Chemical aspects of iron oxide coagulation in water: Laboratory studies and implications for natural systems

Initial coagulation rates of colloidal hematite (-Fe₂O₃) particles (diameter less than 0.1 µm) were measured experimentally in well-defined laboratory systems at constant temperature. The relative stability ratio,W, was obtained at various ionic strengths in NaCl medium and at pH values in the range from 3 to 12. ExperimentalW values ranged from 1 to 10⁴ in various systems. The results delineate the roles ofspecific andgeneralized coagulation mechanisms for iron oxides. Among the specifically-interacting species (G _ads ⁰ >G _coul ⁰ ) studied were phosphate, monomeric organic acids of various structures, and polymeric organic acids. The critical coagulation-restabilization concentrations of specifically-interacting anions (from 10^–7 to 10^–4 molar) can be compared with the general effects of non-specific electrolyte coagulants (10^–3 to 10^–1 molar). The laboratory results are interpreted with the help of a Surface Complex Formation/Diffuse Layer Model (SCF/DLM) which describes variations of interfacial charge and potential resulting from variations of coagulating species in solution. Comparison of these laboratory experiments with observations on iron behavior in estuarine and lake waters aids in understanding iron removal mechanisms and coagulation time scales in natural systems.     

中山市绿色生态小区规划建设研究

在深入解析绿色生态小区实质内涵的基础上，综合评述了中山市绿色生态小区建设在概念理解、小区景观建设、住宅建设经济性及和谐统一等方面存在的主要问题，结合中山近年城市建设发展情况，从提高城市竞争力、提升城市品位和促进“两个适宜”城市发展目标的实现等方面具体分析了中山绿色生态小区建设的实践意义。最后从做好宣传、提高市民意识、推动实施政策等方面提出今后中山绿色生态小区发展之建议，以期促进中山城市的良性运作和健康发展。     

An experimental study of anorthosite dissolution in lunar picritic magmas: Implications for crustal assimilation processes

Experiments characterizing the kinetics of anorthosite dissolution in lunar picritic magmas (very low-Ti, low-Ti, and high-Ti picritic glasses) were conducted at 0.6 GPa and 1250-1400 °C using the dissolution couple method. Reaction between the anorthosite and lunar picritic magmas at 1250-1300 °C produced a spinel + melt layer. Reaction between the anorthosite and an olivine-saturated low-Ti magma at 1250-1300 °C produced a crystal-free region between the spinel + melt layer and the olivine-saturated magma. The anorthosite dissolution experiments conducted at 1400 °C simply dissolved anorthosite and did not result in a crystal-bearing region. The rate of anorthosite dissolution strongly depends on temperature and composition of the reacting melt. Concentration profiles that develop during anorthosite dissolution are nonlinear and extend from the picritic glass compositions to anorthite. These profiles feature a large and continuous variation in melt density and viscosity from the anorthosite-melt interface to the initial picritic magmas. In both the low-Ti and high-Ti magmas the diffusive fluxes of TiO₂, Al₂O₃, and SiO₂ are strongly coupled to the concentration gradients of CaO and FeO. Anorthosite dissolution may play an important role in producing the chemical variability of the lunar picritic magmas, the origin of spinel in the lunar basalts and picritic glasses, and the petrogenesis of the high-Al basalts.     

下庄铀矿田337矿床成矿流体稀土元素示踪

337铀矿床位于下庄矿田东缘,区内发育近EW向、NNE向构造裂隙群及NW向辉绿岩和正长岩脉体,发育以碱性为主的多种围岩蚀变。区内矿床主要赋矿围岩的稀土元素特征属壳源型。矿石内金属矿物以沥青铀矿为主,矿石的LREE/HREE比值为3.25,Sm/Nd比值平均为0.307,Ce/Yb比值为7.127,这些数据都显示出成矿流体具有较深来源。矿石较围岩亏损稀土元素尤其是轻稀土元素,稀土元素分布模式平缓,与幔源辉绿岩特别是与正长岩的稀土元素分布模式相近,负铕异常比围岩更为强烈,反映成矿流体的来源具有幔源性。结合区域地质特征,可以认为337矿床成矿流体来源具有幔源性质。     

Zircon LA-ICP-MS U-Pb age, Ce^4＋/Ce^3＋ ratios and the geochemical features of the Machangqing complex associated with copper deposit

1IntroductionQuite a number of porphyry copper deposits havebeen found in the Cenozoic alkali-intrusions along theJinshajiang-Ailaoshan-Red River fault zone,whichconstitute the Cenozoic ore belt in China.The Cenozo-ic alkali-intrusive rocks are similar in…     

用BP神经网络预测土抗剪强度指标c、ψ

提出了应用BP神经网络来预测土抗剪强度指标c、ψ.结合工程实例,详细介绍了该方法的建模过程,结果表明预测结果和实测结果很接近,神经网络在土性参数方面应用前景很广阔.     

VSP资料约束地层反滤波研究

浅地表的低速带和地层滤波作用导致地震信号的能量衰减,地震子波的高频快速衰减,速度频散的子波变形,对地震底层分析带来了严重的影响。地层反滤波算法就是为了消除地层对子波的影响,利用VSP中的直达下行波推算出每个地层滤波算子,计算出各个地层滤波算子的反算子,然后利用这些反算子恢复出地表记录中损失掉的高频成分,减弱地层滤波对波形的影响,增加地表记录的频率成分和波形的准确度。分析实际地震资料表明,经过地层反滤波处理后的记录频率成分明显提升,地质构造更加准确、清晰。     

检波器尾锥与地表耦合阻尼研究

结合检波器与松散地表耦合的实际,设计了双自由度耦合模型,从理论上分析了检波器与地表耦合系统的特性,并结合野外实验定性地分析了在不同表土情况下,检波器尾锥与地表耦合系统中尾锥与地表之间的阻尼变化时对耦合系统特性及地震资料的影响,揭示了合理的选择检波器尾锥与地表之间的阻尼在地震信号采集中的意义。     

深层地震勘探激发井深探讨

深层地震勘探野外资料采集的关键是在保证原始资料一定信噪比的基础上,同时兼顾分辨率,激发井深是决定资料品质的重要因素之一。通过对虚反射滤波作用分析,提出了充分利用虚反射能量设计最佳激发井深,增强下传地震波能量的采集方法。理论分析和试验资料表明,在高速层下4～7m的最佳激发岩性深度是深层勘探的理想井深。     

一种基于梯度信息的小波SAR图像滤波方法

提出一种基于梯度的自适应小波滤波方法.这种算法利用梯度和纹理信息控制阈值的选取,使滤波器在平坦区域能够有效去除噪声、在边缘区域有效保持边缘.应用于SAR图像斑点噪声滤波,并与增强Lee,Frost滤波,Gamma MAP滤波和Kuan滤波几种算法的结果进行比较分析,表明这种算法不仅能有效去除斑点噪声还能很好地保持图像的边缘等细节信息.