赣南营前岩体的年代学、地球化学、Sr-Nd-Hf同位素组成及其地质意义

赣南营前岩体由早期似斑状花岗闪长岩和晚期细粒黑云母花岗岩组成,在前者中普遍发育暗色基性包体。SHRIMP锆石U-Pb测年显示似斑状花岗闪长岩为172.2±3.1Ma,细粒黑云母花岗岩为168±3Ma,包体为167.6±3.3Ma。所有的岩石均为钙碱性系列,稀土元素显示LREE富集,HREE亏损,Eu负异常并不明显的特征,Nb-Ta负异常显示壳源物质的特征。晚期细粒黑云母花岗岩、早期似斑状花岗闪长岩、暗色包体的(87Sr/86Sr)i和εNd(t)值分别为0.70885～0.70965、0.71058～1.46393、0.70788～0.70923和-6.38～-5.31、-6.51～-5.17、-5.47～-4.31;锆石εHf(t)值分别为-12.4～-5.7、-9.2～-4.2、-9.4～+0.1。结合岩相学、地球化学研究,初步认为营前岩体的两期花岗质岩石源于地壳重熔,地幔底侵导致地壳熔融形成营前岩体,基性岩浆加入到未冷却的酸性岩浆中形成了目前所见到的暗色包体。结合区域上的研究资料,认为中侏罗世期间,沿"十杭"断裂带及与其相平行的一些深断裂发生了板块的撕裂,这些缝合带是岩石圈相对薄弱的地带,有利于幔源物质底侵上升以及壳幔相互作用。     

反相流动注射催化光度法测定废水中的亚硝酸根

采用反相流动注射技术与催化光度法相结合,用微机化流动注射分析仪准确控制反应时间,优化了实验条件,克服了催化光度法反应时间难以控制引起的方法精密度、准确度不高的弱点,拟定了测定痕量亚硝酸根的流动注射催化光度方法。分析速度第小时20次,NO2^- 质量浓度在0．00－2．00mg/L,回归方程斜率为0．155。方法直接测定电厂测水中NO2^-的结果与Griess法相符合,RSD＜5．0％（n=5）。     

毛乌素沙区1961-2016年降水特征

基于毛乌素沙区10个气象站1961-2016年观测资料,应用Mann-Kendall方法和t检验法对各气象站年降水量进行了突变检验,借助小波分析讨论了各气象站年降水量的周期特征,根据降水量等值线划分结果对整个研究区分区分析了年、季、月和日尺度上的降水变化特征,并在两个时段上分析了季节性降水的差异。结果表明：毛乌素沙区年降水量空间特征差异明显,东部亚区呈上升趋势,中西部亚区呈下降趋势,但变化趋势不显著且无突变发生;降水年内分配不均,干湿季分明,降水集中在5-9月,夏秋季降水占全年降水比重大,季、月和日尺度降水量存在梯度递减变化;年降水量的年际变化过程存在多重时间尺度的自相似结构;近26年的冬春季降水增加显著,但降水波动幅度小于前30年。     

Rainfall threshold determination for flash flood warning in mountainous catchments with consideration of antecedent soil moisture and rainfall pattern

Flash flood disaster is a prominent issue threatening public safety and social development throughout the world, especially in mountainous regions. Rainfall threshold is a widely accepted alternative to hydrological forecasting for flash flood warning due to the short response time and limited observations of flash flood events. However, determination of rainfall threshold is still very complicated due to multiple impact factors, particular for antecedent soil moisture and rainfall patterns. In this study, hydrological simulation approach (i.e., China Flash Flood-Hydrological Modeling System: CNFF-HMS) was adopted to capture the flash flood processes. Multiple scenarios were further designed with consideration of antecedent soil moisture and rainfall temporal patterns to determine the possible assemble of rainfall thresholds by driving the CNFF-HMS. Moreover, their effects on rainfall thresholds were investigated. Three mountainous catchments (Zhong, Balisi and Yu villages) in southern China were selected for case study. Results showed that the model performance of CNFF-HMS was very satisfactory for flash flood simulations in all these catchments, especially for multimodal flood events. Specifically, the relative errors of runoff and peak flow were within?±?20%, the error of time to peak flow was within?±?2 h and the Nash–Sutcliffe efficiency was greater than 0.90 for over 90% of the flash flood events. The rainfall thresholds varied between 93 and 334 mm at Zhong village, between 77 and 246 mm at Balisi village and between 111 and 420 mm at Yu village. Both antecedent soil moistures and rainfall temporal pattern significantly affected the variations of rainfall threshold. Rainfall threshold decreased by 8–38 and 0–42% as soil saturation increased from 0.20 to 0.50 and from 0.20 to 0.80, respectively. The effect of rainfall threshold was the minimum for the decreasing hyetograph (advanced pattern) and the maximum for the increasing hyetograph (delayed pattern), while it was similar for the design hyetograph and triangular hyetograph (intermediate patterns). Moreover, rainfall thresholds with short time spans were more suitable for early flood warning, especially in small rural catchments with humid climatic characteristics. This study was expected to provide insights into flash flood disaster forecasting and early warning in mountainous regions, and scientific references for the implementation of flash flood disaster prevention in China.     

