EDI convection measurements at 5–6 RE in the post-midnight region

We present the first triangulation measurements of electric fields with the electron drift instrument (EDI) on Equator-S. We show results from five high-data-rate passes of the satellite through the near-midnight equatorial region, at geocentric distances of approximately 5–6 R_E, during geomagnetically quiet conditions. In a co-rotating frame of reference, the measured electric fields have magnitudes of a few tenths of mV/m, with the E × B drift generally directed sunward but with large variations. Temporal variations of the electric field on time scales of several seconds to minutes are large compared to the average magnitude. Comparisons of the “DC” baseline of the EDI-measured electric fields with the mapped Weimer ionospheric model and the Rowland and Wygant CRRES measurements yield reasonable agreement.     

A combined method to model grain crushing with DEM

This paper presents a combined method to model grain crushing effects with discrete element method.This method combines the two most commonly used concepts to model grain crushing in DEM,i.e.the replacement method and the agglomerate method,so that it is both accurate and efficient.The method can be easily implemented.The performance is shown by several DEM simulations of biaxial tests.Particles with different crush-abilities are modeled.DEM simulation results with and without grain crushing are compared and discussed.The change of grain size distribution due to grain crushing is also investigated.     

Offset dependence of overburden time-shifts from ultrasonic data

Depletion or injection into a reservoir implies stress changes and strains in the reservoir and its surroundings. This may lead to measurable time-shifts for seismic waves propagating in the subsurface. To better understand the offset dependence of time-shifts in the overburden, we have systematically quantified the time-shifts of three different overburden shales in controlled laboratory tests. These experiments may be viewed as an analogue to the time-shifts recorded from seismic field surveys. For a range of different stress paths, defined as the ratio between the horizontal and the vertical stress changes, the changes of the P-wave velocities in different directions were measured such that the offset dependence of time-shifts for different stress paths could be studied. The time-shifts are stress path dependent, which is particularly pronounced at large offsets. For all stress paths, the time-shifts exhibit a linearly decreasing trend with increasing offset, that is, a negative offset gradient. At zero offset, for which the ray path is normal to the bedding, the time-shifts are similar for all investigated stress paths. The isotropic stress path is associated with the smallest offset gradient of the time-shifts. In contrast, the constant-mean-stress path shows the largest gradient with a flip in the polarity of the time-shifts for the largest offsets. The separate contributions from the strain and velocity changes to the time-shifts were also quantified. The time-shifts for the isotropic stress path are dominated by the contribution from velocity changes at all offsets. In contrast, the strain contributes significantly to the time-shifts at small offsets for the constant-mean-stress path. This shows that the offset dependence in pre-stack seismic data may be a key to understand the changes of subsurface stresses, pore pressure and strain upon depletion or injection. To utilize this knowledge from laboratory experiments, calibrated rock physics models and correlations are needed to constrain the seismic time-shifts and to obtain an adequately updated geological model reflecting the true anisotropic nature of the subsurface. This may have important implications for improved recovery and safety, particularly in mature fields.     

Archaeological site distribution by geomorphic setting in the southern lower Cuyahoga River Valley,northeastern Ohio: Initial observations from a GIS database

In this study, we compiled unpublished archival documentation of archaeological site locations from the southern part of the Cuyahoga River Valley in northeastern Ohio, USA, registered at the State of Ohio Historic Preservation Office into a Geographic Information Systems (GIS) database. Using digitized soil shapefiles to generate a geomorphic data layer, we assessed the spatial and temporal distribution of 79 known archaeological sites by landform association. This digital compilation indicates that Woodland period, Late Prehistoric, and Historic sites occur in most geomorphic settings along the river valley. In contrast, Paleoindian and Archaic sites only occur on Wisconsinan cut terraces and in upland interfluve settings, indicating that most of these documented sites are in primary contexts and have not been reworked. We discuss the distribution of archaeological sites in the study region as a function of various factors, including cultural activities, taphonomic processes, landform development, and the nature and extent of the original archaeological surveys. Observed spatial patterns of known sites clearly reflect local geomorphological controls; artifactual contexts from the earlier prehistoric periods are underrepresented in the database. We conclude that additional site surveys, as well as the excavation and documentation of new sites in this part of Ohio, are required to understand local prehistoric economies and to ascertain patterns of culturally mediated land use. © 2004 Wiley Periodicals, Inc.     

Ejby—A new H5/6 ordinary chondrite fall in Copenhagen,Denmark

On February 6, 2016 at 21:07:19 UT, a very bright fireball was seen over the eastern part of Denmark. The weather was cloudy over eastern Denmark, but many people saw the sky light up—even in the heavily illuminated Copenhagen. Two hundred and thirty three reports of the associated sound and light phenomena were received by the Danish fireball network. We have formed a consortium to describe the meteorite and the circumstances of the fall and the results are presented in this paper. The first fragment of the meteorite was found the day after the fall, and in the following weeks, a total of 11 fragments with a total weight of 8982 g were found. The meteorite is an unbrecciated, weakly shocked (S2), ordinary H chondrite of petrologic type 5/6 (Bouvier et al. 2017). The concentration of the cosmogenic radionuclides suggests that the preatmospheric radius was rather small ~20 cm. The cosmic ray exposure age of Ejby (83 ± 11 Ma) is the highest of an H chondrite and the second highest age for an ordinary chondrite. Using the preatmospheric orbit of the Ejby meteoroid (Spurny et al. 2017) locations of the recovered fragments, and wind data from the date of the fall, we have modeled the dark flight (below 18 km) of the fragments. The recovery location of the largest fragment can only be explained if aerodynamic effects during the dark flight phase are included. The recovery location of all other fragments are consistent with the dark flight modeling.     

