Geochemical characterization of surface water and spring water in SE Kashmir Valley,western Himalaya: Implications to water–rock interaction

Water samples from precipitation, glacier melt, snow melt, glacial lake, streams and karst springs were collected across SE of Kashmir Valley, to understand the hydrogeochemical processes governing the evolution of the water in a natural and non-industrial area of western Himalayas. The time series data on solute chemistry suggest that the hydrochemical processes controlling the chemistry of spring waters is more complex than the surface water. This is attributed to more time available for infiltrating water to interact with the diverse host lithology. Total dissolved solids (TDS), in general, increases with decrease in altitude. However, high TDS of some streams at higher altitudes and low TDS of some springs at lower altitudes indicated contribution of high TDS waters from glacial lakes and low TDS waters from streams, respectively. The results show that some karst springs are recharged by surface water; Achabalnag by the Bringi stream and Andernag and Martandnag by the Liddar stream. Calcite dissolution, dedolomitization and silicate weathering were found to be the main processes controlling the chemistry of the spring waters and calcite dissolution as the dominant process in controlling the chemistry of the surface waters. The spring waters were undersaturated with respect to calcite and dolomite in most of the seasons except in November, which is attributed to the replenishment of the CO₂ by recharging waters during most of the seasons.     

Rječina River sediments (Croatia): from captured spring to polluted prodelta

Surface sediments (fraction <63 μm) from the source to the mouth of the Rječina, short (18.3 km) karst allogenic river in Croatia, which is an important source of drinking water, were studied to investigate their mineral (by XRD) and chemical (by ICP-MS) composition to check possible anthropogenic influence at the lower course due to paper industry and mills, and in the prodelta area from untreated municipal sewage and the large harbor of Rijeka town. In all analyzed sediment samples and in the sandstone source, rock quartz is a major mineral, while feldspar and mica group minerals are less abundant. Chlorite is a minor or trace mineral in all samples. Calcite and dolomite are abundant in the river prodelta, reflecting changes in bedrock lithology from flysch to carbonates. In river sediments, Fe is the most abundantly analyzed element, while Ca is the most abundant in prodelta sediments. Concentrations of Al, Mn, Ni, Cr, Co, La and Nd decrease downstream, while Mg, S, Na, B, Pb, Zn, As, Sn, U, Mo, Hg and Ag have relatively higher concentration in prodelta sediments. The results are compared with sediments of other rivers in the area: Raša, Rižana and Dragonja, as well as with those of the Rosandra Creek (Italy). Sediments in the Raša River showed similar behavior as those in the Rječina, as the highest concentration of metals was found in the restricted upper part of the estuary, characterized by rapid deposition of clay particles and terrestrial sedimentary organic matter. The comparison also showed that the most contaminated were the sediments from the Rižana, followed by those from the Rječina and Rosandra Creek, which had similar results. Among the studied elements, As was present in all sediment samples at concentrations >6 ppm that might have the lowest toxic effects. At the lower Rječina and in prodelta sediments, Pb was also present at slightly elevated concentrations (>31 ppm) that could cause such effects. Concentrations of Zn in the prodelta correspond to those occurring in moderately polluted sediments (90–200 ppm). In the prodelta sediments, Hg is slightly below toxicity threshold (1 ppm), while Ag is present at toxicity threshold (0.5 ppm) or close to it. Rječina River could act as a good illustrative example for behavior of toxic metals in allogenic karstic rivers, in which accumulation of anthropogenically introduced pollutants usually occurs in their estuaries, as a result of transport and deposition of fine particles.     

Preface: Proceedings of the 5th International Symposium on Lithographic Limestone and Plattenkalk

