The petrogenetic association of carbonatite and alkaline magmatism: constraints from the Masfut-Rawda Ridge, Northern Oman Mountains

Summary ?A new occurrence of carbonatites associated with intrusive ijolite and syenite has been discovered within the Hawasina Complex underlying the Semail Ophiolite Complex at the southern part of the Rawda-Masfut ridge, Northern Oman Mountains. The carbonatites occur as dikes and sills with lengths of several hundreds of meters and range in composition from calciocarbonatites to ferruginous calciocarbonatites. The carbonatites intruded the ijolite and the associated radiolarian cherts of the Early Cretaceous Sid’r Formation. The close spatial association of carbonatite, ijolite, syenite and radiolarian cherts along with geological, petrographical and geochemical data indicates that these rocks are of intra-oceanic origin. Petrological and field relationships between the carbonatite and associated alkaline silicate intrusives from the Masfut area are consistent with the carbonatites being generated as derivative magmas through liquid immiscibility. They appear to represent magmas related to the volcanism associated with regional crustal extension that preceded the genesis of the Semail Ophiolite. Received April 19, 2001; revised version accepted February 18, 2002     

Hydrothermal jarosite and hematite in a pyroxene-hosted melt inclusion in martian meteorite Miller Range (MIL) 03346: Implications for magmatic-hydrothermal fluids on Mars

Low-temperature aqueous processes have been implicated in the generation of jarosite and hematite on the martian surface, but little is known regarding the role that high-temperature magmatic fluids may have played in producing similar assemblages on Mars. We have identified jarosite and hematite in a clinopyroxene-hosted melt inclusion in martian meteorite MIL 03346 that shows evidence of having been hydrothermally precipitated. In addition to jarosite and hematite, the melt inclusion contains titanomagnetite, pyrrhotite, potassic-chlorohastingsite, an iron-rich silicate glass and possibly goethite. These phases were identified and characterized using scanning electron microscopy (SEM), con-focal Raman-spectroscopy and electron probe microanalysis (EPMA).Based on observed textural relationships and the compositions of the hosted phases, we report that the jarosite-bearing melt inclusion in MIL 03346 has recorded a fluid-rich history that began in the magmatic stage and continued to low-temperatures. This history begins at entrapment of a volatile-rich silicate melt that likely reached fluid-saturation after only minor crystallization within the melt inclusion. This fluid, rich in chlorine, reacted with surrounding silicate material to produce the potassic-chlorohastingsite. As cooling proceeded, the liquid phase eventually became more oxidized and reacted with the pyrrhotite. Sulfide oxidation resulted in SO₄²⁻ formation and concomitant acid production, setting the stage for jarosite formation once the fluid cooled beyond the upper thermal stability of jarosite (∼200 °C). As the fluid cooled below 200 °C, jarosite continued to precipitate with hematite and/or goethite until equilibrium was established or reactions became kinetically unfavorable.This work suggests an additional jarosite-hematite formation pathway on Mars; one that may be important wherever magmatic-hydrothermal fluids come into contact with primary sulfide grains at the martian surface or subsurface. Moreover, hydrothermal fluids rich in chlorine, sulfur, and iron are important for ore-forming processes on Earth, and their indirect identification on Mars may have important implications for ore-formation on Mars.     

Glaciodynamically upthrusted bands of englacially transported debris in the Pleistocene of central Poland

