Seasonal and spatial variation in abundance and egg production of Paracalanus parvus (Copepoda: Calanoida) in/out Jiaozhou Bay, China

The spatial distribution of stage-specific abundance and reproduction of the copepod Paracalanus parvus were studied from October 2005 to September 2006 in the Jiaozhou Bay. This copepod occurred continuously in this bay throughout the year. The species reached the lowest abundance in April and peaked in June. From October to December, distribution center mainly occurred in offshore water and at the mouth of the bay. In winter, early copepodites and adults gradually decreased and till February, most of the population was only comprised of CIV–CV stages. Overwintering copepodites matured in March and males tended to mature before female. From May to September, each stage occurred in the population and gradually reached high abundance. Temperature and chlorophyll a (Chl-a) concentration in the three stations can't clearly explain the seasonal variation in stage-specific abundance, so we surmised the important effect of the Yellow Sea. Egg production rate (EPR) reached its lowest in winter and peaked in June at 60.8 eggs female⁻¹ day⁻¹ in nearshore water. In the warming period, EPR in nearshore water was statistically higher and EPR > 10 eggs female⁻¹ day⁻¹ lasted longer than that in offshore water, showing the importance of nearshore water for recruitment of P. parvus. Our study showed that EPR was positively related to temperature and total chlorophyll a in offshore water and mouth of the bay. In nearshore water, the relationships between EPR and temperature and Chl-a in three size fractions were not the same as those in offshore water, suggesting complicated ecosystem in such a eutrophic area in warming period.     

Chlorinated hydrocarbons in seawater: Analytical method and levels in the northeastern Pacific

A method is described for analyzing nanogram quantities of chlorinated hydrocarbons from 1-1 samples of seawater. Seawater samples are pumped through a copper column containing a mixture by weight of 5% activated carbon powder, 10% MgO and 85% refined diatomaceous earth. The chlorinated hydrocarbons in the seawater are adsorbed or trapped on the column and subsequently eluted with 30% benzene in acetone (v/v) for analysis by gas-liquid chromatography.This procedure was used to analyze chlorinated hydrocarbon levels in samples collected off the southern California coast. We suggest that anthropogenic chlorinated hydrocarbons can be used for the investigation of large-scale ocean currents and mixing processes.     

A literature review of the saturation state of seawater with respect to calcium carbonate and its possible significance for scale formation on OTEC heat exchangers

An investigation has been made of available data on the saturation state of seawater with respect to calcium carbonate and its possible significance for scale formation on Ocean Thermal Energy Conversion (OTEC) heat exchangers. Pertinent oceanographic data is lacking at or near potential OTEC sites for the calculation of the degree of saturation of seawater with respect to calcium carbonate. Consequently, only “extrapolated” saturation values can be used. These indicate that near surface seawater is probably supersaturated, with respect to the calcium carbonate phases calcite and aragonite, at all potential OTEC sites. The deep seawater that would be brought to the surface at the potential Atlantic Ocean sites is also likely to be supersaturated with respect to calcium carbonate. The deep seawater at the potential Pacific Ocean sites may be slightly undersaturated.The fact that OTEC heat exchangers will be operating in seawater, which is supersaturated with respect to calcium carbonate, means that if nucleation of calcite or aragonite occurs on the heat exchanger surfaces, significant growth rates of calcium carbonate scale may be expected. The potential for calcium carbonate nucleation is highest at cathodic metal surface locations, which are produced as the result of aluminum corrosion in seawater. Consequently, corrosion and scale formation may be closely related. What the possible effects of biofouling may be on this process are not known.     

