基于PXRF的西南印度洋脊硫化物表层沉积物地球化学找矿研究

海底热液喷发形成的热液羽状流中富含成矿物质,并沉淀在距离热液喷口不等的范围内。对西南印度洋中脊热液喷口附近、距离喷口中等距离、远离喷口的六个表层沉积物样品开展了不同粒度沉积物的便携式XRF（PXRF）分析。结果表明,PXRF可以有效获得的洋中脊钙质沉积物中成矿元素的富集特征。>40目的沉积物样品具有较高的Cu、Zn、Fe、Mn等元素含量,40目以下沉积物中则相对稳定,可能与粗粒沉积物中玄武岩碎屑/玻璃含量较高有关,与镜下鉴定结果一致。以热液喷口为中心,表层沉积物中表现出Cu、Zn、As、Fe、Mn的元素分带,靠近喷口的沉积物中具有较高的成矿元素的含量,并具有较高的Cu/Fe、Zn/Fe比值或者Cu/Mn与Zn/Mn比值。上述结论表明,洋中脊沉积物中成矿元素的含量主要受与喷口的距离的影响,而与粒度的关系不大,洋中脊沉积物地球化学找矿应采用40目以下粒径沉积物作为分析样品。通过PXRF获得的Cu、Zn、As、Fe、Mn等元素含量及其比值特征可以作为海底多金属硫化物沉积物地球化学找矿的指标,该方法满足快速有效识别洋中脊沉积物中地球化学异常的要求。     

中国对推进非洲海洋领域能力建设的进展情况分析及发展建议

非洲同中国具有传统友谊,中非之间海洋合作是中非合作大框架的新内容,是促进世界和平格局与应对全球海洋灾害的必然选择。文章从非洲国家对海洋能力建设的需求入手,分析了其海洋科技基础和面临的挑战,回顾了中国与非洲国家间的海洋合作与对非援助情况,提出了对推进非洲海洋能力建设的建议,认为在"一带一路"建设中,通过充分有效利用中非海洋科技论坛机制、培养非洲海洋科技人才、开展联合调查等几个方面的努力,将能较快速地提升非洲沿海国家的海洋建设能力,从而促进非洲沿海国家的可持续发展,进一步推动中非海洋科技合作。     

Principal stress rotation and cyclic shear strength for an elliptical rotation stress path

Based on the analytical solutions for wave-induced soil response in an unsaturated anisotropic seabed of finite thickness, an elliptical, i.e., noncircular rotation stress path is proven to be a more common state in a soil element with the cyclic shear stresses due to the traveling linear wave. The influence of an elliptical stress path on the characterization of failure strength is analyzed using three new parameters representing the shape, size, and the orientation of the ellipse. A series of cyclic rotational shear tests on the reconstituted specimens of Chinese Fujian Standard Sand have been performed to investigate the effect of elliptical stress path. A strength function in term of failure cycles is derived to quantify the failure strength of a given sand within a seabed subjected to regular wave loading. The results provide a basis for the evaluation of liquefaction potential of seabed but also point to a unique backbone cycle shear strength curve for soil under principal stress rotation.     

九龙江河口区微生物多样性及群落结构的时空分布

河口区由于其独特的地理环境和理化条件,拥有丰富的微生物资源,在生物地球化学循环中起着重要作用.然而,由于人类活动带来的河口区环境因素改变,引起的微生物群落结构的时空变化目前还知之甚少.本研究选取九龙江河口区7个近年来遭受较为严重人类活动干扰的采样点,分别在丰水期和枯水期采集表层水体,采用流动注射法测定了水体的三氮、电导率、pH值和溶解性磷酸盐等环境参数,采用海水和淡水培养基,基于纯培养技术分析了可培养细菌的总数和分布特征,并通过构建16S rRNA基因克隆文库的方法研究细菌的多样性和群落结构变化.研究表明,变形菌门(Proteobacteria)、放线菌门(Actinobacteria)和拟杆菌门(Bacteroidetes)是各克隆文库中最优势的类群.在河口下游海水区,变形菌门微生物与放线菌门微生物的比例约为2∶1~3∶1,而在河口上游淡水区,变形菌门和放线菌门的比例约为1∶1.在河口下游海水区,α变形菌纲(Alphaproteobacteria)为变形菌门中的优势类群,而在河口上游淡水区,β变形菌纲(Betaproteobacteria)为优势类群.厚壁菌门(Firmicutes)是克隆文库中丰度占第四的类群,说明水体可能遭受畜牧养殖粪便污染.本研究表明,九龙江河口区微生物群落结构受水体盐度、温度、水文情况等时空因子及人类活动造成的营养物浓度上升、动物粪便污染等共同影响,呈现出独特的时空分布特点.     

