Bio-climatic imprints on a Holocene loess palaeosol from China

Micromorphology, heavy minerals, pollen and soil properties were examined in a typical Holocene loess profile in the north of the Loess Plateau, consisting of a palaeosol (locally known as the Ansai palaeosol) underlain by the Malan loess and overlain by modern loess. The palaeosol consists of an upper humus-rich (AB) horizon over a clay-rich (Bt) horizon. The humus-rich horizon is intensely weathered, contains precipitated calcitic material derived from the overlying modern loess, and has both high pollen content and diversity. Clay coatings in the clay-rich horizon indicate formation by eluviation–illuviation of clay. Pedogenetic characteristics and pollen analysis imply that the vegetation during the time of most intensive soil development is likely to have been a warm-temperate forest. A complex interpretation of the loess–palaeosol sequence recognizes several development stages. The phase of soil development, maximum and minimum limiting ages for which are ca. 8800 and 4400 ¹⁴C years BP, involved continuing but reduced loess deposition, and successive Holocene bio-climatic environment overprinted new features on the palaeosol.     

Origin of Natural Gas in Kekeya Field, Tarim Basin, China

This paper is mainly concentrated on the geochemical characteristics and origin of gas of Kekeya field in the Tarim basin, NW China. This study shows that Permian mudstone is the main source rock of oil and gas. Based on the carbon isotopes of C1--C4, the carbon isotope of gas in Kekeya field is a little heavier than that in the typical marine-derived gas. The relationship between carbon isotopes of methane and ethane is coincident with Faber equation of gas derived from organic matter Ⅰ/Ⅱ. The majority of gas maturity is estimated, based on the formula, at 1.8%-2.2% besides K2 and K18 wells. In addition, the gas derived from 0.9%-1.2% Ro source rocks may also bemixture. ^40Ar/^36Ar and ^3He/^4He ratios from the gas samples also support the mixing process. Moreover, the gas in this region is mainly generated from more mature source rocks although the low mature gas exists.     

用L-曲线法确定半参数模型中的平滑因子

提出了一种新的方法——L-曲线法确定平滑因子。通过确定合适的平滑因子，更好地控制了残差部分V^TPV与光滑度部分S^TRS之间的平衡，得到了更准确的参数估值。通过算例，将基于L-曲线法确定平滑因子的半参数模型解算方法和其他方法进行了比较。结果表明，用L-曲线法确定平滑因子后，提高了半参数模型计算结果的精度，可以更好地将观测值中的系统误差分离出来。     

塔城市一次暴雪天气的分析

2003年2月22日塔城市出现一次暴雪天气过程。文章着重分析了此次天气过程的高空环流形势、地面形势、T—Td等，指出暖湿气流是造成暴雪的主要原因。     

AHP及模糊综合评判法在路基长期稳定性评价中的应用

根据对一低液限粉土路基的现场工程地质调查及检测,确定了影响该路基长期稳定性的主要影响因素,并结合AHP法,应用两级模糊综合评判的方法对该路基的长期稳定性进行了评价。     

On Tension Failure of 2-D Rock Specimens and Associated Acoustic Emission

Summary To understand the failure mechanism of quasi-brittle materials like rock under tensile stress, observations on the failure process of granite and marble plate specimens under tension are summarized and presented. Micro- and macro-failure properties of rock plates under uniaxial tension have been characterized by using an acoustic emission technique. Acoustic emission signals associated with micro-fractures are captured to locate the sources. An algorithm based on arrival time difference is developed for this purpose. The results reveal clearly the failure processes of rock which include initiation, nucleation and propagation of micro-fractures when the axial stress is close to the peak strength of rock. It is believed that the difference in heterogeneity between granite and marble specimens leads to different fracture shapes and different behaviors of associated acoustic emissions. Numerical simulation of acoustic emissions for two-dimensional tensile test is also carried out. The simulated characteristics are in good agreement with the experimental results.     

