On the Spatial Distribution and Seasonal Variation of Lower-Troposphere Ozone over Europe

Surface ozone data from 25 Europeanlow-altitude sites and mountain sites located between79°N and 28°N were studied. The analysiscovered the time period March 1989–February 1993.Average summer and winter O₃ concentrations inthe boundary layer over the continent gave rise togradients that were strongest in the north-west tosouth-east direction and west-east direction, respectively. WintertimeO₃ ranged from 19 to 27 ppbover the continent, compared to about 32 ppb at thewestern border, while for summer the continentalO₃ values ranged between 39 and 56 ppb and theoceanic mixing ratios were around 37 ppb. In the lowerfree troposphere average wintertime O₃ mixingratios were around 38 ppb, with only an 8 ppbdifference between 28°N and 79°N. For summerthe average O₃ levels decreased from about 55 ppbover Central Europe to 32 ppb at 79°N. Inaddition, O₃ and O_x(= O₃ + NO₂)in polluted and clean air were compared. Theamplitudes of the seasonal ozone variations increasedin the north-west to south-east direction, while thetime of the annual maximum was shifted from spring (atthe northerly sites) to late summer (at sites inAustria and Hungary), which reflected the contributionof photochemical ozone production in the lower partsof the troposphere.     

Reactive Nitrogen Compounds at Spitsbergen in the Norwegian Arctic

Simultaneousindependent measurements of NO_y and NO_x(NO_x= NO + NO₂) by high-sensitivitychemiluminescence systems and of PAN (peroxyacetylnitrate) and PPN (peroxypropionyl nitrate) by GC-ECDwere made at Spitsbergen in the Norwegian Arcticduring the first half year of 1994. The average mixingratio of the sum of PAN and PPN (denoted PANs)increased from around 150 pptv in early winter to amaximum of around 500 pptv in late March, whereasepisodic peak values reached 800 pptv. This occurredsimultaneously with a maximum in ozone which increasedto 45–50 ppbv in March–April. The average NO_xmixing ratio was 27 pptv and did not show any cyclethrough the period. The NO_y mixing ratio showeda maximum in late March, while the difference betweenNO_y and PAN decreased during spring. This is anindication of the dominance of PAN in the NO_ybudget in the Arctic, but possible changes in theefficiency of the NO_y converter could alsocontribute to this. Although most PAN in theArctic is believed to be due to long range transport,the observations indicate local loss and formationrates of up to 1–2 pptv h^-1 in April–May.Measurements of carbonyl compounds suggest thatacetaldehyde was the dominant, local precursor ofPAN.Now at 1.     

RECOGNISING THE UNCERTAINTY IN THE QUANTIFICATION OF THE EFFECTS OF CLIMATE CHANGE ON HYDROLOGICAL RESPONSE

A widely used method of evaluating effects of climate change on flow regime is to perturb the climate inputs to a rainfall–runoff model and examine the effect on a statistic of the modelled flows. Such studies require four elements: a method of perturbing the climate, a rainfall–runoff model, a study catchment and a flow index. In practice the direction and magnitude of the estimated effects depend on each of the four elements, leading to concern over the usefulness and generality of the results. To investigate these uncertainties two climate scenarios and eight climate sensitivity tests have been applied to three UK catchments using two conceptual rainfall–runoff models in order to quantify effects of climate change on three flow indices representing mean runoff, flood magnitudes and low flows. The sensitivity tests were found to be useful to assess the suitability of the models to simulate flows outside the conditions experienced in their calibration. Both models gave internally consistent results but, on close examination, one model was found inappropriate for this application. Results show that the effect of climate change on flow varies between catchments and that different flow response indices can change in opposite directions, e.g. floods increased in magnitude while low flows reduced. Contrasting results were obtained from the two climate scenarios.     

