The Ediacaran–Early Cambrian detrital zircon record of NW Iberia: possible sources and paleogeographic constraints

Ediacaran and Early Cambrian sedimentary rocks from NW Iberia have been investigated for detrital zircon U–Pb ages. A total of 1,161 concordant U–Pb ages were obtained in zircons separated from four Ediacaran samples (3 from the Cantabrian Zone and one from the Central Iberian zone) and two Lower Cambrian samples (one from the Cantabrian Zone and one from the Central Iberian Zone). Major and trace elements including REE and Sm–Nd isotopes were also analyzed on the same set of samples. The stratigraphically older Ediacaran sequence in the Cantabrian Zone has a maximum sedimentation age of ca. 600 Ma based on detrital zircon content and is intruded by ca. 590–580 Ma granitoids constraining the deposition of this part of the sequence between ca. 600 and 580 Ma. The stratigraphically younger Ediacaran sequence in the Cantabrian Zone has a maximum sedimentation age of ca. 553 Ma. The Ediacaran sample from the Central Iberian Zone has an identical within error maximum sedimentation age of ca. 555 Ma. The detrital zircon U–Pb age patterns are very similar in all the Ediacaran samples from both zones including the main age groups ca. 0.55–0.75 Ga, ca. 0.85–1.15 Ga and minor Paleoproterozoic (ca. 1.9–2.1 Ga) and Archean (ca. 2.4–2.6 Ga) populations. Kolmogorov–Smirnov statistical tests performed on this set of samples indicate that they all were derived from the same parent population (i.e., same source area). The same can be said on the basis of Nd isotopes, REE patterns and trace element concentrations. The two Cambrian samples, however, show contrasting signatures: The sample from the Cantabrian Zone lacks the ca. 0.85–1.15 Ga population and has a high proportion of Paleoproterozoic and Archean zircons (>60 %) and a more negative ε _Nd and higher T _DM values than the Ediacaran samples. The Early Cambrian sample from the Central Iberian Zone has the same U–Pb detrital zircon age distribution (based on KS tests) as all the Ediacaran samples but has a significantly more negative ε _Nd value. These data suggest apparently continuous sedimentation in the NW Iberian realm of northern Gondwana between ca. 600 and 550 Ma and changes in the detrital influx around the Ediacaran–Cambrian boundary. The nature and origin of these changes cannot be determined with available data, but they must involve tectonic activity on the margin as evidenced by the angular unconformity separating the Ediacaran and Lower Cambrian strata in the Cantabrian Zone. The absence of this unconformity and the apparent continuity of detrital zircon age distribution between Ediacaran and Cambrian rocks in the Central Iberian Zone suggest that the margin became segmented with significant transport and sedimentation flux changes in relatively short distances. As to the paleoposition of NW Iberia in Ediacaran–Early Cambrian times, comparison of the data presented herein with a wealth of relevant data from the literature both on the European peri-Gondwanan terranes and on the terranes of northern Africa suggests that NW Iberia may have lain closer to the present-day Egypt–Israel–Jordan area and that the potential source of the hitherto enigmatic Tonian–Stenian zircons could be traced to exposed segments of arc terranes such as that described in the Sinai Peninsula (Be’eri-Shlevin et al. in Geology 40:403–406, 2012).     

Flotation of galena. Influence of grain size,of pulp deoxygenation,and of cleaning with ammonium acetate

The flotation of < 10, 10–20, and 20–40 μm galena fractions was studied. For uncleaned galena a given collector coverage produced better floatability with increasing grain size. Nitrogen had a detrimental effect only for the < 10 μm fraction, producing at a given collector coverage a recovery smaller than that obtained with air.Galena cleaned with 400 g/l ammonium acetate had very poor floatability, although xanthate abstraction was fairly high; this confirms that strong xanthate adsorption is necessary for flotation. Formation of monothiocarbonate was small in all cases, which points to a very minor influence, if any, of this compound in the flotation process.In blank flotation tests, or for very low residual xanthate concentrations, a peak at 208 nm and a shoulder at 255 nm were observed. The former was assigned to the uncomplexed Pb²⁺ ion, and the latter was tentatively attributed to the PbOH⁺ ion.Lead in solution results from dissolution of the oxidation products of galena, as galena itself has an exceedingly low solubility. The curve for total lead in solution vs. initial xanthate concentration, had a minimum for an initial xanthate concentration of 10^?5M, the further increase in dissolved lead is attributed to formation of complexes such as PbX⁺ (X = xanthate). Dissolved lead concentrations were nearly as high for cleaned as for uncleaned galena, which indicates a high oxidation rate of the mineral.     