Removal rate and releases of polybrominated diphenyl ethers in two wastewater treatment plants,Korea

Wastewater treatment plants (WWTPs) play an important role in minimizing the release of many pollutants into the environment. Nineteen congeners in two WWTPs in Korea were determined to investigate the occurrence and fate of polybrominated diphenyl ethers (PBDEs) during wastewater treatment processes. The concentration of total PBDEs was 69.6 and 183 ng/L in influent, which declined to 1.59 and 2.34 ng/L in the final effluent, respectively (Tongyeong and Jinhae WWTPs). PBDEs were found to exist mostly in the particulate phase of wastewater, which rendered sedimentation efficient for the removal of PBDEs. BDE-209 was the predominant congener in the influent and sludge. Most of the PBDEs entering the WWTPs presumably ended up in the sludge, with < 2% being discharged with the final effluent. According to the mass loading estimation, every day 2.55–9.29 g PBDEs entered the two WWTPs, 2.8–10.4 g were disposed to landfill sites in sludge form and 0.06–0.12 g were discharged to the surrounding water through final effluent, respectively. Preliminary results indicated that the ecological risk to organisms in soil exposed to PBDEs through the usage of sludge application to agricultural land was relatively low. To our knowledge, this study is the first to report on the removal efficiency of PBDEs in a WWTP in Korea.     

Effect of Ca(OH)2, NaCl,and Na2SO4 on the corrosion and electrochemical behavior of rebar

The corrosion of rebar in reinforced concrete in marine environments causes significant damage to structures built in ocean environments. Studies on the process and mechanism of corrosion of rebar in the presence of multiple ions may help to control damage and predict the service life of reinforced concrete structures in such environments. The effect of interactions between sulfate and chloride ions and calcium hydroxide on the electrochemical behavior of rebar are also important for evaluation of structure durability. In this work, electrochemical impedance spectroscopy(EIS) plots of rebar in Ca(OH)_2 solution and cement grout, including NaCl and Na_2SO_4 as aggressive salts, were measured for different immersion times. The results show that corrosion of rebar was controlled by the rate of charge transfer as the rebar was exposed to chloride solution. In the presence of high concentrations of sulfate ions in the electrolyte, generation and dissolution of the passive film proceeded simultaneously and corrosion was mainly controlled by the diffusion rate. When Na_2SO_4 and NaCl were added to Ca(OH)_2 solution, the instantaneous corrosion rate decreased by a factor of 10 to 20 as a result of the higher p H of the corroding solution.     

牛背梁自然保护区林线不同海拔巴山冷杉径向生长对气候变化的响应

近年来气候变化对秦岭植被的影响已得到众多研究的证实,牛背梁作为秦岭东部主脊和国家级自然保护区,该地区亚高山林线植被对气候变化的生态响应现状尚未得到广泛关注。依照树木年代学原理,进行响应分析并建立回归模型,探讨了牛背梁林线关键树种巴山冷杉（Abies fargesii）年表特征及对气候响应的海拔分异特征。结果表明：（1）随海拔升高,树木生长对气候的敏感性逐渐上升,但轮宽年表的同步性和信号强度呈先下降后上升的特点。（2）不同海拔树轮宽度年表的气候响应结果基本一致,对气温的敏感性均较降水强,敏感时段为当年2～8月,差异主要体现在,高海拔树木受生长季末期8月气温的影响较重,中海拔树木受生长季前期3～4月降水和上年冬季10～11月气温的促进,而低海拔树木受初春1～2月降水的限制作用明显。（3）对比分析低、中、高海拔3个回归模型中显著因子的变化趋势,发现气候变化可以促进巴山冷杉生长季的提前,但不同海拔树木的生长动态各异,说明研究区林线不同海拔巴山冷杉生长对全球变化可能具有不同的响应机制。     

