Assessment of Raman spectroscopy as a tool for the non-destructive identification of organic minerals and biomolecules for Mars studies

Several characteristic geological features found on the surface of Mars by planetary rovers suggest that a possible extinct biosphere could exist based on similar sources of energy as occurred on Earth. For this reason, analytical instrumental protocols for the detection of biomarkers in suitable geological matrices unequivocally have to be elaborated for future unmanned explorations including the forthcoming ESA ExoMars mission. As part of the Pasteur suite of analytical instrumentation on ExoMars, the Raman/LIBS instrument will seek elemental and molecular information about geological, biological and biogeological markers in the Martian record. A key series of experiments on terrestrial Mars analogues, of which this paper addresses a particularly important series of compounds, is required to obtain the Raman spectra of key molecules and crystals, which are characteristic for each biomarker. Here, we present Raman spectra of several examples of organic compounds which have been recorded non-destructively—higher n-alkanes, polycyclic aromatic hydrocarbons, carotenoids, salts of organic acids, pure crystalline terpenes as well as oxygen-containing organic compounds. In addition, the lower limit of β-carotene detection in sulphate matrices using Raman microspectroscopy was estimated.     

Pediment response to drainage basin evolution in south-central Arizona

The Sonoran Desert portion of the Basin and Range physiographic province contains a number of streams that now flow across once-closed basins. We explore here the research questions of if and how granitic rock pediments respond to the transition from rimming endorheic basins to bordering through-flowing streams. Granitic rock pediments of the northern Usery and eastern McDowell Mountains once graded to the closed Miocene–Pliocene Pemberton basin that occupied the present-day location of the confluence of the Salt and Verde Rivers. The process of lake overflow, which integrated these rivers, first aggraded fill terraces that, in turn, caused aggradation of a mantle of transported grus on bedrock pediments. Subsequent episodic incision of the Salt and Verde rivers lowered the base level; this led to the development of erosional features such as rolling topography of a degrading pediment mantle; exposure of the former piedmont angle and its associated zones of enhanced bedrock decay and regolith carbonate; and exposure of spheroidally weathered bedrock and emerging tors, some of which experienced 20^th century erosion. The granitic pediments of the former Pemberton Basin, which now transport grus to the Salt and Verde rivers, have actively adjusted to aggradational and degradational events associated with drainage integration and do not appear to be inherited from an ancient wet climatic interval.     

An example of type IV minute scale pulsations and the standing magnetoacoustic wave model

An example of m-Dm solar radio pulsations consisting of a mixture of different minute scale periodic components is discussed. The ratios of the observed periods are independent on the observing frequency. They can be reproduced by the pulsation model of standing magnetoacoustic waves in coronal flux tubes driven by trapped protons.     

Richtmyer-Meshkov Experiments on the Omega Laser

Observations of the interstellar medium reveal a dynamic realm permeated by shocks. These shocks are generated on a large range of scales by galactic rotation, supernovae, stellar winds, and other processes. Whenever a shock encounters a density interface, Richtmyer-Meshkov instabilities may develop. Perturbations along the interface grow, leading to structure formation and material mixing. An understanding of the evolution of Richtmyer-Meshkov instabilities is essential for understanding galactic structure, molecular cloud morphology, and the early stages of star formation. An ongoing experimental campaign studies Richtmyer-Meshkov mixing in a convergent, compressible, miscible plasma at the Omega laser facility. Cylindrical targets, consisting of a low density foam core and an aluminum shell covered by an epoxy ablator, are directly driven by fifty laser beams. The aluminum shell is machined to produce different perturbation spectra. Surface types include unperturbed (smooth), single-mode sinusoids, multi-mode (rough), and multi-mode with particular modes accentuated (specified-rough). Experimental results are compared to theory and numerical simulations.     

