DEVELOPMENT OF A DECISION SUPPORT SYSTEM FOR MANAGING PESTICIDE LOSSES IN AGRICULTURAL WATERSHEDS

1 INTRODUCTION Agricultural use of pesticides has been recognized as one of the important non-point pollution sources in the world, and the pesticide application to agricultural lands has led to large amounts of residues discharged into surface water through runoff (Leonard, 1990). There have been growing concerns about the fate and transport of pesticides in agricultural lands, due to the associated adverse impacts on water environment and human health (Agassi et al., 1995; Ng and Clegg…     

Methodology for construction, calibration and validation of a national hydrological model for Denmark

An integrated groundwater/surface water hydrological model with a 1 km² grid has been constructed for Denmark covering 43,000 km². The model is composed of a relatively simple root zone component for estimating the net precipitation, a comprehensive three-dimensional groundwater component for estimating recharge to and hydraulic heads in different geological layers, and a river component for streamflow routing and calculating stream–aquifer interaction. The model was constructed on the basis of the MIKE SHE code and by utilising comprehensive national databases on geology, soil, topography, river systems, climate and hydrology. The present paper describes the modelling process for the 7330 km² island of Sjælland with emphasis on the problems experienced in combining the classical paradigms of groundwater modelling, such as inverse modelling of steady-state conditions, and catchment modelling, focussing on dynamic conditions and discharge simulation. Three model versions with different assumptions on input data and parameter values were required until the performance of the final, according to pre-defined accuracy criteria, model was evaluated as being satisfactory. The paper highlights the methodological issues related to establishment of performance criteria, parameterisation and assessment of parameter values from field data, calibration and validation test schemes. Most of the parameter values were assessed directly from field data, while about 10 ‘free’ parameters were subject to calibration using a combination of inverse steady-state groundwater modelling and manual trial-and-error dynamic groundwater/surface water modelling. Emphasising the importance of tests against independent data, the validation schemes included combinations of split-sample tests (another period) and proxy-basin tests (another area).     

The BEAM-project: prediction and assessment of mixture toxicities in the aquatic environment

Freshwater and marine ecosystems are exposed to various multi-component mixtures of pollutants. Nevertheless, most ecotoxicological research and chemicals regulation focus on hazard and exposure assessment of individual substances only, the problem of chemical mixtures in the environment is ignored to a large extent. In contrast, the assessment of combination effects has a long tradition in pharmacology, where mixtures of chemicals are specifically designed to develop new products, e.g. human and veterinary drugs or agricultural and non-agricultural pesticides. In this area, two concepts are frequently used and are thought to describe fundamental relationships between single substance and mixture effects: Independent Action (Response Addition) and Concentration Addition. The question, to what extent these concepts may also be applied in an ecotoxicological and regulatory context may be considered a research topic of major importance, as the concepts would allow to make use of already existing single substance toxicity data for the predictive assessment of mixture toxicities. Two critical knowledge gaps are identified: (a) There is a lack of environmental realism, as a huge part of our current knowledge about the applicability of the concepts is restricted to artificial situations with respect to mixture composition or biological effect assessment. (b) The knowledge on what exactly is needed for using the concepts as tools for the predictive mixture toxicity assessment is insufficient. Both gaps seriously hamper the necessary, scientifically sound consideration of mixture toxicities in a regulatory context.In this paper, the two concepts will be briefly introduced, the necessity of considering the toxicities of chemical mixtures in the environment will be demonstrated and the applicability of Independent Action and Concentration Addition as tools for the prediction and assessment of mixture toxicities will be discussed. An overview of the specific aims and approaches of the BEAM project to fill in the identified knowledge gaps is given and first results are outlined.     