Magmatic rocks from the pre-Mesozoic basements of the Sambuco and Maggia nappes have been dated by U–Pb zircon ages with the LA-ICPMS technique. Several magmatic events have been identified in the Sambuco nappe. The mafic banded calc-alkaline suite of Scheggia is dated at 540 Ma, an age comparable to that of mafic rocks in the Austroalpine Silvretta nappe. The Sasso Nero peraluminous augengneiss has an age of 480–470 Ma, like many other “older orthogneisses” in Alpine basement units. It hosts a large proportion of inherited zircons, which were dated around 630 Ma, a Panafrican age indicating the Gondwanan affiliation of the Sambuco basement. The calc-alkaline Matorello pluton yielded ages around 300 Ma, similar to numerous Late Carboniferous intrusions in other basement units of the Lower Penninic (Monte Leone, Antigorio, Verampio) and Helvetic domains (Gotthard and other External Crystalline Massifs). Associated lamprophyric dykes are slightly younger (300–290 Ma), like similar dykes sampled in gneiss blocks included in the sedimentary cover of the underlying Antigorio nappe (290–285 Ma). The Cocco granodiorite and Rüscada leucogranite, both intruding the basement of the neighbouring Maggia nappe, yielded ages of ca. 300–310 Ma, identical within errors to the age of the Matorello pluton. They are significantly older than former age determinations. This age coincidence, coupled with remarkable petrologic similarities between the Cocco and Matorello granodiorites, strongly suggests paleogeographic proximity of the Sambuco and Maggia nappes in Late Carboniferous times. In recent publications these two nappes have been interpreted as belonging to distinct Mesozoic paleogeographic domains: “European” for Sambuco and “Briançonnais” for Maggia, separated by the “Valais” oceanic basin. In this case, the similarity of the Matorello and Cocco intrusions would demonstrate the absence of any significant transcurrent movement between these two continental domains. Alternatively, according to a more traditional view, Sambuco and Maggia might belong to a single large Alpine tectonic unit.     

Lithostratigraphic development and neotectonic significance of the Quaternary sediments along the Kachchh Mainland Fault (KMF) zone,western India

The Kachchh Mainland Fault (KMF) is a major E–W trending seismically active fault of the Kachchh palaeorift basin whose neotectonic evolution is not known. The present study deals with the eastern part of the KMF zone where the fault is morphologically expressed as steep north facing scarps and is divisible into five morphotectonic segments. The Quaternary sediments occurring in a narrow zone between the E–W trending KMF scarps and the flat Banni plain to the north are documented. The sediments show considerable heterogeneity vertically as well as laterally along the KMF zone. (The Quaternary sediments for a northward sloping and are exposed along the north flowing streams which also show rapid decrease in the depth of incision in the same direction.) The deposits, in general, comprise coarse as well as finer gravelly deposits, sands and aeolian and fluvial miliolites. The Quaternary sediments of the KMF zone show three major aggradation phases. The oldest phase includes the colluvio-fluvial sediments occurring below the miliolites. These deposits are strikingly coarse grained and show poor sorting and large angular clasts of Mesozoic rocks. The sedimentary characteristics indicate deposition, dominantly by debris flows and sediment gravity flows, as small coalescing alluvial fans in front of the scarps. These deposits suggest pre-miliolite neotectonic activity along the KMF. The second aggradation phase comprises aeolian miliolites and fluvially reworked miliolites that have been previously dated from middle to late Pleistocene. The youngest phase is the post-miliolite phase that includes all deposits younger than miliolite. These are represented by comparatively finer sandy gravels, gravelly sands and sand. The sediment characteristics suggest deposition in shallow braided stream channels under reduced level of neotectonic activity along the KMF during post-miliolite time evidenced by vertical dips of miliolites and tilting of gravels near the scarps. The tectonically controlled incision and dissection of the Quaternary deposits is the result of neotectonic activity that continues at present day. The overall nature, sedimentary characteristics and geomorphic setting of the sediments suggest that the KMF remained neotectonically active throughout the Quaternary period.     

G23FM: a tool for meshing complex geological media

We present G23FM, a mesh generation tool for discretizing two- and three-dimensional complex fractured geological media. G23FM includes different techniques to generate finite element grids that maintain the geometric integrity of input surfaces, and geologic data and produce optimal triangular/tetrahedral grids for flow and transport simulations. G23FM generates grid for two-dimensional cross-sections, represents faults and fractures, for three-dimensional fractured media, and has the capability of including finer grids. Different examples are presented to illustrate some of the main features of G23FM.     

Chemical and Strontium Isotopic Compositions of the Hanjiang Basin Rivers in China: Anthropogenic Impacts and Chemical Weathering

The Hanjiang River, the largest tributaries of the Changjiang (Yangtze) River, is the water source area of the Middle Route of China’s South-to-North Water Transfer Project. The chemical and strontium isotopic compositions of the river waters are determined with the main purpose of understanding the contribution of chemical weathering processes and anthropogenic inputs on river solutes, as well as the associated CO₂ consumption in the carbonate-dominated basin. The major ion compositions of the Hanjiang River waters are characterized by the dominance of Ca²⁺ and HCO₃ ⁻, followed by Mg²⁺ and SO₄ ²⁻. The increase in TDS and major anions (Cl⁻, NO₃ ⁻, and SO₄ ²⁻) concentrations from upstream to downstream is ascribed to both extensive influences from agriculture and domestic activities over the Hanjiang basin. The chemical and Sr isotopic analyses indicate that three major weathering sources (dolomite, limestone, and silicates) contribute to the total dissolved loads. The contributions of the different end-members to the dissolved load are calculated with the mass balance approach. The calculated results show that the dissolved load is dominated by carbonates weathering, the contribution of which accounts for about 79.4% for the Hanjiang River. The silicate weathering and anthropogenic contributions are approximately 12.3 and 6.87%, respectively. The total TDS fluxes from chemical weathering calculated for the water source area (the upper Hanjiang basin) and the whole Hanjiang basin are approximately 3.8 × 10⁶ and 6.1 × 10⁶ ton/year, respectively. The total chemical weathering (carbonate and silicate) rate for the Hanjiang basin is approximately 38.5 ton/km²/year or 18.6 mm/k year, which is higher than global mean values. The fluxes of CO₂ consumption by carbonate and silicate weathering are estimated to be 56.4 × 10⁹ and 12.9 × 10⁹ mol/year, respectively.     