Distribution of free electrons in the galactic plane

A method is proposed for constructing a map of the electron density distribution in the galactic plane. Data on the dispersion measures DM of more than 1500 pulsars and their distances, found by an independent method, are used. The independent distances of the pulsars are estimated using an empirical relation of the form L=γP ^α Ṗ ^β W ^δ between the radio luminosity L of the pulsars and their periods P, the rate of change Ṗ. of their periods, and the half width W of their pulses. A map of the electron density distribution in the galactic plane within a ±400 pc layer is provided. __________ Translated from Astrofizika, Vol. 49, No. 2, pp. 277–287 (May 2006).     

Turnover Frequency in Solar Microwave Bursts with an Extremely Flat Optically Thin Spectrum

Four microwave bursts have been selected from the Nobeyama Radio Polarimeter (NoRP) observations with an extremely flat spectrum in the optically thin part and a very hard spectral index between 0 and ?1 in the maximum phase of all bursts. It is found that the time evolution of the turnover frequency is inversely proportional to the time profiles of the radio flux in all bursts. Based on the nonthermal gyrosynchrotron theory of Ramaty (Astrophys. J. 158, 753, 1969), the local magnetic field strength and the electron spectral index are calculated uniquely from the observed radio spectral index and the turnover frequency. We found that the electron energy spectrum is very hard (spectral index 1?–?2), and the time variation of the magnetic field strength is also inversely proportional to the radio flux as a function of time in all bursts. Hence, the time evolution of the turnover frequency can be explained directly by its dependence on the local magnetic field strength. The high turnover frequency (several tens of GHz) is mainly caused by a strong magnetic field of up to several hundred gauss, and probably by the Razin effect under a high plasma density over \(10^{10}~\mbox{cm}^{-3}\) in the maximum phase of these bursts. Therefore, the extremely flat microwave spectrum can be well understood by the observed high turnover frequency and the calculated hard electron spectral index.     

Fundamental and harmonic radiation in type III solar radio bursts

Type III solar radio bursts are investigated by modelling the propagation of the electron beam and the generation and subsequent propagation of waves to the observer. Predictions from this model are compared in detail with particle, Langmuir wave, and radio data from the ISEE-3 spacecraft and with other observations to clarify the roles of fundamental and harmonic emission in type III radio bursts. Langmuir waves are seen only after the arrival of the beam, in accord with the standard theory. These waves persist after a positive beam slope is last resolved, implying that sporadic positive slopes persist for some time, unresolved but in accord with the predictions of stochastic growth theory. Local electromagnetic emission sets in only after Langmuir waves are seen, in accord with the standard theory, which relies on nonlinear processes involving Langmuir waves. In the events investigated here, fundamental radiation appears to dominate early in the event, followed and/or accompanied by harmonic radiation after the peak, with a long-lived tail of multiply scattered fundamental or harmonic emission extending long afterwards. These results are largely independent of, but generally consistent with, the conclusions of earlier works.     

Determining risk sources and strategies among farmers of contrasting risk awareness: A case study for Cukurova region of Turkey

In this paper, the results of a survey conducted in the Cukurova region of Turkey are presented. The aim of this research is to identify groups of farmers who differ in their risk sources and risk management strategies. The respondents to the survey were divided into three risk attitude groups, risk averse, risk seeking and risk neutral. Factor analysis has been conducted on information obtained from 112 farmers in 2000. From the findings of the research, risk sources were labelled as environmental, price, catastrophe, input costs, production and technological, political, finance, personal, marketing, health and social security. The dimensions of risk strategies were named as diversification, off-farm income, marketing, planning, financing and security.     

Spurenelemente in der Aare (Schweiz)

Instrumental neutron activation analysis was used for the determination of more than 20 trace and minor elements in water and silt samples (suspended load) of the river Aare. The samples were collected at four different locations along the river between its source and the lake of Bienne. The principal results are: 1. The concentrations of all elements investigated are much lower than WHO-limits for drinking water. 2. Human activities are responsible for an increase of some elements along the river. 3. The concentrations of dissolved trace elements are generally anticorrelated with the water flow rate. 4. The concentrations of the trace elements in particulates (in μg/l) are correlated with the flow rate of water. Except for Ca?Sr there are no significant interelement correlations for all four sampling stations.