甘肃白银厂铜多金属矿田重磁异常及构造特征北大核心CSCD

甘肃白银厂铜多金属硫化物矿田是受陆缘弧环境火山机构及其同生断裂控制的典型火山岩赋矿块状硫化物矿床(VHMS)。为了进一步探讨该矿床重磁场特征及与构造和矿床的关系,通过对区内的重磁场异常数据进行位场分离、小波分析和基于张量数据的三维欧拉反褶积自动确定地质体位置和埋藏深度的定量反演计算。结果表明,研究区布格重力场具有西部高、东部低的特征,其磁场可划分为4个磁场区;局部异常按一定分布规律呈圆形或似圆形正负相间分布,不同尺度的重磁细节异常图在一定程度上反映出引起重磁异常的地质异常体具有一定的延深且分布稳定,而且这些地质异常体具有向深部复合的趋势。经位场分离后正负相间的剩余重磁异常分布范围和分布特征大致反映了白银厂奥陶纪中酸性火山岩建造构造为一个继承性的火山穹窿构造,东、西部不同的重磁异常特征说明东西部的火山喷发具有不同的基底、源区和喷发方式。发育NW向、NE向、近NS向、NEE向等4组断裂构造,近NS向断裂F3、F4、F5、F6、F7形成时间稍晚于NEE向断裂,其与NEE向断裂F1、F2共同形成了研究区棋盘网格状的构造分布特征,这两组断裂为研究区内主要的控岩、控矿断裂。火山机构的分布明显受断裂构造控制,火山口集中分布在深大断裂、大断裂或两组断裂的交汇处。矿田内各矿床及成矿有利地段均处于研究区中部低缓重磁异常场内正负磁异常变化的梯度带内。本次研究为控矿要素研究和开展找矿预测工作提供了丰富、翔实的地球物理资料。     

Photosynthetic efficiency, cell volume, and elemental stoichiometric ratios in Thalassirosira weissflogii under phosphorus limitation

Nutrient limitation is known to inhibit growth and metabolism and to alter elemental stoichiometric ratios in phytoplankton. In this study, physiological changes in Thalassirosira weissflogii were measured under different dissolved inorganic phosphate (DIP) regimes in semi-continuous cultures to revisit the utility of the Redfield ratio for assessing nutrient limitation. The results showed that cell size increased with decreasing DIP availability. In the P-depleted treatment (f/2-P) the cell size was 1.48 times larger than that in the P-limited (f/100) treatment and 2.67 times larger than that in the P-saturated treatment (f/2 and f/10). The fucoxanthin to chlorophyll a ratio (Fuco/chl a) was relatively stable (about 0.3) in P-saturated cultures and was 10 times higher than that in P-limited and P-depleted cultures. During the experimental period, the photosynthetic efficiency index, ?F/Fm′, was relatively stable at ~0.50 in the P-saturated cultures, but quickly declined with decreasing DIP availability. Although cellular P content showed a significant difference between the P-saturated culture (1.6 pg/cell) and the P-limited culture (0.7 pg/cell), the N/P ratio in T. weissflogii did not show a trend with DIP availability and fluctuated slightly around 25. Our results suggest that cell division in T. weissflogii is not strictly size-gated but is probably regulated by a biochemical, and hence, an elemental stoichiometric ratio threshold, and that deviation of the cellular N/P ratio from the Redfield ratio is not a reliable indicator of algal nutrient stress.     