Sinkhole characterization in the Dead Sea area using airborne laser scanning

Since the early 1980s, the Dead Sea coast has undergone a near catastrophic land deterioration as a result of a rapid lake-level drop. One conspicuous expression of this deterioration is the formation of sinkholes fields that puncture the coastal plains. The evolution of sinkholes along nearly 70-km strip has brought to a halt the regional development in this well-known and toured area and destroyed existing infrastructures. Great efforts are being invested in understanding the phenomena and in development of monitoring techniques. We report in this paper the application of airborne laser scanning for characterization of sinkholes. We demonstrate first the appropriateness of laser scanning for this task and its ability to provide detailed 3D information on this phenomenon. We describe then an autonomous means for their extraction over large regions and with high level of accuracy. Extraction is followed by their detailed geometric characterization. Using this high-resolution data, we show how sinkholes of 0.5 m radius and 25 cm depth can be detected from airborne platforms as well as the geomorphic features surrounding them. These sinkhole measures account for their embryonic stage, allowing tracking them at an early phase of their creation.     

Resources and eco-environmental protection of salt lakes in China

The Chinese salt lake mega-region is controlled by an arid and semi-arid climate, and modern salt lakes are mainly distributed within areas with mean annual precipitation <500 mm. According to their geomorphological features, structural conditions, and material composition, salt lakes in China can be broadly divided into four regions. The degrees of exploitation and utilization of these salt lakes differ because these four regions have experienced different climatic changes and structural activities and have had their own characteristics of salt lake evolution since the beginning of the Quaternary. The salt lakes in these regions have different scales, economic value, and technical conditions for traffic. Among others, Jarantai (Jartai) Salt Lake and Yuncheng Salt Lake are better in terms of comprehensive utilization and environmental protection, and the potash salt lakes represented by Qarhan are most important in terms of exploitation. At present, there exist many environmental problems in the salt lake regions of China, especially in remote, small and medium-sized basins, where abusive or wasteful mining, low recovery, and mining of a single saline mineral have caused impoverishment and large quantities of byproducts. Furthermore, climatic environmental factors can also cause significant changes of salt lake environment. Since 1987, against the background of global warming, the climate in the northwest salt lake region has turned warm and wet, and lakes have exhibited a tendency for expansion and rise, whereas in the east of the region, the climate has remained in a warm dry stage, lake levels have dropped, and salt lakes have become desertified. With the implementation of the strategy of building an environmentally friendly society in China, increasing attention is being paid to eco-environmental protection. It is suggested that experience and advanced techniques in terms of comprehensive utilization, overall development, and environmental protection of salt lakes at home and abroad be further developed to strengthen observation and monitoring of environmental changes of salt lakes and build an environmentally friendly, great salt lake industry.     

Prediction of Floor Water Inrush: The Application of GIS-Based AHP Vulnerable Index Method to Donghuantuo Coal Mine,China

Floor water inrush represents a geohazard that can pose significant threat to safe operations for instance in coal mines in China and elsewhere. Its occurrence is controlled by many factors, and the processes are often not amenable to mathematical expressions. To evaluate the water inrush risk, the paper proposes the vulnerability index approach by coupling the analytic hierarchy process (AHP) and geographic information system (GIS). The detailed procedures of using this innovative approach are shown in a case study in China (Donghuantuo Coal Mine). The powerful spatial data analysis functions of GIS was used to establish the thematic layer of each of the six factors that control the water inrush, and the contribution weights of each factor was determined with the AHP method. The established AHP evaluation model was used to determine the threshold value for each risk level with a histogram of the water inrush vulnerability index. As a result, the mine area was divided into five regions with different vulnerability levels which served as general guidelines for the mine operations. The prediction results were further corroborated with the actual mining data, and the evaluation result is satisfactory.