Water Resources Planning and Climate Change Assessment Methods

This paper, which provides background for other papers in the volume, first reviews the nature and development of water resources planning and evaluation criteria at the Federal level in the United States. These criteria constitute a highly developed, complex set of guidelines for project planning and evaluation. The level of development of these criteria and their long historical development from theoretical foundations must be taken into account in relating global climate change to possible changes in planning criteria. Second, the essentials of water project planning and evaluation, including benefit-cost principles and more complex concepts of social decision-making, are outlined. Third, the paper provides an overview of global climate change assessment methods, including impact assessment and integrated assessment. Impact assessment uses a relatively straightforward comparison of with and without situations; integrated assessment attempts to improve on impact assessment by developing more complex models that incorporate a range of feedbacks and interrelationships.     

Flotation of oxidized minerals of copper using a new synthetic chelating reagent as collector

A new synthetic reagent containing a mixed aliphatic-aromatic structure, with a hydrocarbon chain and an aminothiophenol chelating group, has proven to be an effective collector for the flotation of chrysocolla minerals. The flotation is optimum in the narrow pH range of 5.5 to 6, falls sharply at pH 5, and is moderate in the pH range 7 to 11. Infrared spectra indicate that copper aminothiophenolate chelates are formed on the surface of the chrysocolla under the conditions of maximum flotation.     

Carboniferous diamictite dykes in the Falkland Islands

Sedimentary dykes hosted in ? Ordovician-Devonian strata on the Falkland Islands contain diamictite. The dykes, which are discordant to the host rocks, are sub-vertical, parallel-sided sheets formed by downward injection of a semi-fluidized sediment. On West Falkland palynomorphs present in 2 of the 11 dykes located demonstrate a Late Visean-Early Namurian age. This is older than the main Lafonian Diamictite Formation (Permian) and indicates that the dykes are a rare preservation of sediments formed during the main ice coverage of the Gondwana glaciation. Vitrinite reflectance from organic matter in the dykes indicates a shallow burial history (< 2–3 km) for the southwest Falkland Islands implying deposition of an incomplete or condensed sequence during Late Palaeozoic times, although the stratigraphical relationship of the dykes indicates that this may be extended back into the Mid Palaeozoic. The two diamictite dykes located on East Falkland are shown to be younger; probably Permian in age.     

Relationship of larval-stage growth and mortality to recruitment of striped bass,Morone saxatilis, in Chesapeake Bay

Variable recruitments of striped bass were hypothesized to be caused by factors influencing growth and survival of larvae. Eggs and larvae were collected in the Potomac River from 1987 to 1989 and in the Upper Chesapeake Bay in 1988 and 1989 to estimate abundances, larval growth and survival rates, and environmental variability. Larval batch dates, ages, and growth and mortality rates were estimated from analysis of otolith daily increments. A retrospective analysis of Potomae River ichthyoplankton data from 1974–1977 and 1980–1982 provided additional estimates of larval abundances and vital rates for comparative purposes. Significant correlations betweens vital rates (growth and mortality) and abundances of striped bass larvae, and the Maryland juvenile recruitment index indicated that recruitment level may be fixed during the larval stage. The ratio of mean daily growth and mortality rates (G:Z) of larvae in the Potomac River for 1987–1989 was highest in 1987 when the juvenile index was relatively high, and was lower in 1988 and 1989 when juvenile indices were low. In the Upper Bay, mean larval growth rate, survival rate, and the G:Z ratio were highest in 1989 when the juvenile index also was high. In both tributaries, abundances of late-stage larvae (8 mm SL) were correlated with juvenile-stage recruitment indices. The retrospective analysis provided additional evidence that Potomac River larval abundances and G:Z ratios were positively correlated with juvenile recruitment indices in the 1974–1977 and 1980–1982 periods. Conditions favoring striped bass larval abundance and potential recruitment differed between the Potomac River and the Upper Bay. In the Potomac, late-stage larval abundances coincided with late-season water temperatures that were relatively warm, low river discharges and high, late-season densities of zooplankton prey, which favored larval growth. In the Upper Bay, the high abundance of late-stage larvae in 1989 relative to 1988 was attributed to a higher egg production that was coincident with high zooplankton abundances.     