On the circulation in the East Frisian Wadden Sea: numerical modeling and data analysis

 In this paper we use a combination of numerical modeling and data analysis to gain a better understanding of the major characteristics of the circulation in the East Frisian Wadden Sea. In particular, we concentrate on the asymmetry of the tidal wave and its modulation in the coastal area, which results in a complex pattern of responses to the sea-level forcing from the North Sea. The numerical simulations are based on the 3-D primitive equation General Estuarine Transport Model (GETM) with a horizontal resolution of 200 m and terrain-following vertical coordinates. The model is forced at its open boundaries with sea-level data from an operational model for the German Bight (German Hydrographic Office). The validation data for our model simulations include time series of tidal gauge data and surface currents measured at a pile in the back-barrier basin of the Island Langeoog, as well as several ADCP transects in the Accumer Ee tidal inlet. Circulation and turbulence characteristics are investigated for typical situations driven by spring and neap tides, and the analysis is focused on dominating temporal and spatial patterns. By investigating the response of five back-barrier basins with rather different morphologies to external forcing, an attempt is made to elucidate the dominating physical balances controlling the circulation in the individual sub-basins. It is demonstrated that the friction at the seabed tends to slow down the tidal signal in the shallow water. This leads to the establishment of flood dominance in the shallow sea north of the barrier islands. South of the islands, where the water volume of the channels at low tide is smaller than the tidal prism, the asymmetry of the tidal signal is shifted towards ebb dominance, a feature which is particularly pronounced at spring tide. At the northern open boundary, the tidal wave propagating from west to east generates a sea-level difference of ∼1 m along the boundary, and thereby triggers vigorous alongshore currents. The frictional control in the model is located in the inlets, as well as along the northern boundary. The correlation between velocity and turbulent kinetic energy tends to the establishment of a net southward transport, giving theoretical support to the observed accumulation of sediments on the intertidal flats. Weak turbulence along the northern shores of the barrier islands and the small magnitude of the residual currents there promote accumulation of suspended matter in these areas, although wave action will generally counteract this effect. Received: 29 May 2002 / Accepted: 26 September 2002 Responsible Editor: Jean-Marie Beckers Acknowledgements We are indebted to S. Dick for providing the data from the operational model of BSH and to B. Flemming for the useful discussions. The topography data and Fig. 1 have been prepared in cooperation with F. Meyer. Figure 2 has been prepared by G. Brink-Spalink. We also thank for the comments from an anonymous reviewer which helped to improve our paper.     

Field Survey and Numerical Simulations: A Review of the 1998 Papua New Guinea Tsunami

— The Papua New Guinea (PNG) tsunami of 1998 is re-examined through a detailed review of the field survey as well as numerous numerical computations. The discussion of the field survey explores a number of possible misinterpretations of the recorded data. The survey data are then employed by a numerical model as a validation tool. A Boussinesq model and a nonlinear shallow water wave (NLSW) model are compared in order to quantify the effect of frequency dispersion on the landslide-generated tsunami. The numerical comparisons indicate that the NLSW model is a poor estimator of offshore wave heights. However, due to what appears to be depth-limited breaking seaward of Sissano spit, both numerical models are in agreement in the prediction of maximum water elevations at the overtopped spit. By comparing three different hot-start initial profiles of the tsunami wave, it is shown that the initial shape and orientation of the tsunami wave is secondary to the initial displaced water mass in regard to prediction of water elevations on the spit. These numerical results indicate that agreement between numerical prediction of runup values with field recorded values at PNG cannot be used to validate either a NLSW tsunami propagation model or a specific landslide tsunami hot-start initial condition. Finally, with the use of traditional tsunami codes, a new interpretation of the PNG runup measurements is presented.     

An EFTEM/HRTEM high-resolution study of the near surface of labradorite feldspar altered at acid pH: evidence for interfacial dissolution-reprecipitation

Using an approach combining high-resolution and energy-filtered transmission electron microscopy (HRTEM and EFTEM), we have studied with Å to nm-spatial resolution the interfacial region that delimits the near-surface altered zone and non-altered labradorite feldspar after dissolution under acid pH conditions. The interface is characterized by extremely sharp and spatially coincident changes in structure and chemistry. The 500-nm-thick altered zone is depleted in interstitial cations (Ca, Na, K) and Al, a framework element, whereas it is enriched in H, O, and Si. Modeling H⁺-alkali interdiffusion within a 500-nm-thick altered zone shows that volume interdiffusion cannot reproduce the sharp chemical interfaces measured by EFTEM. Based on these new data, we propose that the near-surface altered zone is a result of interfacial dissolution-reprecipitation, and not of preferential leaching of cations and interdiffusion with H⁺. This implies an intrinsic dissolution process that is stoichiometric, where the breaking of bonds and release of interstitial cations and framework elements (Al, Si, and O) to solution occur contemporaneously at equal relative rates from the original fluid–mineral interface.     

