Geochemical processes controlling arsenic mobility in groundwater: A case study of arsenic mobilization and natural attenuation

The behavior of As in the subsurface environment was examined along a transect of groundwater monitoring wells at a Superfund site, where enhanced reductive dechlorination (ERD) is being used for the remediation of groundwater contaminated with chlorinated solvents. The transect was installed parallel to the groundwater flow direction through the treatment area. The ERD technology involves the injection of organic C (OC) to stimulate in situ microbial dechlorination processes. A secondary effect of the ERD treatment at this site, however, is the mobilization of As, as well as Fe and Mn. The concentrations of these elements are low in groundwater collected upgradient of the ERD treatment area, indicating that, in the absence of the injected OC, the As that occurs naturally in the sediment is relatively immobile. Batch experiments conducted using sediments from the site inoculated with an Fe(III)- and As(V)-reducing bacterium and amended with lactate resulted in mobilization of As, Fe and Mn, suggesting that As mobilization in the field is due to microbial processes.     

A kinetic approach to describe trace-element distribution between particles and solution in natural aquatic systems

The partitioning of radioactive trace elements between seawater and particulate matter from surface sediments and sediment traps was investigated in laboratory experiments. For the elements Na, Zn, Se, Sr, Cd, Sn, Sb, Cs, Ba, Hg, Th and Pa (group I) constant distribution coefficients (K_d) were found after a few days of equilibration, whereas the elements Be, Mn, Co and Fe (group II) showed an increasing K_d over the whole time of observation of 108 days. The time dependence of K_d is described by an adsorption-desorption equilibrium (group I elements), followed by a lattice transport reaction step (group II elements). The reaction rate constants are compared to Mn oxidation rates and to adsorption rate constants derived from in situ measurements of the $\text{U}\text{Th}$ disequilibrium as available from literature.     

OBSERVATIONS ON THE HINTEREIS AND VERNAGTFERNER

Abstract

Adequate water resources management at the basin level needs quality downscaling of climate change scenarios for application to impact assessment and adaptation work. This study evaluates the ability of a regional climate model (RegCM3) to simulate the present-day climate and regional water balance over the Niger River Basin (NRB). RegCM3 gives a good simulation of the NRB hydroclimatic features. The mean bias error for monthly temperature is 1.5°C, 0.3 mm d^-1 for rainfall, and 0.4 mm d^-1 for runoff. Moderate to high correlations (0.66–0.95) were found between the modelled and the observed variables. RegCM3-based water cycling indices were not statistically different from the observation. Seasonal moistening efficiency (m) ranges between 19% and 37%; 66% of the available atmospheric moisture over NRB precipitates between June and September, of which 21% originates from local evaporation. The result suggests that the moisture sink period is July to October with very high precipitation efficiency over the basin. The model reproduces the hydroclimatology of the NRB and hence is a suitable tool for further studies relating to the assessment of climate change impacts on river basin water systems.

Editor Z. W. Kundzewicz; Associate editor D. Hughes     

A DEVICE FOR MEASURING GULLY HEADWALL MORPHOLOGY

This paper describes a low-cost device for measuring the three-dimensional morphology of a gully headwall. The device was designed to operate in a gully system with the following characteristics: overhanging banks caused by a thick, dense root mat; retreat of the underlying unconsolidated sediments through small slab failures, leading to a considerable variation in retreat rate at each point on the headwall; and changes in the orientation of the headwall owing to changes in sediment properties and the topographical and hydrological controls of gully growth. The device is used to measure a series of closely spaced vertical profiles of the headwall, and the collected data are combined to draw a contour map showing the distance from the plane of the instrument to the headwall. Comparing maps for sequential times enables retreat rates for the diffferent proportions of the headwall to be quantified.     

Spatially explicit measures of production of young alewives in Lake Michigan: Linkage between essential fish habitat and recruitment

The identification and protection of essential habitats for early life stages of fishes are necessary to sustain fish stocks. Essential fish habitat for early life stages may be defined as areas where fish densities, growth, survival, or production rates are relatively high. To identify critical habitats for young-of-year (YOY) alewives (Alosa pseud oharengus) in Lake Michigan, we integrated bioenergetics models with GIS (Geographic Information Systems) to generate spatially explicit estimates of potential population production (an index of habitat quality). These estimates were based upon YOY alewife bioenergetic growth rate potential and their salmonine predators’ consumptive demand. We compared estimates of potential population production to YOY alewife yield (an index of habitat importance). Our analysis suggested that during 1994–1995, YOY alewife habitat quality and yield varied widely throughout Lake Michigan. Spatial patterns of alewife yield were not significantly correlated to habitat quality. Various mechanisms (e.g., predator migrations, lake circulation patterns, alternative strategies) may preclude YOY alewives from concentrating in areas of high habitat quality in Lake Michigan.     

A PRELIMINARY STUDY ON THE CHEMICAL AND MINERALOGICAL COMPOSITION OF LOESS.

In general, geologically speaking, it has been noted that if the formation of coal took place during the Permo-Carboniferous period, its volatile matter will al ways be less than 30％ when analized, and the contrary is usually the case for coal created during the Tertiary and Jurassic, these having more than 40％.     

A PETROGRAPHICAL STUDY OF THE CHINESE AGALMATOLITES

Ⅰ. INTRODUCTION. The most popular Chinese agalmatolites are Shoushanshih (壽山石), Changhuashih (昌化石), Chingtienshih (青田石) and Kwanglushih (廣綠石). They are named after the names of places, as the name Shoushanshih is from     

Photogrammetric Capabilities of the Kodak DC40, DCS420 and DCS460 Digital Cameras

The aim of this study is to assess the impact of sensor size and resolution of different digital camera sensors upon the accuracy and precision of three dimensional data derived by photogrammetry. Kodak DC40, DCS420 and DCS460 digital cameras were used to produce digital images of retroreflective targets in a 4 m three dimensional test field. The image locations of the targeted points were automatically measured using an off the shelf image processing software package. Two different sub-pixel measurement approaches were examined: centre of gravity and weighted mean. From the automated sub-pixel measurement of the targeted points, results indicate that the high resolution DCS460 camera produces optimum results using either the weighted mean or centre of gravity approaches. Although this was perhaps expected, the far lower resolution DC40 camera performed better than was originally anticipated, suggesting potential for the cheaper DC40 for many applications.     

Reconnaissance de la structure géologique du bassin de saïss occidental, Maroc, par sondages électriques

A geophysical study, based on 96 electrical resistivity measurements with a line length up to 4 km, was performed in the southern and southwestern parts of the Meknes Plateau, Morocco, which is a part of the Saiss Basin, located between the Rif Range to the north and the Middle Atlas Range to the south. This basin, whose maximum depth is 1.5km in the north, is filled with Triassic to Quaternary deposits overlying the Palæozoic basement and includes two main aquifers. The interpretation of the resistivity measurements, calibrated from deep boreholes, made it possible to obtain a new hydrogeological model for the Saiss Basin. The understanding of the basin structure is of primary importance for the water supply of this area, which has been affected by severe droughts in recent years.