Two kinds of buried structures are described from Dzirżenin, north-east of Warsaw, where they occur within a glaciofluvial landform: (1) narrow till ridges, showing vertically oriented structures, excavated from stratified gravel and sands; and (2) a narrow vertical zone of massive gravelly/sandy material, involving vertically oriented lens-like layers composed of massive sand with pebbles, or of diamicton. The gravelly/sandy zone is also closely surrounded by stratified glaciofluvial sediments. In spite of their vertical position and internal deformation, the till ridges and gravelly/sandy zone show non-tectonic contacts with the surrounding, stratified, undisturbed sediments. The glaciofluvial sediments that occur immediately next to the structures under discussion are characterized by the occurrence of comparatively coarse material and interbeddings of diamicton, which wedge out away from these structures. The gravelly/sandy zone separates different kinds of water-laid deposits. The buried structures are interpreted as former debris-laden bands, thrust upwards within the frontal part of the ice sheet and then transformed into still-frozen debris ridges projecting over the already dead ice. Further melting of the decaying ice resulted in abundant glaciofluvial sedimentation, and the debris ridges also supplied material for the deposition of the neighbouring stratified deposits. One of the ridges separated different glaciofluvial environments. The glaciofluvial sediments completely buried the ice-cemented ridges, which were finally transformed by a melting-out process into the till ridges and the gravelly/sandy zone. The former are interpreted as having been transformed from upturned debris-laden bands with a high concentration of debris or from the bands composed of frozen-up sediment slabs. The gravelly/sandy zone is interpreted as having (most probably) been deposited from upturned bands characterized by a lesser concentration of debris.     

Speleothem evidence for late Holocene climate variability and floods in Southern Greece

We present stable isotope data (δ¹⁸O, δ¹³C) from a detrital rich stalagmite from Kapsia Cave, the Peloponnese, Greece. The cave is rich in archeological remains and there are reasons to believe that flooding of the cave has directly affected humans using the cave. Using a combination of U–Th and ¹⁴C dating to constrain a site-specific correction factor for (²³²Th/²³⁸U) detrital molar ratio, a linear age model was constructed. The age model shows that the stalagmite grew during the period from ca. 950 BC to ca. AD 830. The stable oxygen record from Kapsia indicates cyclical changes of close to 500 yr in precipitation amount, with rapid shifts towards wetter conditions followed by slowly developing aridity. Superimposed on this signal, wetter conditions are inferred around 850, 700, 500 and 400–100 BC, and around AD 160–300 and AD 770; and driest conditions are inferred to have occurred around 450 BC, AD 100–150 and AD 650. Detrital horizons in the stalagmite indicate that three major floods took place in the cave at 500 BC, 70 BC and AD 450. The stable carbon isotope record reflects changes in biological activity being a result of both climate and human activities.     

Simulated asteroid materials based on carbonaceous chondrite mineralogies

A set of high‐fidelity simulated asteroid materials, or simulants, was developed based on the mineralogy of carbonaceous chondrite meteorites. Three varieties of simulant were developed based on CI1 chondrites (typified by Orgueil), CM2 chondrites (typified by Murchison), and CR2/3 chondrites (multiple samples). The simulants were designed to replicate the mineralogy and physical properties of the corresponding meteorites and anticipated asteroid surface materials as closely as is reasonably possible for bulk amounts. The simulants can be made in different physical forms ranging from larger cobbles to fine‐grained regolith. We analyzed simulant prototypes using scanning electron microscopy, X‐ray fluorescence, reflectance spectroscopy at ambient conditions and in vacuum, thermal emission spectroscopy in a simulated asteroid environment chamber, and combined thermogravimetry and evolved gas analysis. Most measured properties compare favorably to the reference meteorites and therefore to predicted volatile‐rich asteroid surface materials, including boulders, cobbles, and fine‐grained soils. However, there were also discrepancies, and mistakes were made in the original mineral formulations that will be updated in the future. The asteroid simulants are available to the community from the nonprofit Exolith Lab at UCF, and the mineral recipes are freely published for other groups to reproduce and modify as they see fit.     

新的加利福尼亚地震动日常概率地图

美国地质调查局(USGS)5月18日宣布开放一个可显示加州地区未来24小时内发生地震概率的公共网站。在余震或可能的前震序列期间,它以地图的形式向人们展示地震发生概率的变化。     

A least sensitive multichannel optimum filter for sensor arrays

A family of multichannel filters that can provide complete suppression of coherent interference for almost all frequencies is characterized. The authors then determine the particular member in this family that yields an output that is least sensitive to estimation errors in the parameters which characterize the coherent interference. This filter, called the absolutely optimum array filter (AOAF), is described. This robustness property of the AOAF filter is considered particularly important in applications where imperfect estimates of the parameters are used in the filter design. An example illustrating the results is presented