运用STOMP数值模拟器进行多空介质中尿素水解以及方解石沉淀数值模拟

遍布于美国能源部所辖野外场地的地下放射性核素和痕量金属污染对美国能源部的长期监管职能提出了最严峻的挑战。目前较有前景的一个原地固化污染物方法是利用尿素酶催化尿素水解,进而推动方解石沉淀及与之共同沉淀。运用STOMP数值模拟器实施一系列反应性溶质数值模拟来研究系统中水流、运移、反应与反应导致的介质性质变化之间的紧密的非线性耦合,并在研究中系统性增加反应系统的复杂度和物理-化学的非均质性以考察模拟效果。通过调整反应速率表达式中尿素酶浓度和沉淀反应常数,对尿素水解和方解石沉淀速率进行了敏感度分析。结果显示:尿素水解速率是矿物沉淀总量的决定性因素,沉淀物的空间分布既取决于水解速率也取决于沉淀速率;在一维水流柱6个空隙体积的时间段模拟中,观察到了5%的最大空隙度减少;当二维模拟中考虑一个低渗透性包裹体时,被改变的流场重新对生成的沉淀组成物进行了分布,形成了扭曲的反应锋面。模拟结果也显示沉淀在低渗透性区域边界上形成,这说明位于这个区域里面的污染物可能被囊裹而从流线中被隔离起来。     

浅层地热能在合肥地区的应用

根据合肥地区的水文与工程地质条件,研究浅层地热能在合肥地区应用的适宜方式,并结合工程实例,对浅层地热能应用的地源热泵空调系统中的地埋管换热器设计、自动控制与监测、运行控制等关键技术进行了探讨,旨在合肥地区推广应用浅层地热能,实现浅层地热能与地源热泵系统、建筑空调系统相匹配。     

Thermo 6300型电感耦合等离子体发射光谱仪常见故障及排除方法

详细介绍了美国Thermo仪器公司生产的Thermo 6300型电感耦合等离子体发射光谱仪在使用过程中不能"引燃"、容易"熄火"、数据稳定性差等常见故障及排除方法,以及其辅助设备的维护维修实例。     

鄂尔多斯盆地天环坳陷迁移演化与坳陷西翼油气成藏

鄂尔多斯盆地是我国陆上最重要的含油气盆地之一,本文以鄂尔多斯盆地西缘为研究对象,以地震反射资料为基础,主要采用地震剖面"层拉平"与"平衡剖面恢复"等技术手段,对天环坳陷形成与迁移演化历史进行了动态分析。研究结果表明:1)天环坳陷最早形成于晚侏罗世,后期由于受燕山晚期及喜马拉雅山期构造运动影响,坳陷核部逐渐向东迁移至现今位置,前后累计迁移距离约30 km;2)当坳陷核部向东迁移至有效烃源岩范围附近时,原先已形成的油气藏发生重新调整,油气向坳陷西翼高部位运移、聚集,从而形成了次生构造油气藏。     

埋藏环境白云石结构类型

近年来我国在白云岩储层油气勘探方面取得了重大进展,这些白云岩储层绝大多数为埋藏阶段形成的白云岩,同时大量研究也证实地层中大部分白云岩形成于埋藏环境。国际学术界对埋藏环境白云石的成因结构分类比较细致,但在我国这方面的研究还不够深入,因此本文借助国际上对埋藏环境白云石成因结构的分类方法,并结合中国白云岩研究的实际情况尝试提出埋藏环境白云石结构分类方案。该方案首先以白云石在岩石中的产状分为基质白云石和胶结白云石两大类,再以晶粒大小、晶型、晶面特征、接触关系为分类依据,将埋藏环境白云石分为六种结构类型。     

准噶尔盆地西北缘克百地区二叠系沉积特征及沉积模式

准噶尔盆地西北缘二叠系是重要的产油层和储集层,通过岩心观察、薄片分析,结合测井和录井资料,对西北缘克百断裂下盘二叠系砂砾岩的沉积环境和沉积特征进行了深入研究。研究表明,该区砂砾岩既有水上冲积扇沉积环境沉积的,也有水下扇三角洲前缘沉积环境形成的。前者主要为棕褐色、泥质杂基含量高、分选和磨圆差,储层物性相对较差;后者经过了稳定水流的淘洗,杂基含量少,钙质或沸石类胶结发育,分选性和磨圆度也较高,其物性条件也明显较好。并据此建立了研究区冲积扇与扇三角洲有机结合的沉积模式,该模式突出了湖岸线的重要性,同时模糊冲积扇与扇三角洲之间的界限。并对冲积扇与扇三角洲各亚相的岩性特征、沉积结构和沉积序列进行了归纳和总结,为该区寻找二叠系优质储层提供借鉴和思路。     