Solubility of hydrous ferric oxide and iron speciation in seawater

Iron solubility equilibria were investigated in seawater at 36.22‰ salinity and 25°C using several filtration and dialysis techniques. In simple filtration experiments with 0.05 μm filters and Millipore ultra-filters, ferric chlorides fluorides, sulfates, and FeOH²⁺ species were found to be insignificant relative to Fe(OH)₂⁺ at p[H⁺] = ?log [H⁺] greater than 6.0. Hydrous ferric oxide freshly precipitated from seawater yielded a solubility product of ${}^1\text{K}{}_{\mathrm{<mtext>so</mtext>}}\text{=}\text{[Fe}{}^{\mathrm{3+}}\text{][H}{}^{\mathrm{+}}\text{]}{}^{\mathrm{?3}}\text{= 4.7 · 10}{}^5$. Solubility studies based on the rates of dialysis of various seawater solutions and on the filtration of acidified seawater solutions indicated the existence of the Fe(OH)₃⁰ species. The formation constant for this species can be calculated as ${}^1\text{β}{}_3\text{=}\text{[Fe(OH)}{}_3{}^0\text{] [H}{}^{\mathrm{+}}\text{]}{}^3\text{/[Fe}{}^{\mathrm{3+}}\text{] = 2.4 · 10}{}^{\mathrm{?14}}$. The Fe(OH)₄^? species is present at concentrations which are negligible compared to Fe(OH)₂⁺ and Fe(OH)₃⁰ in the normal pH range of seawater. However, there is at least one other significant ferric complex in seawater above p[H⁺] = 8.0 (possibly with bicarbonate, carbonate, or borate ions) in addition to the Fe(OH)₂⁺ and Fe(OH)₃⁰ species.     

Deformations and Manifestations of Degassing in the Sedimentary Cover of the Equatorial Segment of the West Atlantic: Implications for Lithospheric Geodynamics

Manifestations of fluids and deformations in the sedimentary cover, which are both factors of brightening (blanking anomalies) in seismoacoustic records, in the equatorial segment of the Atlantic coincide with the sublatitudinal zones of the activated passive parts of transform faults and with zones of lower gravity anomalies and higher values of remnant magnetization, which form as a result of serpentinization. The cause-and-effect sequence of intraplate phenomena includes: the contrasting geodynamic state → horizontal movements that form macrofractures → water supply to the upper mantle → serpentinization of rocks in the upper mantle → deformations associated with vertical uplift of basement and sedimentary cover blocks, coupled with fluid generation → and fluid accumulation in the sedimentary cover, accompanied by the formation of anomalies in seismoacoustic records. Based on the seismic data, we have identified imbricate-thrust deformations, diapir structures, stamp folds, and positive and negative flower structures, indicating the presence of strike-slip faults in the passive parts of transform faults. The general spatial distribution of deformation structures shows their concentration in cold mantle zones. Correlative comparison of the structural characteristics of deformations shows the direct relationship between the heights of structures and the development of serpentinization processes. As per the age of the basement, deformations range from 27–38 to 43–53 Ma; a quite thick sedimentary cover makes it possible to reveal them based on the characteristic types of seismoacoustic records. The formation of the Antilles arc ca. 10 Ma ago affected the equatorial segment of the Atlantic; it formed kink bands where lithospheric blocks underwent displacements with counterclockwise rotations, deformations related to compression and vertical uplift of crustal fragments, and local extension that favored degassing of endogenous fluids. Sublatitudinally oriented imbricate-thrust deformations with different vergences indicate irregularity and alternating strike-slip directions as blocks between fractures were laterally influenced.     

Nonlinear dynamics of gravity flows in sloping channels

Doklady Earth Sciences -     

Enhanced geochemical gradients in a marine shallow-water hydrothermal system: Unusual arsenic speciation in horizontal and vertical pore water profiles

The shallow marine hydrothermal vents near Ambitle Island in eastern Papua New Guinea discharge hot, slightly acidic, As-rich, chemically reduced fluid into cool, slightly alkaline, oxygenated seawater. Gradients in temperature, pH, and total As (As^T), among others, are established as the two aqueous phases mix. The hydrothermal fluid contained 900 μg/L As^T, almost exclusively present as the reduced As^III, while local seawater measured between 1.2 and 2.4 μg/L As, with approximately equal levels of As^III and As^V. Of particular interest in this study was As speciation and abundance in pore waters as a function of sediment depth and as a function of distance from the area of focused venting. With increasing distance, As^T concentration in the pore water decreased rapidly, but remained elevated up to 300 m from the area of focused venting when compared to a non-hydrothermal control site. As a function of depth (to 100 cm) As^T concentration in the pore water profiles was elevated and generally increased with depth. Surprisingly, aqueous As^V far exceeded aqueous As^III at almost all distances and depths investigated, while at the control site the As^III concentration exceeded that of As^V. In the Tutum Bay hydrothermal system, chemical disequilibria among As species provide potential metabolic energy for arsenite oxidizing microorganisms where hydrothermal fluid mixes with seawater near the vent orifice, and for arsenate reducing microorganisms with increasing distance and depth from the hydrothermal point source.