why the Convention has been particularly controversial in the US. Education is integral to addressing these challenges, as well as reengagement with the Program by both the National Park Service and the federal administration. Intangible values associated with World Heritage mean that the Convention still enjoys considerable support in the US, providing a solid foundation for such a reengagement.     

Hopane,sterane and n-alkane distributions in shallow sediments hosting high arsenic groundwaters in Cambodia

The presence of elevated As in ground waters exploited for drinking water and irrigation in South-East Asia is causing serious impacts on human health. A key mechanism that causes the mobilization of As in these waters is microbially mediated reductive transformation of As-bearing Fe(III) hydrated oxides and the role of degradable organic matter (OM) in this process is widely recognized. A number of different types of OM that drive As release in these aquifers have been suggested, including petroleum derived hydrocarbons naturally seeping into shallow sediments from deeper thermally mature source rocks. However, the amount of information on the characteristics of the OM in South-East Asian aquifers is limited. Here the organic geochemical analyses of the saturated hydrocarbon fractions and radiocarbon analysis, of two additional sites in SE Asia are reported. The results show that the OM in a given sedimentary horizon likely derives from multiple sources including naturally occurring petroleum. The importance of naturally occurring petroleum as one of the sources was clearly indicated by the n-alkane CPI of approximately 1, the presence of an unresolved complex mixture, and hopane (dominated by 17α(H),21β(H) hopanes) and sterane distribution patterns. The results also indicate that the OM in these aquifers varies tremendously in content, character and potential bioavailability. Furthermore, the presence of petroleum derived OM in sediments at both sites doubles the number of locations where their presence has been observed in association with As-rich, shallow aquifers, suggesting that the role of petroleum derived OM in microbially mediated As release might occur over a wider range of geographical locations than previously thought.     

How effective are plant macrofossils as a proxy for macrophyte presence? The case of <Emphasis Type="Italic">Najas flexilis</Emphasis> in Scotland

Preventing biodiversity loss is a key aim of modern conservation, and paleolimnology can inform conservation strategies for target species and habitats where other data are unavailable. Care must be taken to fully understand the possibilities and limits of such techniques, particularly where they concern single species. This study uses plant and seed distribution data to inform macrofossil reconstructions of the rare macrophyte Najas flexilis (Slender Naiad) in Scotland, UK. It answers three questions: (a) How does the location of N. flexilis seeds in the surface sediments relate to the distribution of N. flexilis plants? (b) How do the numbers of seeds in surface sediments correlate with % cover of N. flexilis plants across lakes with differing N. flexilis abundances? (c) What are the implications of these findings for paleolimnology? Percentage N. flexilis cover and number of N. flexilis seeds in surface sediments were recorded at ~100 sample points at each of three sites; one where the species was abundant, one where it was occasional and one where it was extinct. At all sites, N. flexilis seeds were present in surface sediments across the entire lake. No correlation between % cover N. flexilis and the number of seeds in surface sediments was found within individual sites. The distribution of seeds in these lakes appeared to be related to multiple environmental and ecological variables including latitude and longitude (proxies for water currents). This is attributed to the ability of seed-bearing N. flexilis plants to fragment and float large distances on water. Between sites, there was a significant difference in the mean seed counts, with higher mean seed counts corresponding to higher abundances of N. flexilis plants. It is concluded that N. flexilis is likely to be well represented in sediment cores taken from any location within a basin, but that care should be taken when inferring changes in N. flexilis abundance from changes in the numbers of seeds in sediment samples. This work demonstrates that the reproductive ecology (number of seeds produced and dispersal mechanisms) is an important factor to consider when attempting reconstructions of single aquatic plant populations from macrofossil records.     

Health and environmental co-benefits and conflicts of actions to meet UK carbon targets

Many actions to reduce GHG emissions have wider impacts on health, the economy, and the environment, beyond their role in mitigating climate change. These ancillary impacts can be positive (co-benefits) or negative (conflicts). This article presents the first quantitative review of the wider impacts on health and the environment likely to arise from action to meet the UK's legally-binding carbon budgets. Impacts were assessed for climate measures directed at power generation, energy use in buildings, and industry, transport, and agriculture. The study considered a wide range of health and environmental impacts including air pollution, noise, the upstream impacts of fuel extraction, and the lifestyle benefits of active travel. It was not possible to quantify all impacts, but for those that were monetized the co-benefits of climate action (i.e. excluding climate benefits) significantly outweigh the negative impacts, with a net present value of more than £85 billion from 2008 to 2030. Substantial benefits arise from reduced congestion, pollution, noise, and road accidents as a result of avoided journeys. There is also a large health benefit as a result of increased exercise from walking and cycling instead of driving. Awareness of these benefits could strengthen the case for more ambitious climate mitigation action.

