The “Boscobel Landslip” of October 1st, 1901—the largest historic landslide in Barbados,West Indies

Barbados is a small Caribbean island located on the crest of an accretionary prism about 125 km east of the Lesser Antilles volcanic island arc. The oldest strata, Eocene sandstones and shales, are overlain by Oligocene–Miocene chalks and marls, in turn overlain by Pleistocene reef and lagoonal limestones that cover about 85 % of the island. The Eocene sediments, which crop out in the Scotland District of Barbados, are prone to soil creep and landslides covering tens to hundreds of hectares. The largest historic landslide, the “Boscobel Landslip,” occurred on 01 October 1901. We used nineteenth-century and more modern topographic and geologic maps, air photographs, and various archival and petrophysical data, to supplement reconnaissance of the landslide in the field. We identified about ten million cubic meters of the displaced material of the landslide, as well as the meteorological and geological conditions that contributed to the Boscobel Landslip. Similar landslides would pose a presently unquantified hazard to inhabitation and future development in the Scotland District.     

Effects of groundwater flow on mineral diagenesis, with emphasis on carbonate aquifers

 This article provides a critical synopsis of the effects of groundwater flow on mineral diagenesis. Emphasis is placed on those aspects and processes that change porosity and permeability in carbonate aquifers, because they are of particular importance to human societies as sources of supplies of water for human consumption (drinking, irrigation) and of crude oil and natural gas. Diagenetic settings in carbonates as well as clastics are generally ill defined. This paper proposes a new comprehensive classification of diagenetic settings into near-surface, shallow-, intermediate-, and deep-burial diagenetic settings; hydrocarbon-contaminated plumes; and fractures. These settings are defined on the basis of mineralogy, petroleum, hydrogeochemistry, and hydrogeology. This classification is applicable to all sedimentary basins. Diagenesis is governed by various intrinsic and extrinsic factors that include thermodynamic and kinetic constraints, as well as microstructural factors that may override the others. These factors govern diagenetic processes, such as dissolution, compaction, recrystallization, replacement, and sulfate–hydrocarbon redox-reactions. Processes such as cementation, dissolution, and dolomitization require significant flow of groundwater driven by an externally imposed hydraulic gradient. Other processes, such as stylolitization and thermochemical sulfate reduction, commonly take place without significant groundwater flow in hydrologically nearly or completely stagnant systems that are geochemically "closed." Two major effects of groundwater flow on mineral diagenesis are enhancement and reduction of porosity and permeability, although groundwater flow can also leave these rock properties essentially unchanged. In extreme cases, an aquifer or hydrocarbon reservoir rock can have highly enhanced porosity and permeability due to extensive mineral dissolution, or it can be plugged up due to extensive mineral precipitation. Received, April 1998 · Revised, July 1998 · Accepted, September 1998     

Main Species Characteristics of Phytoplankton Spring Blooms in NE Atlantic and Arctic Waters (68–80° N)

A compilation of phytoplankton species abundance data from the spring bloom along the northern Norwegian coast and in the Barents Sea shows that the quantitatively most important species are the prymnesiophyte Phaeocystis pouchetii and the common cold water to temperate diatoms Chaetoceros socialis, Skeletonema costatum sensu lato, Fragilariopsis oceanica, Thalassiosira spp., Chaetoceros furcellatus, Chaetoceros compressus, Chaetoceros debilis and Bacterosira bathyomphala. The relative abundance of diatoms and Phaeocystis varied highly and apparently stochastically between years. P. pouchetii occurred during all stages of the spring bloom and sometimes completely dominated the phytoplankton community. Along the Norwegian coast, the importance of P. pouchetii increased northwards. The species composition in coastal fjords at 70° N is surprisingly similar to that of shelf waters in the Barents Sea (up to 80° N). An exception is S. costatum sensu lato which was seldom observed in Arctic waters. Small flagellates (<10 μm) other than dinoflagellates and P. pouchetii are also important among the Barents Sea spring phytoplankton. Associations of species seem rigid over time and are dominated by C. socialis and P. pouchetii in northern waters. Biogeographical categories of spring bloom species in relation to environmental conditions are discussed.     

4He diffusion in specular hematite

In order to test the chronometer qualities of speculante for the (U + Th)/He dating method, ⁴He release experiments by stepwise heating of two specularites from the Rimbach mineralization locality in the southern Vosgues (France) have been carried out. The diffusion coefficients define linear Arrhenius plots within a temperature interval of 250 to 830 °C, which is suggestive of volume diffusion. Extrapolation of the diffusion behavior to 20° C yields diffusion coefficients (D₂₀ values) smaller than 10^?26 [cm² s^?1] for both hematites with activation energies at 116 [kJ/mole]. The results of our study suggest that specularite is a very helium retentive hematite variety which is capable of quantitatively retaining radiogenic helium over geologic periods of time.     

