Hydrogeochemical outline of thermal waters and geothermometry applications in Anatolia (Turkey)

The chemical compositions of a total of 120 thermal water samples from four different tectonically distinct regions (Central, North, East and West Anatolia) of Turkey are presented and assessed in terms of geothermal energy potential of each region through the use of chemical geothermometers. Na–Ca–HCO₃ type waters are the dominant water types in all the regions except that Na–Cl type waters are typical for the coastal areas of West Anatolia and for a few inland areas of West and Central Anatolia where deep water circulation exists. The discharge temperature of the springs ranges up to 100°C, and the bottom-hole temperatures in drilled wells up to 232°C. Geothermometry applications yield reservoir temperatures of about 125°C for Central Anatolia, 110°C for North Anatolia, 136°C for East Anatolia and 251°C for West Anatolia, the latter agreeing with some of the bottom hole temperatures measured in drilled wells. The results reveal that the highest geothermal energy potential in Turkey is associated with the West Anatolian extensional tectonics which provides a regional, deep-seated heat source and a widespread graben system allowing deep circulation of waters. The North Anatolian region, bounded to the south by the dextral North Anatolian Fault along which most of the geothermal sites are located, has the lowest energy potential, probably due to the restriction of the heat source to local magmatic activities confined to pull-apart basins. The East Anatolian region (undergoing contemporary compression) and the Central Anatolian region (where the compressional regime in the east is converted to the extensional regime in the west) have moderate energy potential. Although the recently active volcanoes suggest the presence, at depth, of still cooling magma chambers that are potential heat sources, the lack of well-developed fault systems is probably responsible for the comparatively low energy potential of these regions. Almost all the thermal waters of Turkey are saturated with respect to calcite and, hence, have a significant calcite scaling potential which is particularly high for West Anatolian waters.     

Geochemical Monitoring of Geothermal Waters (2002–2004) along the North Anatolian Fault Zone, Turkey: Spatial and Temporal Variations and Relationship to Seismic Activity

A total of nine geothermal fields located along an 800-km long E-W transect of the North Anatolian Fault Zone (NAFZ), Turkey were monitored for three years (2002–2004 inclusive; 3-sampling periods per year) to investigate any possible relationship between seismic activity and temporal variations in the chemistry and isotope characteristics of waters in the fields. The geothermal fields monitored in the study were, from west to east, Yalova, Efteni, Bolu, Mudurnu, Seben, Kur?unlu-Çank?r?, Hamamözü, Gözlek and Re?adiye. The chemical (major anion-cation contents) and isotopic (¹⁸O/¹⁶O, D/H, ³H) compositions of hot and cold waters of the geothermal sites were determined in order to both characterize the chemical nature of the individual fields and identify possible temporal variations associated with localized seismic activity. The geothermal waters associated with the NAFZ are dominantly Na-HCO₃, whereas the cold waters are of the Ca-HCO₃ type. The oxygen- and hydrogen-isotope compositions reveal that the hot waters are meteoric in origin as are their cold water counterparts. However, the lower δ¹⁸O, δD and ³H contents of the hot waters point to the fact that they are older than the cold waters, and that their host aquifers are recharged from higher altitudes with virtually no input from recent (post-bomb) precipitation. Although no major earthquakes (e.g., with M ≥ 5) were recorded along the NAFZ during the course of the monitoring period, variations in the chemical and isotopic compositions of some waters were observed. Indeed, the timing of the chemical/isotopic changes seems to correlate with the occurrence of seismic activity of moderate magnitude (3 < M < 5) close to the sampling sites. In this respect, Cl, ³H and Ca seem to be the most sensitive tracers of seismically-induced crustal perturbations, and the Yalova and Efteni fields appear to be the key localities where the effects of seismic activity on the geothermal fluids are most pronounced over the monitoring period. The present study has produced a ‘baseline’ database for future studies directed at characterizing the effects of moderate-major earthquakes on the composition of geothermal waters along the NAFZ. Future work involving longer monitoring periods with more frequent sampling intervals should lead to a better understanding of the underlying mechanism(s) producing the observed chemical and isotopic variations.     