中晚全新世毛乌素沙地东南部气候变化过程

位于中国北方半干旱区的毛乌素沙地对气候变化响应敏感,是研究气候变化的理想区域。通过对毛乌素沙地东南部锦界剖面磁化率、有机质含量、CaCO₃含量的分析,重建了7.5 ka BP以来的气候变化过程。结果显示：中晚全新世毛乌素沙地东南部环境与气候变化可分为3个阶段：7.5～4.6 ka BP,夏季风占主导,气候暖湿,与全新世大暖期对应;4.6～3.3 ka BP,气候突变为干冷并波动频繁;3.3～2.5 ka BP气候以干冷为主。另外,存在5次千年尺度的干旱事件：7.0～6.8 ka BP、6.6～5.7 ka BP、4.6～4.1 ka BP、3.7～3.5 ka BP、3.3～2.5 ka BP。研究区气候变化与全球具有较好的一致性。     

小冰期福建海岸沙丘的沉积环境

选取福建东南沿海典型海岸沙丘——东海沙丘,运用GPR（Ground Penetrating Radar）技术探测海岸沙丘内部构造,辅助天然剖面和人工探槽观测,进行系统的年代采样与OSL（Optically Stimulated Luminescence）测年,并选择物理意义明确的粒度参数作为主要环境代用指标,获得了亚热带季风区砂质海岸带典型海岸沙丘的沉积年代和沉积结构。结果表明：（1）东海沙丘是由若干灌丛沙丘组成的横向沙丘,0～6 m主要是～0.45 ka BP以来形成的海岸风成沙丘,可以划分为～0.45 ka BP和0.22～0.12 ka BP两个阶段。（2）东海沙丘沉积过程是多因素共同作用的结果,冷干的气候环境是沙丘发育的适宜条件,入境台风频率增加可能加快了风沙的沉积过程。对比历史文献资料发现,气候异常期往往与社会动荡期、重要历史事件相对应。     

Evaluation of diffuse and preferential flow pathways of infiltrated precipitation and irrigation using oxygen and hydrogen isotopes

Subsurface-water flow pathways in three different land-use areas (non-irrigated grassland, poplar forest, and irrigated arable land) in the central North China Plain were investigated using oxygen (¹⁸O) and hydrogen (²H) isotopes in samples of precipitation, soils, and groundwater. Soil water in the top 10 cm was significantly affected by both evaporation and infiltration. Water at 10–40 cm depth in the grassland and arable land, and 10–60 cm in poplar forest, showed a relatively short residence time, as a substantial proportion of antecedent soil water was mixed with a 92-mm storm infiltration event, whereas below those depths (down to 150 cm), depleted δ¹⁸O spikes suggested that some storm water bypassed the shallow soil layers. Significant differences, in soil-water content and δ¹⁸O values, within a small area, suggested that the proportion of immobile soil water and water flowing in subsurface pathways varies depending on local vegetation cover, soil characteristics and irrigation applications. Soil-water δ¹⁸O values revealed that preferential flow and diffuse flow coexist. Preferential flow was active within the root zone, independent of antecedent soil-water content, in both poplar forest and arable land, whereas diffuse flow was observed in grassland. The depleted δ¹⁸O spikes at 20–50 cm depth in the arable land suggested the infiltration of irrigation water during the dry season. Temporal isotopic variations in precipitation were subdued in the shallow groundwater, suggesting more complete mixing of different input waters in the unsaturated zone before reaching the shallow groundwater.