Varved sediments of Lake Yoa (Ounianga Kebir,Chad) reveal progressive drying of the Sahara during the last 6100 years

The sedimentological and geochemical properties of a 7·47 m long laminated sequence from hypersaline Lake Yoa in northern Chad have been investigated, representing a unique, continuous 6100 year long continental record of climate and environmental change in the eastern Central Sahara. These data were used to reconstruct the Mid to Late Holocene history of this currently hyper‐arid region, in order to address the question of whether the Mid Holocene environmental transition from a humid to a dry Sahara was progressive or abrupt. This study involved a suite of analyses, including petrographic and scanning electron microscope examination of thin sections, X‐ray diffraction, X‐radiography, granulometry, loss on ignition and magnetic susceptibility. The potential of micro‐X‐ray fluorescence core scanning was tested at very high resolution. Detailed microscopic investigation revealed the sedimentary processes responsible for the formation of the fine laminations, identified the season during which they were formed, and confirmed their annually rhythmic nature. High‐resolution X‐ray fluorescence core scanning allowed the distinction of each individual lamination over the entire record, opening new perspectives for the study of finely laminated sediment sequences. Geochemical and mineralogical data reveal that, due to decreasing monsoon rainfall combined with continuous and strong evaporation, the hydrologically open and fresh Mid Holocene Lake Yoa slowly evolved into the present‐day hypersaline brine depleted in calcium, which has existed for about the past 1050 years. During the oldest part of the investigated period, Lake Yoa probably contained a permanently stratified lower water column that was nevertheless disrupted relatively frequently by mixing events. Deep‐water anoxia became more stable because of increased salinity‐driven density stratification. In parallel, the sediment grain‐size proxies record a progressive increase of aeolian input in the course of the last 6100 years. Altogether, all geochemical and sedimentological indicators point to a progressive drying of the eastern Central Sahara, strengthening previous conclusions based on palaeoecological indicators.     

Improved numerical dissipation for time integration algorithms in structural dynamics

A new family of unconditionally stable one-step methods for the direct integration of the equations of structural dynamics is introduced and is shown to possess improved algorithmic damping properties which can be continuously controlled. The new methods are compared with members of the Newmark family, and the Houbolt and Wilson methods.     

Jahresgänge des Dampfdrucks und der relativen Feuchte in verschiedenen Gebieten des Mittelmeers

Zusammenfassung Für 11 ausgewählte Gebiete auf dem Hauptschiffahrtweg längs der nordafrikanischen Küste sind Jahresgänge des Dampfdrucks und der relativen Feuchte aus den Messungen abgeleitet, die seit 1950 an Bord deutscher Handelsschiffe mit dem Schleuderpsychrometer durchgeführt wurden. Eine Erklärung des inversen Ganges der relativen Feuchte auf See wird versucht.

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Summary For 11 selected areas within the principal route of navigation along the coast of Northern Africa annual variations of vapour pressure and humidity are derived from measurements with help of swing psychrometers, which were carried out since 1950 aboard German merchant ships. An explanation of the inverse variation of the humidity at sea is attempted.

     

The fall and rise of metropolitan government in Copenhagen

In this paper it is argued that the re-establishment of a metropolitan government in the Greater Copenhagen Area in 2000 (Greater Copenhagen Authority) is not to be seen as a return to the kind of regional, coordinative authority (Greater Copenhagen Council) that was abolished in the Thatcherite climate of the 1980s. Throughout the 1980s and 1990s new forms of urban governance, entrepreneurialism and a higher national priority to the capital region were introduced, which changed the conditions under which the new metropolitan government is operating. This `contextualization' of the analysis of the two generations of metropolitan government points to the fact that typologies of metropolitan government, such as the one put forward by Sharpe (1995), often lacks analytical cogency. This revised version was published online in August 2006 with corrections to the Cover Date.     

Concurrent low- and high-affinity sulfate reduction kinetics in marine sediment

Bacterial sulfate reduction in marine sediments generally occurs in the presence of high millimolar concentrations of sulfate. Published data indicate that low sulfate concentrations may limit sulfate reduction rates below 0.2-2 mM. Yet, high sulfate reduction rates occur in the 1-100 μM range in freshwater sediments and at the sulfate-methane transition in marine sediments. Through a combination of ³⁵S-tracer experiments, including initial velocity experiments and time course experiments, we searched for different sulfate affinities in the mixed community of sulfate reducers in a marine sediment. We supported the radiotracer experiments with a highly sensitive ion chromatographic technique for sulfate with a detection limit of 0.15 μM SO₄²⁻ in marine pore water. Our results showed that high and low affinities for sulfate co-occur and that the applied experimental approach may determine the observed apparent half saturation constant, K_m. Our experimental and model data both show that sulfate reduction in the studied marine sediment could be explained by two dominating affinities for sulfate: a low affinity with a mean half saturation constant, K_m, of 430 μM SO₄²⁻ and a high affinity with a mean K_m of 2.6 μM SO₄²⁻. The high-affinity sulfate reduction was thermodynamically un-constrained down to <1 μM SO₄²⁻, both in our experiments and under in situ conditions. The reduction of radio-labeled sulfate was partly reversible due to concurrent re-oxidation of sulfide by Fe(III) and possibly due to a reversibility of the enzymatic pathway of sulfate reduction. A literature survey of apparent K_m values for sediments and pure cultures is presented and discussed.