Pace and Pattern of Recent Treeline Dynamics: Response of Ecotones to Climatic Variability in the Spanish Pyrenees

Treeline ecotones are regarded as sensitive monitors of the recent climatic warming. However, it has been suggested that their sensitivity depends more on changes in tree density than on treeline position. We study these processes and the effect of climate, mainly air temperature, on tree recruitment and recent treeline dynamics. We selected three relatively undisturbed sites in the Spanish Pyrenees, dominated by Pinusuncinata, and analyzed their recent dynamics at local spatial (0.3–0.5 ha) and short temporal scales (100–300 years). We wanted to establish whether higher temperature was the only climatic factor causing an upward shift of the studied alpine treelines. The data we report show that treelines were ascending until a period of high interannual variability in mean temperature started (1950–95). During the late twentieth century, treeline fluctuation was less sensitive to climate than was the change in tree density within the ecotone. Tree recruitment and treeline position responded to contrasting climatic signals; tree recruitment was favored by high March temperatures whereas treeline position ascended in response to warm springs. We found a negative relationship between mean treeline-advance rate and March temperature variability. According to our findings, if the interannual variability of March temperature increases, the probability of successful treeline ascent will decrease.     

Assessing the inconsistency between groundwater vulnerability and groundwater quality: the case of Chapala Marsh, Mexico

Aquifer systems present intrinsic properties such as vulnerability, which is identified as the potential risk of groundwater pollution by contaminants generated by human activity. When there are surface sources of pollution, usually there is a direct relationship between high vulnerability and decreased water quality. Nevertheless, this relationship is not observed in all aquifers and so the causative circumstances of inconsistencies between aquifer vulnerability and water quality have been investigated. This work addresses the vulnerability assessment of the Chapala Marsh area, Mexico, using SINTACS analysis. The Chapala Marsh aquifer is characterized by a granular structure and a fractured recharge zone; there are natural and anthropogenic sources of pollution. The results show discrepancies between the vulnerability indices and groundwater quality, as indicated by the existence of vulnerable areas with good water quality and vice versa. This is because the SINTACS method works well when contaminants have only vertical movement. For scenarios with lateral movement of contaminants, the method of geographic weighted regression (GWR) is used to model the influence of potential sources of contaminants on the water quality.     

Radar interferometry techniques for the study of ground subsidence phenomena: a review of practical issues through cases in Spain

Subsidence related to multiple natural and human-induced processes affects an increasing number of areas worldwide. Although this phenomenon may involve surface deformation with 3D displacement components, negative vertical movement, either progressive or episodic, tends to dominate. Over the last decades, differential SAR interferometry (DInSAR) has become a very useful remote sensing tool for accurately measuring the spatial and temporal evolution of surface displacements over broad areas. This work discusses the main advantages and limitations of addressing active subsidence phenomena by means of DInSAR techniques from an end-user point of view. Special attention is paid to the spatial and temporal resolution, the precision of the measurements, and the usefulness of the data. The presented analysis is focused on DInSAR results exploitation of various ground subsidence phenomena (groundwater withdrawal, soil compaction, mining subsidence, evaporite dissolution subsidence, and volcanic deformation) with different displacement patterns in a selection of subsidence areas in Spain. Finally, a cost comparative study is performed for the different techniques applied.     

Evaluation of trenching,ground penetrating radar (GPR) and electrical resistivity tomography (ERT) for sinkhole characterization

This paper explores the suitability and advantages of combining the trenching technique with geophysical surveys [ground penetrating radar (GPR) and electrical resistivity tomography (ERT)] for sinkhole characterization in a mantled karst area. The approach is applied to two active sinkholes concealed by anthropogenic deposits and formed by contrasting subsidence mechanisms; collapse and sagging. The ERT section acquired across the collapse sinkhole images the clayey fill of the depression as an obvious low resistivity area, showing the approximate location of the sinkhole edges. Spatially dense GPR surveys provide information on the position of the boundaries of the concealed subsidence structures and their three‐dimensional (3D) internal geometry, revealing the dominant subsidence mechanism. We illustrate the impact of several factors on the quality of the GPR data such as sinkhole size, nominal frequency of the antennas, antenna shielding, and the presence of backfilled excavations and above‐surface objects. Trenches provided detailed information on the subsurface structure of the sinkhole, subsidence magnitude, partitioning of the strain, and the position of the sinkhole edges, especially when they are deep enough and excavated across the central sector and perpendicular to the boundaries. The stratigraphic and structural relationships observed in the trench were then used to infer the spatial evolution of the sinkholes (e.g. enlargement), their kinematic behavior (episodic versus progressive), and to differentiate discrete subsidence events and their associated magnitude. Numerical dates were used to estimate average subsidence rates and the recurrence of subsidence events. Such integrated data sets may be used as an objective basis to forecast the future behavior of potentially damaging sinkholes and to assess the associated hazard and risk. Copyright © 2013 John Wiley & Sons, Ltd.     

