Quantifying hydrogen‐deuterium exchange of meteoritic dicarboxylic acids during aqueous extraction

Abstract— Hydrogen isotope ratios of organic compounds in carbonaceous chondrites provide critical information about their origins and evolutionary history. However, because many of these compounds are obtained by aqueous extraction, the degree of hydrogen‐deuterium (H/D) exchange that occurs during the process needs to be quantitatively evaluated. This study uses compound‐specific hydrogen isotopic analysis to quantify the H/D exchange during aqueous extraction. Three common meteoritic dicarboxylic acids (succinic, glutaric, and 2‐methyl glutaric acids) were refluxed under conditions simulating the extraction process. Changes in δD values of the dicarboxylic acids were measured following the reflux experiments. A pseudo‐first order rate law was used to model the H/D exchange rates which were then used to calculate the isotope exchange resulting from aqueous extraction. The degree of H/D exchange varies as a result of differences in molecular structure, the alkalinity of the extraction solution and presence/absence of meteorite powder. However, our model indicates that succinic, glutaric, and 2‐methyl glutaric acids with a δD of 1800%***_o would experience isotope changes of 38_o, 10_o, and 6_o, respectively during the extraction process. Therefore, the overall change in δD values of the dicarboxylic acids during the aqueous extraction process is negligible. We also demonstrate that H/D exchange occurs on the chiral α‐carbon in 2‐methyl glutaric acid. The results suggest that the racemic mixture of 2‐methyl glutaric acid in the Tagish Lake meteorite could result from post‐synthesis aqueous alteration. The approach employed in this study can also be used to quantify H/D exchange for other important meteoritic compounds such as amino acids.     

Tidal effects on temperature front in the Yellow Sea

Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades in autumn as thermocline declines. TF intensity ⋎S _T ⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the TF. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).     

贵州织金煤矿区龙潭组岩石特征及其意义

织金矿区含煤地层为上二叠统龙潭组,含主要可采煤6层.煤系地层以含玄武岩屑、海绿石为特征的5类碎屑岩夹碳酸盐岩,水平、沙纹、波状层理发育,煤系中稳定的灰岩、硅铁质灰岩标志层较多,有利于煤层的划分与对比,并产丰富的动植物化石及碎块.属海、陆交替环境下的标型海陆交互相沉积.     

The influence of a non‐associated flow rule on the calculation of the factor of safety of soil slopes

This paper presents a method that incorporates a non‐associated flow rule into the limit analysis to investigate the influence of the dilatancy angle on the factor of safety for the slope stability analysis. The proposed method retain's the advantage of the upper bound method, which is simple and has no stress involvement in the calculation of the energy dissipation and the factor of safety. Copyright © 2001 John Wiley & Sons, Ltd.     

流动VLBI站氢原子钟的研制与性能测试

氢脉泽是射电天文所必需的频率标准.文中对为流动vLBI站研制的新一代氢脉泽的物理结构特点进行了讨论，包括对腔泡结构、磁屏蔽、原子束光学系统等.同时性能测试表明在80秒到1天之间频率稳定度优于1×10     

广西森林旅游资源的特色及其开发意义

广西森林旅游资源多达 816 .7万hm2 ,景点 2 80个 ,内容丰富 ,前景广阔 ,加强广西森林旅游资源特色的开发 ,有利于促进广西旅游业可持续发展 ,有利于经济、社会、环境效益的提高及人们的文化素质和生活质量的提高。     

沉积物粒度分析在厦门市第四纪环境研究和地层划分对比中的应用

采用MS2000型激光粒度分析仪进行测试，利用计算机粒度分析软件对数据进行整理和计算，绘制出样品的频率曲线、概率累积曲线以及粒度众数位值曲线等图件并进行沉积环境分析。厦门地区第四纪环境演化经历了中更新世同安组(含泥中粗砂、含泥细中砂、砂为主)海积一冲积一更新统上部龙海组(含泥粗中砂、含泥细中砂、含泥粗砂、粗砂、细中砂、含细砾中粗砂、中细砂等)冲积一洪冲积一更新世上部东山组(砂、砂砾、含泥中粗砂、粗砂、泥质中细砂、细砂、中粗砂等)冲洪积及部分海积(粉砂、细粉砂、含碳质泥、粘土、淤泥质粘土、粉砂质粘土等)一全新世长乐组(粉砂，淤泥质粘土、粉砂质粘土、碳质粘土、含砂淤泥质粘土，粉砂质亚粘土、粉细砂亚粘土等)海湾沉积。在解释环境变化的同时，说明粒度变化曲线在一定程度上可以作为地层划分的依据之一，并以此对研究区地层进行了详细划分。     

澳门附近海域沉积物污染状况及特征分析

掌握澳门附近海域沉积物的污染状况及特征,对于合理安排澳门海洋海岸工程疏浚泥的海洋倾倒,防止造成海洋污染有十分重要的意义。根据1997—1999年连续三年对澳门附近主要区域的海洋沉积物采样测定结果,通过分析认为澳门附近海域沉积物污染具有下列特征:1)沉积物中重金属和油类含量普遍较高,除了总Hg外均高于珠江口海区的其他港口;2)沉积物中污染物的分布受人类活动的影响明显,澳门内港受船只排污、码头作业、陆地工业和生活污水排放的影响,是澳门附近海域沉积物污染最为严重区域;3)受水质交换的影响明显,澳门外港、路环岛东北等区域受珠江径流影响水质交换较快,沉积物中污染物的含量较低,而内港由于水质交换较差,沉积物中污染物的含量相对较高;4)与沉积物的成分组成(吸附)有关,大部分污染物与沉积物中粉砂有较好的相关性,表明粉砂对污染物质有较广泛性的吸附能力,尤其是Cu、Zn、Cd、油类、有机质。     

菏泽市地质灾害现状与防治

菏泽市地质灾害类型主要为地震、地面塌陷、地面沉降、地裂缝、砂土液化、土地盐渍化及地氟病等，其发育与分布受地质构造、水文地质条件的控制以及气象、人类活动等因素的影响。就其分布、危害、致灾原因等做了分析，并提出了防治建议和对策。