Adsorption of rare earth elements onto Carrizo sand: Experimental investigations and modeling with surface complexation

Rare earth element (REE) adsorption onto sand from a well characterized aquifer, the Carrizo Sand aquifer of Texas, has been investigated in the laboratory using a batch method. The aim was to improve our understanding of REE adsorption behavior across the REE series and to develop a surface complexation model for the REEs, which can be applied to real aquifer-groundwater systems. Our batch experiments show that REE adsorption onto Carrizo sand increases with increasing atomic number across the REE series. For each REE, adsorption increases with increasing pH, such that when pH >6.0, >98% of each REE is adsorbed onto Carrizo sand for all experimental solutions, including when actual groundwaters from the Carrizo Sand aquifer are used in the experiments. Rare earth element adsorption was not sensitive to ionic strength and total initial REE concentrations in our batch experiments. It is possible that the differences in experimental ionic strength conditions (i.e., 0.002-0.01 M NaCl) chosen were insufficient to affect REE adsorption behavior. However, cation competition (e.g., Ca, Mg, and Zn) did affect REE adsorption onto Carrizo sand, especially for light rare earth elements (LREEs) at low pH. Rare earth element adsorption onto Carrizo sand can be successfully modeled using a generalized two-layer surface complexation model. Our model calculations suggest that REE complexation with strong surface sites of Carrizo sand exceeds the stability of the aqueous complexes LnOH²⁺, LnSO₄⁺, and LnCO₃⁺, but not that of Ln(CO₃)₂^- or LnPO₄^o in Carrizo groundwaters. Thus, at low pH (<7.3), where major inorganic ligands did not effectively compete with surface sites for dissolved REEs, free metal ion (Ln³⁺) adsorption was sufficient to describe REE adsorption behavior. However, at higher pH (>7.3) where solution complexation of the dissolved REEs was strong, REEs were adsorbed not only as free metal ion (Ln³⁺) but also as aqueous complexes (e.g., as Ln(CO₃)₂^- in Carrizo groundwaters). Because heavy rare earth elements (HREEs) were preferentially adsorbed onto Carrizo sand compared to LREEs, original HREE-enriched fractionation patterns in Carrizo groundwaters from the recharge area flattened along the groundwater flow path in the Carrizo Sand aquifer due to adsorption of free- and solution-complexed REEs.     

Mixing of event and pre‐event water in a shallow Entisol in sloping farmland based on isotopic and hydrometric measurements,SW China

Water percolation and flow processes in subsurface geologic media play an important role in determining the water source for plants and the transport of contaminants or nutrients, which is essential for water resource management and the development of measures for pollution mitigation. During June 2013, the dynamics of the rainwater, soil water, subsurface flows and groundwater in a shallow Entisol on sloping farmland were monitored using a hydrometric and isotopic approach. The results showed that effective mixing of rainwater and soil water occurred in hours. The rebound phenomenon of δD profiles in soils showed that most isotope‐depleted rainwater largely bypassed the soil matrix when the water saturation in the soil was high. Preferential‐flow, which was the dominant water movement pattern in the vadose zone, occurred through the whole soil profile, and infrequent piston‐flow was mainly found at 20–40 cm in depth. The interflow in the soil layer, composed of 75.2% rainwater, was only generated when the soil profile had been saturated. Underflow in the fractured mudrock was the dominant flow type in this hillslope, and outflow was dominated by base flow (groundwater flow) with a mean contribution of 76.7%. The generation mechanism of underflow was groundwater ridging, which was superimposed upon preferential‐flow composed mainly of rainwater. The quick mixing process of rainwater and soil water and the rapid movement of the mixture through preferential channels in the study soil, which shows a typical bimodal pore size distribution, can explain the prompt release of pre‐event water in subsurface flow. Water sources of subsurface flows at peak discharge could be affected by the antecedent soil water content, rain characteristics and antecedent groundwater levels. Copyright © 2016 John Wiley & Sons, Ltd.