豫西嵩县前范岭石英脉型钼矿床地质特征及辉钼矿Re-Os同位素年龄

位于熊耳山-外方山地区的前范岭钼矿是东秦岭地区新近发现的石英脉型钼矿床之一。赋矿围岩为古元古界熊耳群安山质火山岩类。矿体主要以含辉钼矿石英脉产出,矿石类型以石英脉型为主。金属矿物以辉钼矿和黄铁矿为主,脉石矿物以石英为主,其次为方解石、萤石等。围岩蚀变类型有硅化、钾长石化、青磐岩化等。对6件辉钼矿样品进行Re-Os同位素测年所获得的模式年龄为233.3±3.3～248.2±3.5Ma,等时线年龄为239±13Ma,表明矿床形成于中三叠世。矿床的成矿作用发生于华北与扬子两个板块碰撞对接的晚期阶段。区域上整体的挤压造成了局部的剪切和伸展环境,这种环境为控矿断裂的形成和成矿流体的运移提供了有利条件。嵩县境内现已发现的多处脉型钼矿床很可能形成于同一时期(三叠纪),它们构成了熊耳山与外方山之间的嵩县脉型钼矿田。     

晚古生代古亚洲洋俯冲作用:来自珲春前山镁铁质侵入岩的年代学和地球化学记录

珲春地区前山镁铁质侵入岩主要由橄榄辉长岩、苏长岩和辉长闪长岩组成,形成年龄273±2Ma,为早二叠世侵入岩。该岩体显示出岛弧拉斑玄武岩的元素地球化学特征,弱富集LREE且正Eu(Eu/Eu*=1.05～1.44)异常的REE配分模式,在不相容元素中富集大离子亲石元素(LILE)如Ba和Sr,亏损高场强元素(HFSE)(La/Nb=2.8～4.8;Zr/Sm=8.0～22.5),与起源于流体交代地幔楔部分熔融的岛弧低钾拉斑玄武岩类似。在同位素特征上低放射成因Sr,高放射成因Nd和Hf(87Sr/86Sr(i)=0.70295～0.70375;εNd(t)=+4.5～+6.4;εHf(t)=+9.6～+14.6),反映其来源于同位素组成亏损的交代地幔。结合区域地质背景,我们认为前山镁铁质岩形成于晚古生代期间古亚洲洋向华北板块的俯冲作用背景,其亏损Nb-Ta、Zr-Hf及Hf-Nd同位素解耦特点说明该岩体最有可能来源于俯冲流体交代的地幔楔。     

Mississippian (Early Carboniferous) stromatolite mounds in a fore-reef slope setting, Laibin, Guangxi, South China

The Mississippian (Early Carboniferous) is generally a period of scarce carbonate buildups in South China. This study documents outcrops of stromatolite mounds at Mengcun and Helv villages, in Laibin City, Guangxi Province, South China. The stromatolite mounds contain various stromatolite morphologies including laminar, wavy-laminar, domal or hemispheroidal, bulbous, and flabellate-growth columns. Intramound rocks are brachiopod floatstone and dark thin-bedded laminated micrite limestone. Individual stromatolites at Mengcun village are generally 3–6 cm thick and morphologically represent relatively shallow-water laminar (planar and wavy-undulated stromatolites) and deeper-water domal, bulbous and columnar forms. Where mounds were formed, the stromatolites continued growing upward up to 60 cm thick. Thrombolitic fabrics also occur but are not common. Stromatolite microscopic structure shows the bulk of the lamination to consist of wavy microbialite and discrete thin micritic laminae. These mounds are intercalated in deep-water fore-reef talus breccia, packstone formed as a bioclastic debris flow and thin-bedded limestone containing common chert layers of the Tatang Formation (late Viséan). Further evidence supporting the deep-water setting of the stromatolite mounds are: (1) a laterally thinning horizon of brachiopod floatstone containing deep-water, small, thin-shelled brachiopods, peloidal micritic sediments and low-diversity, mixed fauna (e.g., thin-shelled brachiopods, tube-like worms and algae) that have been interpreted as storm deposits, (2) common fore-reef talus breccias, (3) lack of sedimentary structures indicating current action, (4) preservation of lamination with sponge spicules, and (5) lack of bioturbation suggesting that the stromatolites grew in a relatively low energy, deep-water setting. The stromatolite mounds are the first described stromatolite mounds in Mississippian strata of South China and contain evidence that supports interpretations of (1) growth history of Mississippian microbial buildups and (2) environmental controls on stromatolite growth and lithification.     

Pattern of abrupt climatic fluctuation in the East Asian Monsoon during the Last Glacial: Evidence from Chinese loess records

Records of two loess sections located in mid-eastern and western margins of the East Asian Monsoon area captured 20 Dansgaard-Oescher events and six Heinrich events. All these suggested that the climate in the East Asian Monsoon area fluctuated rapidly on millennial to century timescales during the whole Last Glacial. We found that these loess-based events of rapid climate fluctuations were generally synchronous with those of GRIP records, but that there were differences between the Shagou loess section in the west and the Wangguan loess section in the east: the former was more sensitive to climate change than the latter. Compared with earlier studies on loess records covering the Last Glacial from neighboring areas, we discovered that the magnitude of Dansgaard-Oeschger cycles decreased gradually from west to east and we suggest that it resulted from the combined effect of the Westerlies and the East Asian Monsoon.