Methane sources in gas hydrate-bearing cold seeps: Evidence from radiocarbon and stable isotopes

Fossil methane from the large and dynamic marine gas hydrate reservoir has the potential to influence oceanic and atmospheric carbon pools. However, natural radiocarbon (¹⁴C) measurements of gas hydrate methane have been extremely limited, and their use as a source and process indicator has not yet been systematically established. In this study, gas hydrate-bound and dissolved methane recovered from six geologically and geographically distinct high-gas-flux cold seeps was found to be 98 to 100% fossil based on its ¹⁴C content. Given this prevalence of fossil methane and the small contribution of gas hydrate (≤ 1%) to the present-day atmospheric methane flux, non-fossil contributions of gas hydrate methane to the atmosphere are not likely to be quantitatively significant. This conclusion is consistent with contemporary atmospheric methane budget calculations.In combination with δ¹³C- and δD-methane measurements, we also determine the extent to which the low, but detectable, amounts of ¹⁴C (~ 1–2% modern carbon, pMC) in methane from two cold seeps might reflect in situ production from near-seafloor sediment organic carbon (SOC). A ¹⁴C mass balance approach using fossil methane and ¹⁴C-enriched SOC suggests that as much as 8 to 29% of hydrate-associated methane carbon may originate from SOC contained within the upper 6 m of sediment. These findings validate the assumption of a predominantly fossil carbon source for marine gas hydrate, but also indicate that structural gas hydrate from at least certain cold seeps contains a component of methane produced during decomposition of non-fossil organic matter in near-surface sediment.     

U-Th-Pb and Trace Element Evaluation of Existing Titanite and Apatite LA-ICP-MS Reference Materials and Determination of 208Pb/232Th-206Pb/238U Date Discordance in Archaean Accessory Phases

The last decade has seen a marked increase in U-Th-Pb petrochronological studies focused on titanite and apatite. This has motivated the need for detailed, phase-specific method development and well-characterised reference materials with a wide variety of ages and chemical compositions. This study presents new U-Th-Pb isotope and major-, minor- and trace-element mass fraction data for ten titanite and five apatite reference materials based on integrated EPMA, LA-ICP-MS and isotope-dilution (ID) multi-collector (MC)-ICP-MS characterisation. Cross-comparison of EPMA and LA-ICP-MS data for the same titanite reference material suite demonstrates that careful selection of EPMA primary reference materials is necessary to minimise inaccuracies. We further identify a significant X-ray interference when measuring low Ce abundances in Ti-bearing phases and outline a method for its correction. New ID-MC-ICP-MS and LA-ICP-MS data suggest tri-concordance (defined as concordant ages for the ²³⁸U-²⁰⁶Pb, ²³⁵U-²⁰⁷Pb and ²³²Th-²⁰⁸Pb decay systems) of the MKED-1 titanite reference material and demonstrate the reproducibility of ²⁰⁸Pb/²³²Th measurements in some secondary titanite reference materials. Integration of ²⁰⁸Pb/²³²Th results with U-Pb geochronology provides a meaningful tool to help interpret complex U-Th-Pb isotopic age spectra. We provide example applications of ²⁰⁸Pb/²³²Th LA-ICP-MS measurements toward interpreting Archaean titanite ages from the Acasta Gneiss Complex, Northwest Territories, Canada.     

Effect of partial mining of shaft protection pillar in terms of reliability index

ABSTRACT

The work presents calculations of shaft support reliability index during partial extraction of protection pillar deposit and the related seismic phenomena. It has been assumed that the probability of failure caused by seismic phenomena depends on the velocity random variable of the shaft support vibrations. The random vibration velocity is a function of random variables of energy, shock distance and vibration frequency. Estimations of probability distributions for energy and frequency have been based on the actual measurement data from a mine. Failure probability has been estimated by means of methods based on so-called Hasofer-Lind reliability index β.     

Carbonation of lignite fly ash at ambient T and P in a semi-dry reaction system for CO2 sequestration

The global rise in atmospheric greenhouse gas concentrations calls for practicable solutions to capture CO₂. In this study, a mineral carbonation process was applied in which CO₂ reacts with alkaline lignite ash and forms stable carbonate solids. In comparison to previous studies, the assays were conducted at low temperatures and pressures and under semi-dry reaction conditions in an 8 L laboratory mixing device. In order to find optimum process conditions the pCO₂ (10-20%), stirring rate (500-3000 rpm) and the liquid to solid ratio (L/S = 0.03-0.36 L kg⁻¹) were varied. In all experiments a considerable CO₂ uptake from the gas phase was observed. Concurrently the solid phase contents of Ca and Mg (hydr)oxides decreased and CaCO₃ and MgCO₃ fractions increased throughout the experiments, showing that CO₂ was stabilized as a solid carbonate. The carbonation reaction depends on three factors: Dissolution of CO₂ in the liquid phase, mobilization of Ca and Mg from the mineral surface and precipitation of the carbonate solids. Those limitations were found to depend strongly on the variation of the process parameters. Optimum reaction conditions could be found for L/S ratios between 0.12 and 0.18, medium stirring velocities and pCO₂ between 10% and 20%.Maximum CO₂ uptake by the solid phase was 4.8 mmol g⁻¹ after 120 min, corresponding to a carbonation efficiency for the alkaline material of 53% of the theoretical CO₂ binding capacity. In comparison to previous studies both CO₂ uptake and carbonation efficiencies were in a similar range, but the reaction times in the semi-dry process were considerably shorter. The proposed method additionally allows for a more simple carbonation setup due to low T and P, and produces an easier to handle product with low water content.