Time series analyses of concentration and wind fluctuations

Analyses of concentration fluctuation (C) spectra from boundary-layer smoke plume experiments at six separate locations show that the spectra from these experiments generally exhibit an inertial subrange at high frequencies with a slope of -5/3 and indicate peak energy at a time period of about 50 to 100 s. These periods of peak energy are a factor of two to five less than those for the peak of the wind speed fluctuation (u or v) spectra. A general spectral formula fits normalized spectra from the U.S. and Australia, where the frequency, n, is made dimensionless by multiplying by the plume dispersion parameter, _y , and dividing by the wind speed, u. Peak energy occurs at a dimensionless frequency of n _y/u equal to about 0.15. The Kolmogorov constant in the inertial subrange is estimated from a set of averaged spectra. Cross-spectra indicate little relation between concentration and wind fluctuations. However, most of the correlation that exists is due to periods larger than about 10 or 20 s.     

Linking mineralogy and spectroscopy of highly aqueously altered CM and CI carbonaceous chondrites in preparation for primitive asteroid sample return

The highly hydrated, petrologic type 1 CM and CI carbonaceous chondrites likely derived from primitive, water‐rich asteroids, two of which are the targets for JAXA's Hayabusa2 and NASA's OSIRIS‐REx missions. We have collected visible and near‐infrared (VNIR) and mid infrared (MIR) reflectance spectra from well‐characterized CM1/2, CM1, and CI1 chondrites and identified trends related to their mineralogy and degree of secondary processing. The spectral slope between 0.65 and 1.05 μm decreases with increasing total phyllosilicate abundance and increasing magnetite abundance, both of which are associated with more extensive aqueous alteration. Furthermore, features at ~3 μm shift from centers near 2.80 μm in the intermediately altered CM1/2 chondrites to near 2.73 μm in the highly altered CM1 chondrites. The Christiansen features (CF) and the transparency features shift to shorter wavelengths as the phyllosilicate composition of the meteorites becomes more Mg‐rich, which occurs as aqueous alteration proceeds. Spectra also show a feature near 6 μm, which is related to the presence of phyllosilicates, but is not a reliable parameter for estimating the degree of aqueous alteration. The observed trends can be used to estimate the surface mineralogy and the degree of aqueous alteration in remote observations of asteroids. For example, (1) Ceres has a sharp feature near 2.72 μm, which is similar in both position and shape to the same feature in the spectra of the highly altered CM1 MIL 05137, suggesting abundant Mg‐rich phyllosilicates on the surface. Notably, both OSIRIS‐REx and Hayabusa2 have onboard instruments which cover the VNIR and MIR wavelength ranges, so the results presented here will help in corroborating initial results from Bennu and Ryugu.     

Alkalic parental magmas for chassignites?

Abstract Detailed analysis of cumulate and melt inclusion assemblages in the chassignites provide important constraints on the nature of the melt trapped as inclusions in cumulus olivine (and, by extension, parental magma compositions), the pressures of crystallization, and magmatic volatile contents. These mineral assemblages show strong similarities to the experimental fractionation assemblages that produce the sodic silica‐saturated alkalic lavas on Earth (e.g., Ascension Island, Azores, the Nandewar volcano of Australia). The experimental assemblages were produced from silica‐saturated hawaiite at pressures above 4.3 kbar with dissolved water contents above 0.5 wt%. Such pressures are consistent with Ti:Al ratios of the melt‐inclusion pyroxenes in the Chassigny meteorite. Pyroxene compositions suggest early high crystallization temperatures and thus relatively low initial water and F contents. Feldspars indicate that melt evolution proceeded to rhyolite compositions both within the interstices of the cumulate olivine and within the melt inclusions, even though rhyolitic glass is only found within olivine‐hosted polyphase melt inclusions. The observed rhyolite glass is compositionally similar to the alkali‐rich rhyolite of Ascension Island which is produced experimentally by crystallization of hawaiite. It is proposed that the melt trapped in cumulus olivine of the Chassigny dunite was similar to a terrestrial silica‐saturated hawaiite, while that trapped in olivine of the Northwest Africa (NWA) 2727 dunite was less evolved, perhaps mildly alkalic basalt. Melts similar to terrestrial intra‐plate tholeiite could be parental to the cumulus minerals and evolve upon crystallization at pressures above 4.3 kbar and water contents above ?0.4 wt% to mildly alkalic basalt, silica‐saturated hawaiite, and alkali‐rich rhyolite. The melt inclusion assemblages are inconsistent with either crystallization of a low‐Al, high‐Fe basalt, or low‐pressure crystallization of a terrestrial‐like tholeiite.     

Array filters for sidelobe elimination

The response of an array of sensors to coherent undesired noise interfering with the measurement of a desired signal can be optimized if special filters are applied to the outputs of the sensors. In this paper, we derive analytic expressions for filters which minimize the power spectrum of the array response to the undesired coherent signal while simultaneously providing an all-pass condition for the desired signal. These filters are shown to yield an array rejection response which has zero-width main lobes and no sidelobes. An example illustrating the results is also presented.     

An empirical formula for the height of the coastal internal boundary layer

Observations of the height of the daytime coastal internal boundary layer at several sites are used to justify an empirical formula in the Offshore and Coastal Dispersion (OCD) model, which states that the boundary-layer slope is 0.1 in the first 2km from the shoreline, and 0.03 therafter.     

Prospects for Solar and Space Weather Research with Polish Part of the LOFAR Telescope

The LOw-Frequency ARray (LOFAR) is a new radio interferometer that consists of an array of stations. Each of them is a phase array of dipole antennas. LOFAR stations are distributed mostly in the Netherlands, but also throughout Europe. In the article we discuss the possibility of using this instrument for solar and space weather studies, as well as ionosphere investigations. We are expecting that in the near future the LOFAR telescope will bring some interesting observations and discoveries in these fields. It will also help to observe solar active events that have a direct influence on the near-Earth space weather.     