Headwaters drive streamflow and lowland tracer export in a large-scale humid tropical catchment

Headwaters are generally assumed to contribute the majority of water to downstream users, but how much water, of what quality and where it is generated are rarely known in the humid tropics. Here, using monthly monitoring in the data scarce (2,370 km²) San Carlos catchment in northeastern Costa Rica, we determined runoff-area relationships linked to geochemical and isotope tracers. We established 46 monitoring sites covering the full range of climatic, land use and geological gradients in the catchment. Regression and cluster analysis revealed unique spatial patterns and hydrologically functional landscape units. These units were used for seasonal and annual Bayesian tracer mixing models to assess spatial water source contributions to the outlet. Generally, the Bayesian mixing analysis showed that the chemical and isotopic imprint at the outlet is throughout the year dominated by the adjacent lowland catchments (68%) with much less tracer influence from the headwaters. However, the headwater catchments contributed the bulk of water and tracers to the outlet during the dry season (>50%) despite covering less than half of the total catchment area. Additionally, flow volumes seemed to be linearly scaled by area maintaining a link between the headwaters and the outlet particularly during high flows of the rainy season. Stable isotopes indicated mean recharge elevations above the mean catchment altitude, which further supports that headwaters were the primary source of downstream water. Our spatially detailed “snap-shot” sampling enabled a viable alternative source of large-scale hydrological process knowledge in the humid tropics with limited data availability.     

Temporal and spatial variability in the Guadalquivir estuary: a challenge for real-time telemetry

Meteorological, hydrological, and hydrodynamic data for 3 years (2008–2010) have been used to document and explain the temporal and spatial variability of the physical–biogeochemical interactions in the Guadalquivir River Estuary. A real-time, remote monitoring network has been deployed along the course of the river between its mouth and Seville to study a broad range of temporal scales (semidiurnal, diurnal, fortnightly, and seasonal). This network consists of eight hydrological monitoring stations capable of measuring temperature, conductivity, dissolved oxygen, turbidity, and chlorophyll fluorescence at four depths. In addition, six stations have been deployed to study hydrodynamics, obtaining 20-cell water column current profiles, and there is a meteorological station at the river mouth providing data for understanding atmospheric interactions. Completing this data-gathering network, there are several moorings (tide gauges, current/wave sensors, and a thermistor chain) deployed in the estuary and river mouth. Various sources of physical forcing, such as wind, tide-associated currents, and river discharge, are responsible for the particular temporal and spatial patterns of turbidity and salinity found in the estuary. These variables force the distribution of biogeochemical variables, such as dissolved oxygen and chlorophyll fluorescence. In particular, episodes of elevated turbidity (when suspended particle matter concentration >3,000 mg/l) have been detected by the network, together with episodes of declining values of salinity and dissolved oxygen. All these patterns are related to river discharge and tidal dynamics (spring/neap and high/low tide).     

The application of GPR and ERI in combination with exposure logging and retrodeformation analysis to characterize sinkholes and reconstruct their impact on fluvial sedimentation

This work illustrates the practicality of investigating sinkholes integrating data gathered by ground penetrating radar (GPR), electrical resistivity imaging (ERI) and trenching or direct logging of the subsidence‐affected sediments in combination with retrodeformation analysis. This mutidisciplinary approach has been tested in a large paleosinkhole developed during the deposition of a Quaternary terrace on salt‐bearing evaporites. The subsidence structure, exposed in an artificial excavation, is located next to Puilatos, a village that was abandoned in the 1970s due to severe subsidence damage. Detailed logging of the exposure revealed that the subsidence structure corresponds to an asymmetric sagging and collapse paleosinkhole with no clear evidence of recent activity. The sedimentological and structural relationships together with the retrodeformation analysis indicate that synsedimentary subsidence controlled channel location, the development of a palustrine environment and local changes in the channel pattern. GPR profiles were acquired using an array of systems with different antenna frequencies, including some recently developed shielded antennas with improved vertical resolution and penetration depth. Although radargrams imaged the faulted sagging structure and provided valuable data on fault throw, they did not satisfactorily image the complex architecture of the fluvial deposit. ERI showed lower resolution but higher penetration depth when compared to GPR, roughly capturing the subsidence structure and yielding information on the thickness of the high‐resistivity alluvium and the nature of the underlying low‐resistivity karstic residue developed on top of the halite‐bearing evaporitic bedrock. Data comparison allows the assessment of the advantages and limitations of these complementary techniques, highly useful for site‐specific sinkhole risk management. Copyright © 2016 John Wiley & Sons, Ltd.