Factors controlling the morphological evolution of the Çanakkale Strait (Dardanelles, Turkey)

Seismic profiling, bathymetric and physical oceanographic data collected from the Çanakkale Strait revealed that the morphological evolution of the strait has been controlled by tectonic activity, and sediment erosion and deposition. Sediments in the strait have been sourced mostly by rivers draining the Biga Peninsula during lowstand periods. In highstand periods, by contrast, deposits in the strait were reworked by currents. The seafloor morphology of the Çanakkale Strait is also controlled by a sequence of factors ranging from tectonics to current erosion and deposition. Channel deposits overlying the basement are being eroded at the narrower, meandering central section of the strait (the Nara Passage) due to high current velocities. The eroded sediments are deposited in the relatively linear and wider, northern and southern sectors of the strait exposed to low current velocities. As a result, the high-energy areas are more deeply incised due to the erosion, whereas deposition elevates the seafloor in the areas exposed to lower current energy. Three strike-slip faults, which possibly relate to the activity of the North Anatolian Fault Zone, are responsible for the irregular shape of the strait and this, in turn, controls the current velocity along the strait. The high-energy conditions probably commenced with the latest invasion of Mediterranean waters some 12 ka b.p., and have continued as a two-layered current system to the present day.     

Faulting, mass-wasting and deposition in an active dextral shear zone, the Gulf of Saros and the NE Aegean Sea, NW Turkey

Structural, mass-wasting and sedimentation processes along an active dextral shear zone beneath the Gulf of Saros and the NE Aegean Sea were investigated on the basis of new high-resolution swath bathymetric data and multi-channel seismics. A long history of dextral shearing operating since the Pliocene culminated in the formation of a NE-SW-trending, ca. 800-m-deep basin (the so-called inner basin) in this region, which is bordered by a broad shelf along its northern and eastern sides and a narrow shelf at the southern side. The western extension of the North Anatolian Fault Zone (the Ganos Fault) cuts the eastern shelf along a narrow deformation zone, and ends sharply at the toe of the slope, where the strain is taken up by two NE-SW-oriented fault zones. These two fault zones cut the basin floor along its central axis and generate a new, Riedel-type pull-apart basin (the so-called inner depression). According to the bathymetric and seismic data, these basin boundary fault zones are very recent features. The northern boundary of the inner depression is a through-going fault comprising several NE-SW- and E-W-oriented, overlapping fault segments. The southern boundary fault zone, on the other hand, consists of spectacular en-echelon fault systems aligned in NE–SW and WNW–ESE directions. These en-echelon faults accommodate both dextral and vertical motions, thereby generating block rotations along their horizontal axis. As the basin margins retreat, the basin widens continuously by mass-wasting of the slopes of the inner basin. The mass-wasting, triggered by active tectonics, occurs by intense landsliding and channel erosion. The eroded material is transported into the deep basin, where it is deposited in a series of deep-sea fans and slumps. The high sedimentation rate is reflected in an over 1,500-m-thick basin fill which has accumulated in Pliocene–Quaternary times.     

A slope failure caused by drainage cutoff through the advancement of seasonal frost, Hudson Bay Lowland

A failure occurred between December 14 and 17, 2008 in the upper part of a 45-m high, northwest facing bank of the Nelson River in northern Manitoba (56.687°N, 93.777°W). The slope failure occurred at a spring site in a bay associated with a buried valley. The sediment input to the river from this event is roughly 20,000 to 25,000 m³. The source zone is made up of 25  m of water-bearing sand and gravel confined between ice-rich silty clay at the top of the bank and laminated to rhythmically bedded silt and clay at the base of the section. The collapse was confined to the material above the basal silts and clays and was associated with a perched groundwater flow system. A strong argument for drainage cutoff by the advancement of seasonal frost has been demonstrated through the correlation of the bank collapse with the timing of a significant cold snap recorded at two nearby weather stations. The failure illustrates the importance of stratigraphy in controlling bank erosion in this area. Previously, fluvial erosion was seen as an important control on mass wasting in Horseshoe Bay. However, surface information suggests that no toe erosion except to remove the slide deposit has occurred at this site since 2004.     