Changes in Nutrient and Carbon Availability and Temperature as Factors Controlling Bacterial Growth in the Northern Baltic Sea

The effects of inorganic nutrient (N and P) and glucose C treatments on bacterial growth were followed for 3 days in natural surface and deep water bacterial samples during the main post-spring bloom stages of phytoplankton growth in the northern Baltic Sea. In addition, the importance of photochemical degradation of dissolved organic matter on bacterial growth was investigated vertically (0.1–2.0 m) and spatially, in a salinity gradient from river mouth to open sea. Bacterial production was consistently C limited in the surface layer, with N or both N and P as the secondary limiting nutrients from spring to early summer and in late summer, respectively. In deep water, bacterial growth showed combined temperature and C limitation, and in spring, this also appeared to be true with surface samples. The effect of 1-day sunlight pre-treatment varied from no effect up to a 44% production increase, with clear bacterial production responses only being seen at the surface (10 cm depth). The implications of bacterial C limitation for the structure and function of the surface plankton ecosystem, including its CO₂ exchange with the atmosphere are discussed.     

Composition and solubility of precipitated copper(II) arsenates

Equilibrium reactions involving Cu(II) and As(V) have been studied with respect to formation of complexes in aqueous solutions as well as formation of solid phases. Potentiometric titrations performed at 25 °C (I = 0.1 M Na(Cl)) and at different Cu to As ratios gave no evidence for the existence of Cu(II) arsenate complexes in solution below the pH of the precipitation boundaries (pH ≈ 4), irrespective of the Cu to As ratio and pH. Mixing of solutions of Cu(II) and As(V) at different proportions and adjusting pH to values ranging from 4 to 9 resulted in precipitation of five different solid phases. The elemental composition of the solids was determined using X-ray Photoelectron Spectroscopy, and Environmental Scanning Microscopy-Field Emission Gun equipped with an energy dispersive spectroscopy detector. The average Cu/As ratio was determined by dissolving the solids. Total soluble concentrations of the components Cu(II) and As(V), as well as the basicity of the solid phases were determined by analysis of aqueous solutions. Based upon these experimental data the stoichiometric composition of the solid phases and their stability were determined. The resulting equilibrium model includes the solid phases Cu₃(AsO₄)₂, Cu₃(AsO₄)(OH)₃, Cu₂(AsO₄)(OH), Cu₅Na(HAsO₄)(AsO₄)₃ and Cu₅Na₂AsO₄)₄, where Cu₅Na(HAsO₄)(AsO₄)₃ and Cu₅Na₂(AsO₄)₄ have not been reported previously. In 0.1 M Na(Cl), Na⁺ was found to be a significant component in two of the solid phases. The Cu₅Na₂(AsO₄)₄ was formed in weakly alkaline conditions with pNa < 2.5. Stability constants for all solid phases have been determined. Distribution diagrams as well as predominance area (pNa-pH) diagrams are presented to illustrate stability fields of the different solid phases.     

Quasi-geostrophic shallow-water vortex–patch equilibria and their stability

We examine the equilibrium form, properties, stability and nonlinear evolution of steadily-rotating simply-connected vortex patches in the single-layer quasi-geostrophic model of geophysical fluid dynamics. This model, valid for rotating shallow-water flow in the limit of small Rossby and Froude numbers, has an intrinsic length scale L _D called the “Rossby deformation length” relating the strength of the stratification to that of the background rotation. Here, we generate steadily-rotating vortex equilibria for a wide range of γ?=?L/L _D , where L is the typical horizontal length scale of the vortex. We vary both γ (over the range 0.02?≤?γ?≤?10) and the vortex aspect ratio λ (over the range 0?<?λ?<?1). We find two modes of instability arising at sufficiently small aspect ratio λ?<?λ _c (γ): an asymmetric (dominantly wave 3) mode at small γ (or large L _D ) and a symmetric (dominantly wave 4) mode at large γ (or small L _D ). At marginal stability, the asymmetric mode dominates for γ???3, while the symmetric mode dominates for γ???3. The nonlinear evolution of weakly-perturbed unstable equilibria results in major structural changes, in most cases producing two dominant vortex patches and thin, quasi-passive filaments. Overall, the nonlinear evolution can be classified into three principal types: (1) vacillations for a limited range of aspect ratios λ when 5?≤?γ?≤?6, (2) filamentation and a single-dominant vortex for γ???1, and (3) vortex splitting – asymmetric for 1???γ???4 and symmetric for γ???4.     

Macroscopic impacts of cloud and precipitation processes in shallow convection

This paper presents application of the EULAG model combined with a sophisticated double-moment warm-rain microphysics scheme to the model intercomparison case based on RICO (Rain in Cumulus over Ocean) field observations. As the simulations progress, the cloud field gradually deepens and a relatively sharp temperature and moisture inversions develop in the lower troposphere. Two contrasting aerosol environments are considered, referred to as pristine and polluted, together with two contrasting subgridscale mixing scenarios, the homogeneous and the extremely inhomogeneous mixing. Pristine and polluted environments feature mean cloud droplet concentrations around 40 and 150 mg^?1, respectively, and large differences in the rain characteristics. Various measures are used to contrast evolution of macroscopic cloud field characteristics, such as the mean cloud fraction, the mean cloud width, or the height of the center of mass of the cloud field, among others. Macroscopic characteristics appear similar regardless of the aerosol characteristics or the homogeneity of the subgrid-scale mixing.