Subsurface Transport of Inorganic and Organic Solutes from Experimental Road Spreading of Oil-Field Brine

A study designed to evaluate ground water quality changes resulting from spreading oil-field brine on roads for ice and dust control was conducted using a gravel roadbed that received weekly applications of brine eight times during the winter phase and 11 times during the summer phase of the study. A network of 11 monitoring wells and five pressure-vacuum lysimeters was installed to obtain ground water and soil water samples. Thirteen sets of water- quality samples were collected and analyzed for major ions, trace metals, and volatile organic compounds. Two sets of samples were taken prior to brine spreading, four sets during winter-phase spreading, five sets during summer- phase spreading, and two sets during the interim between the winter and summer phases. A brine plume delineated by elevated specific-conductance values and elevated chloride concentrations developed downgradient of the roadbed during both the winter and summer phases. The brine plume caused chloride concentrations in ground water samples to exceed U.S. EPA public drinking-water standards by two-fold during the winter phase and five-fold during the summer phase. No other major ions, trace metals, or volatile organic compounds exceeded the standards during the winter or summer phases. More than 99 percent dilution of the solutes in the brine occurred between the roadbed surface and the local ground water flow system. Further attenuation of calcium, sodium, potassium, and strontium resulted from adsorption, whereas further attenuation of benzene resulted from volatilization and adsorption.     

Effect of pH on Adsorption Equilibria for Dissolved Weak Organic Electrolytes on Activated Carbon

The influence of pH on the adsorption equilibria of a-picolin and phenol from aqueous solution on activated carbon is studied experimentally for the single solutes and their mixtures. For these weak bases and weak acids the effect of pH on adsorption capacity is contrary, thus allowing an efficient separation by adsorption. A model based on the concept of competitive adsorption of ionic and molecular forms of the organic electrolytes represents the experimental data qualitatively. Deviations between theoretical and experimental results are discussed on the basis of possible interactions of the organic solutes and the activated carbon with components of the buffer used in the experiments.     

A fundamental solution due to a periodic point force in the interior of an elastic half-space

The fundamental solution for a periodic point force in the interior of a three-dimensional, homogeneous, isotropic, elastic half-space is derived. The method of synthesis and superposition is employed to obtain the solution in the Laplace transform as well as the frequency domain. These correspond to the dynamic equivalent of Mindlin's static half-space point force solutions. It is reduced, for certain limiting conditions, to the dynamic equivalent of Boussinesq's and Cerruti's problems of a normal and tangential periodic point force respectively, on the boundary of a half-space. Also, static solutions of Mindlin, Boussinesq and Cerruti are recovered for small frequency parameters. Finally, results are presented and compared with other available solutions.     

MEASURED UNDERWATER NEAR-FIELD E-PATTERNS OF A PULSED,HORIZONTAL DIPOLE ANTENNA IN AIR: COMPARISON WITH THE THEORY OF THE CONTINUOUS WAVE,INFINITESIMAL ELECTRIC DIPOLE1

At Delft Geotechnics the technique of ground-penetrating radar is in use for the detection of buried objects such as pipes. To enable us to give our ‘measurements in the field’ a more quantitative interpretation than can be deduced from these alone, a series of experiments has been started under well-defined conditions. A cylindrical vessel containing water simulates wet soil. Mounted horizontally above the water surface is a pulsed triangular half-wave dipole which is used as a transmitting antenna (TA). It has a carrier-frequency of about 160 MHz and a pulse repetition-frequency of about 50 kHz. A movable receiving dipole (‘probe’) in the water measures the transverse, mutually orthogonal E_φ,- and E_θ-components of the pulses as a function of probe-position (r, θ, φ) and of the height h of the TA above the water surface. When these pulses are Fourier-transformed, the transverse electric fields E_φ and E_θ at 200 MHz are obtained. The resulting field patterns are compared with computational results on the basis of the theory of the continuous wave, infinitesimal electric dipole (‘point dipole’). It can be concluded that:

• 1 Far-field conditions have not fully developed at a depth of about 2.50 m, the largest value of the radius r at which field patterns were measured, although it represents a distance of about 15 wavelengths.
• 2 The attenuation constant of the tapwater used, as deduced from E-field measurements for θ= 0, 2.50 m < r < 2.75 m, is slightly less than the value measured using a network analyser and air line combination, in agreement with (1).
• 3 E _φ field patterns calculated using the value of the conductivity σ corresponding to the former value of the attenuation constant agree reasonably well with the measured patterns for r≤ 2.50 m and for θ < 20° at all antenna heights considered. Calculated Eφ patterns do not agree so well with the measured patterns when h is close to zero. With increasing height the agreement inproves.
• 4 In accordance with the theory of the point-dipole, the angular distribution of the radiation patterns of the TA becomes wider as the frequency decreases.
• 5 The normalized underwater pulse-spectra shift to lower frequencies with increasing r. This can be explained since the attenuation constant of the water rises with rising frequency.