Policy relevance

This article demonstrates that actions to mitigate GHG emissions have significant wider benefits for health and the environment. Including these impacts in cost–benefit analysis would strengthen the case for the UK (and similar countries) to set ambitious emissions reduction targets. Understanding co-benefits and trade-offs will also improve coordination across policy areas and cut costs. In addition, co-benefits such as air quality improvements are often immediate and local, whereas climate benefits may occur on a longer timescale and mainly in a distant region, as well as being harder to demonstrate. Dissemination of the benefits, along with better anticipation of trade-offs, could therefore boost public support for climate action.     

Deriving vulnerability curves using Italian earthquake damage data

The concerted effort to collect earthquake damage data in Italy over the past 30 years has led to the development of an extensive database from which vulnerability predictions for the Italian building stock can be derived. A methodology to derive empirical vulnerability curves with the aforementioned data is presented herein and the resulting curves have been directly compared with mechanics-based vulnerability curves. However, it has been found that a valid comparison between the empirical and analytical vulnerability curves is not possible mainly due to a number of shortcomings in the database of surveyed buildings. A detailed discussion of the difficulties in deriving vulnerability curves from the current observed damage database is thus also presented.     

Talkoot: software tool to create collaboratories for earth science

“Open science,” where researchers share and publish every element of their research process in addition to the final results, can foster novel ways of collaboration among researchers and has the potential to spontaneously create new virtual research collaborations. Based on scientific interest, these new virtual research collaborations can cut across traditional boundaries such as institutions and organizations. Advances in technology allow for software tools that can be used by different research groups and institutions to build and support virtual collaborations and infuse open science. This paper describes Talkoot, a software toolkit designed and developed by the authors to provide Earth Science researchers a ready-to-use knowledge management environment and an online platform for collaboration. Talkoot allows Earth Science researchers a means to systematically gather, tag and share their data, analysis workflows and research notes. These Talkoot features are designed to foster rapid knowledge sharing within a virtual community. Talkoot can be utilized by small to medium sized groups and research centers, as well as large enterprises such a national laboratories and federal agencies.     

It starts at home? Climate policies targeting household consumption and behavioral decisions are key to low-carbon futures

Through their consumption behavior, households are responsible for 72% of global greenhouse gas emissions. Thus, they are key actors in reaching the 1.5 °C goal under the Paris Agreement. However, the possible contribution and position of households in climate policies is neither well understood, nor do households receive sufficiently high priority in current climate policy strategies. This paper investigates how behavioral change can achieve a substantial reduction in greenhouse gas emissions in European high-income countries. It uses theoretical thinking and some core results from the HOPE research project, which investigated household preferences for reducing emissions in four European cities in France, Germany, Norway and Sweden. The paper makes five major points: First, car and plane mobility, meat and dairy consumption, as well as heating are the most dominant components of household footprints. Second, household living situations (demographics, size of home) greatly influence the household potential to reduce their footprint, even more than country or city location. Third, household decisions can be sequential and temporally dynamic, shifting through different phases such as childhood, adulthood, and illness. Fourth, short term voluntary efforts will not be sufficient by themselves to reach the drastic reductions needed to achieve the 1.5 °C goal; instead, households need a regulatory framework supporting their behavioral changes. Fifth, there is a mismatch between the roles and responsibilities conveyed by current climate policies and household perceptions of responsibility. We then conclude with further recommendations for research and policy.     

Equation of state and pressure-induced structural changes in mirabilite (Na2SO4·10H2O) determined from ab initio density functional theory calculations

We have carried out ab initio calculations using density functional theory to determine the bulk elastic properties of mirabilite, Na₂SO₄·10H₂O, and to obtain information on structural trends caused by the application of high pressure up to ~60 GPa. We have found that there are substantial isosymmetric discontinuous structural re-organisations at ~7.7 and ~20 GPa caused by changes in the manner in which the sodium cations are coordinated by water molecules. The low-pressure and intermediate-pressure phases both have sodium in sixfold coordination but in the high-pressure phase the coordination changes from sixfold to sevenfold. These coordination changes force a re-arrangement of the hydrogen-bond network in the crystal. The trend is towards a reduction in the number of hydrogen bonds donated to the sulphate group (from twelve down to six over the range 0–60 GPa) and an increase in hydrogen bonding amongst the Na-coordinated water molecules and the two interstitial water molecules. Ultimately, we observe proton transfers from the interstitial waters (forming OH^? ions) to two of the Na-coordinated waters (forming a pair of H₃O⁺ ions). The equation of state in the athermal limit of the low-pressure phase of mirabilite, parameterised by fitting an integrated form of the third-order Birch-Murnaghan expression to the calculated energy as a function of unit-cell volume, yields the zero-pressure unit-cell volume, V ₀ = 1468.6(9) ų, the incompressibility, K ₀ = 22.21(9) GPa, and the first pressure derivative K ₀′ = (?K/?P)₀ = 5.6(1).