Numerical simulation of a South China Sea typhoon Leo (1999)

Summary ?A South China Sea typhoon, Leo (1999), was simulated using the Penn State/NCAR mesoscale model MM5 with the Betts-Miller convective parameterization scheme (BMEX). The simulation had two nested domains with resolutions at 54 and 18 km, and the forecast duration was 36 hours. The model was quite successful in predicting the track, the rapid deepening, the central pressure, and the maximum wind speed of typhoon Leo as verified with reports from the Hong Kong Observatory (HKO). The structure of the eye, the eye wall, and the spiral convective cloud band simulated in the model are found to be comparable to corresponding features identified in satellite images for the storm, and also with those reported by other authors. A trajectory analysis was performed. Three kinds of trajectory were found: (1) spirally rising trajectories near the eye wall; (2) spirally rising/descending trajectories in the convective/cloud free belt; (3) straight and fast rising trajectories in a heavy convection zone along one of the cloud bands on the periphery of the tropical cyclone. Both the HKO and the U.S. Joint Typhoon Warning Center (JTWC) reported the rapid deepening of Leo started around 00 UTC 29 April. In the model, the eye was first formed in the lower troposphere, and it extended to the upper troposphere within a few hours. We speculate that the spin-up of cyclonic rotation in the low-level eye enhanced the positive vorticity along the low-level eye wall. The positive vorticity was then transported to the upper troposphere by convection, leading to an extension and growth of the eye into the upper troposphere. To examine the impact of convective parameterization scheme (CPS) on the simulation, the Grell scheme (GLEX) was also tested. The GLEX predicted a weaker typhoon with a wilder eye that extended not as high up in the upper troposphere as BMEX. The different structures of the eye between the BMEX and GLEX suggest that the mesoscale features of the eye are dependent on the convection. In other words, the vertical and horizontal distribution of convective heating is essential to the development and structure of the eye. Received December 18, 2001; accepted May 7, 2002 Published online: March 20, 2003     

Sampling Fauna in Stream Sediments as well as Groundwater Using One Net Sampler

Groundwater bores act as traps. Net samplers are regularly used for sampling this type of trap for fauna. To enable direct comparisons of faunal communities in groundwater bores and stream sediments, stream sediment tubes were built similar to groundwater bores and were sampled with net samplers for fauna. These stream sediment tubes consisted of a tube anchored in the stream sediment, also called interstitial space. To test the efficacy of this trap method in stream sediments, it was compared to another type of trap, Hahn's trap. Faunal communities sampled by a net in the stream sediment tubes did not differ hugely from fauna in Hahn's trap samples. Physical and chemical factors of sampled water in both the stream sediment tubes, the surrounding interstitial sediments and the second type of traps, Hahn's traps, showed that water in both the tubes and Hahn's traps was closely related to interstitial water. The net sampler is inexpensive and easy to handle. It is suggested that sampling stream tubes with nets may be an appropriate method for long‐term monitoring studies.     

Modelling transverse dunes

Transverse dunes appear in regions of mainly unidirectional wind and high sand availability. A dune model is extended to two‐dimensional calculation of the shear stress. It is applied to simulate dynamics and morphology of three‐dimensional transverse dunes. In the simulations they seem to reach translational invariance and do not stop growing. Hence, simulations of two‐dimensional dune ?elds have been performed. Characteristic laws were found for the time evolution of transverse dunes. Bagnold's law of the dune velocity is modi?ed and reproduced. The interaction between transverse dunes led to the interesting conclusion that small dunes can travel over bigger ones. Copyright © 2004 John Wiley & Sons, Ltd.