     

The geomorphic dynamics and environmental history of an upper deltaic floodplain tract in the Sacramento–San Joaquin Delta,California, USA

A multi‐proxy approach was used to examine the geomorphic dynamics and environmental history of an upper deltaic ?oodplain tract in the Sacramento–San Joaquin Delta, California. Three long cores were collected from the McCormack–Williamson Tract (MWT) and these cores were analyzed for bulk density, loss‐on‐ignition, ?ne (clay and silt) content, Al concentration, magnetic susceptibility, pollen, and charcoal. Radiocarbon dates obtained for the cores were converted into calendar years and an age–depth model was constructed. Long‐term vertical accretion and sedimentation rates were estimated from the age–depth model. Cross‐core relations show that coarse sediment generally accumulates more rapidly and has greater magnetic susceptibility compared to ?ne sediment. Percentage ?ne and LOI data show a strong linear relationship that indicates ?ooding is the primary mechanism for the deposition of particular organic matter on the ?oodplain and that landscape wash load has contributed a highly consistent fraction of persistent organic matter averaging 5·5 per cent to the site. Down‐core grain size pro?les show two hydrological domains in the cores, namely millennial ?ne–coarse ?uctuations superimposed on general up‐core ?ning. Coarse sediment is viewed as channel or near‐channel overbank deposits, whereas ?ne deposits are considered to be distal overbank ?ood deposits. The coarse–?ne ?uctuations are indicative of changing depositional settings as channels migrated laterally across MWT, whereas the upward ?ning trend re?ects a combination of self‐limiting overbank deposition as ?oodplain elevation increased and decreasing competence as sea‐level rise reduced ?ood‐pulse energy slopes. MWT has been cross‐cut and incised numerous times in the past, only to have the channels abandoned and subsequently ?lled by ?ne sediment. The channels around MWT attained their modern con?guration about 4000 years ago. MWT likely came under tidal in?uence at about 2500 cal BP. Wetlands have recently developed on MWT, but they are inorganic sediment dominated. Copyright © 2004 John Wiley & Sons, Ltd.     

Possible Evidence of Long-Term Oscillations in the Solar Atmosphere

We have obtained the temporal correlation function, Q(t), from time sequences of Caii K filtergrams and Dopplergrams from Antarctica, Taiwan Oscillation Network (TON) and Solar and Heliospheric Observatory (SOHO). Q(t) gives the time evolution of the pattern under examination, supergranulation in this case. It has been found that Q(t) shows oscillatory signals of both 5-min and long-term periods. The 5-min oscillations are suppressed by averaging the images over 10 min. An exponential decay curve which represents the lifetime trend of supergranules, is fitted to Q(t) and subtracted out. The Q(t) residuals thus obtained contain the oscillatory component and are then subjected to a periodogram analysis. Significant periodicities in the range of 1.4–10 hours have been noted. The causes of these oscillations are not fully known at present, but the instrumental and atmospheric factors can be ruled out, pointing to solar origin. Various possibilities are discussed. Some of the observed periodicities may be considered as probable candidates for long-term oscillations in the Sun, such as the elusive gravity modes.     

Persistent 22-year cycle in sunspot activity: Evidence for a relic solar magnetic field

We use the recently presented group sunspot number series to show that a persistent 22-year cyclicity exists in sunspot activity throughout the entire period of about 400 years of direct sunspot observations. The amplitude of this cyclicity is about 10% of the present sunspot activity level. A 22-year cyclicity in sunspot activity is naturally produced by the 22-year magnetic polarity cycle in the presence of a relic dipole magnetic field. Accordingly, a persistent 22-year cyclicity in sunspot activity gives an evidence for the existence of such a relic magnetic field in the Sun. The stable phase and the roughly constant amplitude of this cyclicity during times of very different sunspot activity level strongly support this interpretation.     

Investigation of Barred Galaxies. VII. Comparative Statistics of SB and SA Galaxies. Near and Mid-IR Regions

The near and mid-IR properties of barred and unbarred spiral galaxies are discussed on the basis of complete samples that were compiled earlier. The two types of spirals are shown not to differ from one another in emission power in the near and mid-IR ranges. Multiple regression and principal component analysis have been applied to investigate near and mid-IR properties of SB and SA galaxies, particularly their relation to X-ray and radio continuum emissions. There are definite differences between SB and SA spirals in the near and mid-IR. In the case of SB galaxies, the compactness of 10 m emission is closely related to the J - H color index, and the redder J - H color corresponds to relatively more extended emission at 10 m. It is assumed that these are caused by the bar itself, which stimulates enhanced star formation in a barred galaxy with respect to unbarred spiral.     

A Negative Branch of Polarization for Comets and Atmosphereless Celestial Bodies and the Light Scattering by Aggregate Particles

Optical observations of comets and atmosphereless celestial bodies show that a change of sign of the linear polarization of scattered light from negative to positive at phase angles less than 20° is typical of the cometary coma, as well as of the regolith of Mercury, the Moon, planetary satellites, and asteroids. To explain a negative branch of polarization, this research suggests a unified approach to the treatment of cometary-dust particles and regolith grains as aggregate forms. A composite structure of aggregate particles resulting in the interaction of composing structural elements (monomers) in the light-scattering process is responsible for the negative polarization at small phase angles, if the monomer sizes are comparable to the wavelength. The characteristics of single scattering of light calculated for aggregates of this kind turned out to be close to the properties observed for cometary dust. Unlike the cometary coma, the regolith is an optically semi-infinite medium, where the interaction between particles is significant. To find the reflectance characteristics of regolith, the radiative-transfer equation should be solved for a regolith layer. In this case, the interaction between scatterers can be modeled to a certain extent by representing the regolith grains as aggregate structures consisting of several or many elements. Although real regolith grains are much larger than the particles considered here, laboratory measurements have shown that it is precisely the surface irregularities comparable to the wavelength that cause a negative branch of polarization. The main observed features of the phase and spectral dependence of the linear polarization of light scattered from comets and atmosphereless celestial bodies, which are due to the difference of the elementary scatterers in composition, size, and structure, can be successfully explained using the aggregate model of particles.