A combined geochronological and geochemical investigation for the same domain of zircon provides valuable information on timing and genesis, particularly in the case of multi‐growth metamorphic zircon. A high spatial resolution concurrent analytical method for zircon U‐Pb age and rare earth element content was successfully achieved in this study, using a multi‐collector secondary ion mass spectrometer (SIMS) at a ~ 8 μm diameter scale. Special instrument parameters were employed, including a high mass resolution of approximately 15000 applied to replace the previous energy filter method, and a dynamic multi‐collector mode used to reduce the measurement time to 18 min per analysis. Six zircon reference materials yielded precise and accurate 206Pb/238U ages, which are comparable to those obtained by the ordinary mono‐collector method, but with 2–3 times higher spatial resolution. All zircon grains measured in this study showed enriched heavy‐REE (HREE) contents consistent with previously reported values determined by LA and solution ICP‐MS methods. The light‐REE (LREE) mass fractions measured using both SIMS and LA‐ICP‐MS methods in this study, although with quite different volume, show consistent results within uncertainties. 相似文献
Based on the three-dimensional digital image correlation (3D-DIC) technique, the stereovision system has been applied to the improved triaxial apparatus to obtain 3D full-field deformation of the specimen during triaxial testing. Through the calibration process, the 3D-DIC technique can obtain the accurate specimen’s spatial displacement deformation. Meanwhile, a subpixel edge detection algorithm has been combined with 3D-DIC technique to calculate the radial strain and the volume strain of the specimen directly. Furthermore, a series of consolidated drained and undrained triaxial tests were carried out on Hainan (China) sand specimens and measured by the conventional and the image measurement methods. Compared to the results measured by the conventional method, the image measurement technique can obtain the more experimental data, such as the 3D displacement field of the whole specimen, the local strain distribution, and so on. The measurement results also show the conventional method would be disturbed by the end constraints in triaxial tests so that the strength of the soil would be overestimated. Meanwhile, the middle of the specimen would be selected to calculate the stress–strain relationship without the influence of the end constraints in the proposed method. Based on the image measurement results, the proposed method has the potential to be used in geotechnical tests for exploring the soil’s progressive failure behaviors, inhomogeneous deformation and mechanical characteristics.
Stochastic Environmental Research and Risk Assessment - Storm surges, which may cause considerable casualties and economic losses, are among the most serious natural disasters that threaten the... 相似文献
Groundwater elevation fluctuation has been recognized as one mechanism causing temporal indoor air volatile organic chemical (VOC) impacts in vapor intrusion risk assessment guidance. For dissolved VOC sources, groundwater table fluctuation shortens/lengthens the transport pathway, and delivers dissolved contaminants to soils that are alternating between water saturated and variably saturated conditions, thereby enhancing volatilization potential. To date, this mechanism has not been assessed with field data, but enhanced VOC emission flux has been observed in lab-scale and modeling studies. This work evaluates the impact of groundwater elevation changes on VOC emission flux from a dissolved VOC plume into a house, supplemented with modeling results for cyclic groundwater elevation changes. Indoor air concentrations, air exchange rates, and depth to groundwater (DTW) were collected at the study house during an 86-d constant building underpressurization test. These data were used to calculate changes in trichloroethylene (TCE) emission flux to indoor air, during a period when DTW varied daily and seasonally from about 3.1 to 3.4 m below the building foundation (BF). Overall, TCE flux to indoor air varied by about 50% of the average, without any clear correlation to changes in DTW or its change rate. To complement the field study, TCE surface emission fluxes were simulated using a one-dimensional model (HYDRUS 1D) for conditions similar to the field site. Simulation results showed time-averaged surface TCE fluxes for cyclic water-table elevations were greater than for stationary water-table conditions at an equivalent time-averaged water-table position. The magnitudes of temporal TCE emission flux changes were generally less than 50% of the time-averaged flux, consistent with the field site observations. Simulation results also suggested that TCE emission flux changes due to groundwater fluctuation are likely to be significant at sites with shallow groundwater (e.g., < 0.5 m BF) and permeable soil types (e.g., sand). 相似文献
Water Resources - The Kuye river watershed is a coal mining watershed in Northwest China. The study analyzed runoff change of year, high flow period and low flow period in the past 60 years based... 相似文献