Sediment origin and budget in Sepetiba Bay (Brazil) - an approach based on multielemental analysis

 Sediment origin and transport were determined in a shallow 447 km² coastal lagoon in Brazil, using the distribution of major elements in bottom and suspended sediments. Applying multivariate analysis, the sum of normalized concentrations of Ti, Fe, and Al in sediments was selected to trace the terrigenous influence in bottom sediments, whereas Ca, Si, and K were used as indicators of marine influence. Sepetiba Bay bottom sediments are dominated by up to 80% terrigenous inputs. The open bay sediments are enriched in P, Mg, K, and Ca because of the intensive water column primary production. The inner bay forms an independent circulation cell with a predominance of terrigenous sediments. The results suggest a long residence time for particles in the bay, demonstrated by the magnitude of resuspension flux compared to the total sediment input to the bay. Received: 29 May 1996 · Accepted: 17 December 1996     

Disequilibrium for Ca during growth of pelitic garnet

Compositional zoning in hundreds of almandine-rich garnets in amphibolite by facies micaceous quartzites from the Picuris Range, north-central New Mexico USA, indicates that although Mn, Mg and Fe achieve chemical equilibrium at hand-sample scale during garnet growth, Ca does not. Instead, Ca concentrations at the surface of growing garnets appear to depend strongly on kinetic factors that govern the local chemical environment, yielding disequilibrium for Ca at scales larger than the region immediately surrounding an individual porphyroblast. Detailed zoning profiles were obtained for 371 garnet crystals in a small volume of a single sample of garnetiferous quartzite, and core analyses were made of 97 additional crystals. Each analysis was made on a section that passed precisely through the morphological centre of the crystal, located by means of 3-D imagery from computed X-ray tomography. The data reveal strong correlations between crystal size and concentrations of Mn, Mg and Fe (but not Ca) in garnet cores; a relationship between crystal size and isolation; rigorous cross-correlations among concentrations of Mn, Mg and Fe (but not Ca); and systematic variations in Ca concentrations as a function of crystal size and core composition that are anomalous in comparison to the behaviour of the other divalent cations. We interpret these observations as the result of thermally accelerated diffusion-controlled garnet growth, in circumstances that promoted rapid intergranular diffusion and thus rock-wide equilibration of Mn, Mg and Fe, but that prevented equilibration at similar scale for Ca because of its more sluggish intergranular diffusion. The anomalous behaviour of Ca is made evident in these garnets by the presence of sharp spikes in Ca concentration, which are demonstrably not a consequence of any simultaneous rock-wide event, such as a change in pressure, temperature, or some other intensive parameter. Instead, Ca concentrations probably reflect the local extent of reaction in the immediate vicinity of each porphyroblast. To the degree that such kinetic factors introduce departures from chemical equilibrium for Ca, thermobarometric estimates that involve grossular contents of pelitic garnet will be in error.     

Two stages of zircon and monazite growth in anatectic leucogneiss: SHRIMP constraints on the duration and intensity of Pan-African metamorphism in Prydz Bay, East Antarctica

SHRIMP U–Pb data from two samples of foliated anatectic leucogneiss bracket the high-grade metamorphic history of metasediments from southern Prydz Bay, East Antarctica. Magmatic zircons in these two samples have mean crystallization ages of 535 ± 13 and 536 ± 35 Myr, and provide a good estimate for the timing of peak metamorphism and partial melting. Low-Th monazite grains in the same samples have mean ages of 528 ± 4 and 527 ± 11 Myr, which are within error of the zircon ages but may reflect a lower blocking temperature. High-Th monazite rims with younger mean ages of 518 ± 3 and 512 ± 13 Myr occur around low-Th cores in both samples, and were precipitated from hydrous fluids released during the crystallization of residual melts. These magmatic fluids were channelled along the retrograde foliation present in both samples. All mineral assemblages and fabrics preserved in the metasediments reflect intense Pan-African metamorphism and deformation, associated with high degrees of partial melting and significant vertical displacements of the crust. Continental reconstructions assuming limited Pan-African tectonism in East Antarctica should be reassessed in the light of these new data.