Extensive genetic divergence among Diptychus maculatus populations in northwest China

D. maculates is a kind of specialized Schizothoracinae fish has been locally listed as a protected animal in Xinjiang Province,China. Ili River located in north of Tianshan Mountain and Tarim River located in north of Qinghai-Tibetan Plateau were two main distribution areas of this fish. To investigate the genetic diversity and genetic structure of D. maculates,four populations from Tarim River system and two populations from Ili River system were collected in this study. A 570-bp sequence of the control region was obtained for 105 specimens. Twenty-four haplotypes were detected from six populations,only Kunes River population and Kashi River population shared haplotypes with each other. For all the populations examined,the haplotype diversity(h) was 0.904 8±0.012 6,nucleotide diversity(π) was 0.027 9±0.013 9,and the average number of pairwise nucleotide differences(k) was 15.878 3±7.139 1. The analysis of molecular variance(AMOVA) showed that 86.31% of the total genetic variation was apportioned among populations,and the variation within sampled populations was 13.69%. Genetic differences among sampled populations were highly significant. F st statistical test indicated that all populations were significantly divergent from each other(P 0.01). The largest F st value was between Yurungkash River population and Muzat River population,while the smallest F st value was between Kunes River population and Kashi River population. NJ phylogenetic tree of D-loop haplotypes revealed two main clades. The neutrality test and mismatch distribution analysis suggested that the fish had went through a recent population expansion. The uplift of Tianshan Mountain and movement of Qinghai-Tibetan Plateau might contribute to the wide genetic divergence of D. maculates in northwest China.     

三元插层材料的合成及其在聚丙烯老化中的应用

以FeCl3?6H2O、NiCl2?6H2O、MgCl2?6H2O为原料,以NaOH为沉淀剂采用水热法合成了镁镍铁水滑石 (MgNiFe-LDH),通过X射线衍射 (XRD)、傅里叶变换红外光谱 (FTIR) 和扫描电镜 (SEM) 分析了MgNiFe-LDH结构及形貌,探讨了不同陈化时间和水热温度对MgNiFe-LDH合成的影响。将制得的MgNiFe-LDH添加至聚丙烯 (PP) 中,制备MgNiFe-LDH/PP复合材料,通过对材料的加速老化测其力学性能,研究了添加MgNiFe-LDH前后材料力学性能的差异。研究结果表明,当Mg2+:Ni2+:Fe3+=2:1:1,反应温度为140℃、陈化时间为24 h时,合成的MgNiFe-LDH为片状,形貌较为规整,颗粒粒径约为2μm;经加速老化后,填充MgNiFe-LDH 复合材料的抗老化性能优于纯PP,当MgNiFe-LDH的填充量为6 wt% 复合材料拉伸强度不变,可明显提高PP的抗老化性能。     

The role of salinity in fluvio-deltaic morphodynamics: A long-term modelling study

Salinity difference between terrestrial river discharge and oceanic tidal water plays a role in modifying the local flow field and, as a consequence, estuarine morphodynamics. Although widely recognized, recent numerical studies exploring the long-term morphological evolution of river-influenced estuaries with two-dimensional, depth-averaged models have mostly neglected salinity. Using a three-dimensional morphodynamic model, we aim to gain more insight into the effect of salinity on the morphodynamics of fluvio-deltaic systems. Model results indicate that the resultant estuarine morphology established after 600 years differs remarkably when a salinity gradient is included. A fan-shaped river-mouth delta exhibits less seaward expansion and is cut through by narrower channels when salinity is included. The inclusion of salinity tends to generate estuarine circulation, which favours landward sediment transport and hence limits the growth of the delta while enhancing the development of intertidal areas. The formation of deltaic channel–shoal patterns resulting from morphodynamic evolution tends to strengthen salinity stratification, which is characterized by an increased gradient Richardson number. The direction of the depth-averaged residual sediment transport over a tide may be opposite to the direction of residual velocity, indicating the significant influence of baroclinic effects on the net sediment transport direction (and hence morphological change). The effect of salinity on morphological evolution becomes less profound when the strength of tidal or fluvial forcing is dominant over the other. The effects of sediment type and flocculation, which are particularly important when salinity gradients are present, are also discussed. Overall, this study highlights that neglecting salinity to simulate long-term estuarine morphodynamics requires more careful justification, particularly when the environment is characterized by fine sediment types (favouring suspended transport), and relatively large river discharge and estuarine depth (favouring baroclinic effects). © 2020 John Wiley & Sons, Ltd.     

GPS动态定位中机动随机模型分析

给出了载体状态方程的严密公式和常用近似公式,详细讨论了两者之间的区别。在高精度GPS动态定位中的应用证明,常用近似公式对载体速度和加速度有显著的影响。