Identification of homogenous regions in Gorganrood basin (Iran) for the purpose of regionalization

Estimation of flood in basins with poor condition of hydrometric stations as in quantity and quality is a dominant problem around the world, mainly in developing country where lack of funds and human resources cause more limitation in number of gauging stations. One of the areas that experience frequent floods and also suffer from small number of stations in Iran is Gorganrood basin. So there is a great need for the estimation and prediction of runoff in this area to prevent any future floods. Due to insufficient station in this area, direct prediction of flood is not applicable. Regional flood frequency analysis is a practical and widely used solution for these situations, which involves the identification of homogenous regions. Gorganrood region was hydrologically homogenized according to the extracted parameters that influence the floods. One of these parameters was Normalized Difference Vegetation Index (NDVI) driven from MODIS images. Curvature is another parameter that relates to topographic attributes. From factor analysis, the most appropriate variables were selected. According to these parameters (NDVI, curvature, area, slope…), the regions were classified into homogenous regions. For the purpose of homogenization, hierarchical (wards) clustering, fuzzy clustering and Kohonen method were applied. L-moment technique was used for the investigation of the results. The heterogeneity measure for one of the groups (Group 1) was more than two; therefore some modifications were applied. The region was grouped into two homogenous subregions. All of the clustering methods showed same results. The models showed that class 4 of NDVI is influential on flood in some return periods. The resulted models can be applied in future studies in different aspects of practical hydrology.     

Investigation of heavy metal pollutants at various depths in the Gulf of Izmit

In this study, we report results concerning the accumulation of heavy metals in seawater from Izmit Bay. The bay was divided into the three parts: the eastern, the central and the western basins. The goal of this study was to determine levels of heavy metals at various depths in the bay between April 2008 and May 2010. Liquid–liquid extractions were performed on seawater samples. An atomic absorption spectrophotometer was used to measure levels of six metals: lead, cadmium, chromium, iron, manganese and zinc. We applied our results to evaluate the status of pollution in the Gulf of Izmit. Significant seasonal differences in metal concentrations and higher concentrations of many metals in water near the shore are evidence for uncontrolled release of pollutants in the water.     

Chemical geothermometry and fluid–mineral equilibria for the Ömer–Gecek thermal waters, Afyon area, Turkey

Thermal waters of the Ömer–Gecek geothermal field, Turkey, with temperatures ranging from 32 to 92°C vary in chemical composition and TDS contents. They are generally enriched in Na–Cl–HCO₃ and suggest deep water circulation. Silica and cation geothermometers applied to the Ömer–Gecek thermal waters yield reservoir temperatures of 75–155°C. The enthalpy–chloride mixing model, which approximates a reservoir temperature of 125°C for the Ömer–Gecek field, accounts for the diversity in the chemical composition and temperature of the waters by a combination of processes including boiling and conductive cooling of deep thermal water and mixing of the deep thermal water with cold water. It is also determined that the solubility of silica in most of the waters is controlled by the chalcedony phase. Equilibrium states of the Ömer–Gecek thermal waters studied by means of the Na–K–Mg triangular diagram, Na–K–Mg–Ca diagram, K–Mg–Ca geoindicator diagram, activity diagrams in the systems composed of Na₂O–CaO–K₂O–Al₂O₃–SiO₂–CO₂–H₂O phases, log SI diagrams, and finally the alteration mineralogy indicate that most of the spring and low-temperature well waters in the area can be classified as shallow or mixed waters which are likely to be equilibrated with calcite, chalcedony and kaolinite at predicted temperature ranges similar to those calculated from the chemical geothermometers. It was also observed that mineral equilibrium in the Ömer–Gecek waters is largely controlled by CO₂ concentrations.