Arsenic remobilization from sediments contaminated with mine tailings near the Adak mine in Västerbotten district (northern Sweden)

Weathering of mine tailings have resulted in high As concentrations in water (up to 2900 μg l^− 1) and sediment (up to 900 mg kg^− 1) samples around the Adak mine. Notably, As occurs as As(III) species (15–85%) in the oxic surface and ground water samples, which is not common. Time-series based sediment incubations were set up in the laboratory with contaminated sediments to study the microbial processes involved in transformation and remobilization of As across the sediment–water interface. The microcosm experiments indicate that microorganisms are capable of surviving in As-rich sediments and reduce As(V) to As(III). A decrease in total As concentration in sediments is coupled to an increase in As(III) concentration in the aqueous media. In contrast, the controls (treated with HgCl₂ and formaldehyde) did not show growth, and As(V) concentrations increased steadily in the sediments and aqueous medium. The results imply that active metabolism is necessary for As(V) reduction. These microorganisms possess reduction mechanisms that are not necessarily coupled to respiration, but most likely impart resistance to As toxicity.     

Groundwater ‐ the disregarded component in lake water and nutrient budgets. Part 1: effects of groundwater on hydrology

Lake eutrophication is a large and growing problem in many parts of the world, commonly due to anthropogenic sources of nutrients. Improved quantification of nutrient inputs is required to address this problem, including better determination of exchanges between groundwater and lakes. This first of a two‐part review provides a brief history of the evolution of the study of groundwater exchange with lakes, followed by a listing of the most commonly used methods for quantifying this exchange. Rates of exchange between lakes and groundwater compiled from the literature are statistically summarized for both exfiltration (flow from groundwater to a lake) and infiltration (flow from a lake to groundwater), including per cent contribution of groundwater to lake‐water budgets. Reported rates of exchange between groundwater and lakes span more than five orders of magnitude. Median exfiltration is 0.74 cm/day, and median infiltration is 0.60 cm/day. Exfiltration ranges from near 0% to 94% of input terms in lake‐water budgets, and infiltration ranges from near 0% to 91% of loss terms. Median values for exfiltration and infiltration as percentages of input and loss terms of lake‐water budgets are 25% and 35%, respectively. Quantification of the groundwater term is somewhat method dependent, indicating that calculating the groundwater component with multiple methods can provide a better understanding of the accuracy of estimates. The importance of exfiltration to a lake budget ranges widely for lakes less than about 100 ha in area but generally decreases with increasing lake area, particularly for lakes that exceed 100 ha in area. No such relation is evident for lakes where infiltration occurs, perhaps because of the smaller sample size. Copyright © 2014 John Wiley & Sons, Ltd.     

Transit times of water under steady stormflow conditions in the Gårdsjön G1 catchment

In this paper we report on a series of replicated tracer experiments with deuterium conducted under controlled, steady stormflow conditions at the Gårdsjön G1 catchment in south‐western Sweden. In five different years, these experiments were carried out in a subcatchment of G1. Deuterium was applied as a narrow pulse so that distributions of water transit times could be directly inferred from the observed tracer breakthrough curves. Significantly different transit times of water were observed under similar experimental conditions. Coefficients of variation for estimated mean transit times were greater than 60%, which can be understood as a measure of the interannual variability for this type of experiments. Implications for water transit times under more natural flow conditions as wells as for future experimentation are discussed. Copyright © 2015 John Wiley & Sons, Ltd.     

The role of technology for achieving climate policy objectives: overview of the EMF 27 study on global technology and climate policy strategies

This article presents the synthesis of results from the Stanford Energy Modeling Forum Study 27, an inter-comparison of 18 energy-economy and integrated assessment models. The study investigated the importance of individual mitigation options such as energy intensity improvements, carbon capture and storage (CCS), nuclear power, solar and wind power and bioenergy for climate mitigation. Limiting the atmospheric greenhouse gas concentration to 450 or 550 ppm CO₂ equivalent by 2100 would require a decarbonization of the global energy system in the 21^st century. Robust characteristics of the energy transformation are increased energy intensity improvements and the electrification of energy end use coupled with a fast decarbonization of the electricity sector. Non-electric energy end use is hardest to decarbonize, particularly in the transport sector. Technology is a key element of climate mitigation. Versatile technologies such as CCS and bioenergy are found to be most important, due in part to their combined ability to produce negative emissions. The importance of individual low-carbon electricity technologies is more limited due to the many alternatives in the sector. The scale of the energy transformation is larger for the 450 ppm than for the 550 ppm CO₂e target. As a result, the achievability and the costs of the 450 ppm target are more sensitive to variations in technology availability.     

Rings Around Planets, Atmospheric Superrotation, and Their Great Spots

A common explanation is offered of the facts that the (outer) planets Jupiter, Saturn, Uranus, and Neptune (i) have ring systems inside their magnetospheres, (ii) show alternating atmospheric super- and sub-rotation in latitude belts, and (iii) have great (coloured) whirling spots in their atmospheres, at latitudes of maximal shear flow. The common reason, so we argue, is the action of magnetic torques between the various ring systems in non-synchronous rotation which drive electric currents, help ionize the orbiting gas, and redistribute angular momentum. Very similar reasoning has been used earlier – though incorrect in detail – to explain the complicated system of torsional oscillations in the solar convection zone.     

Arsenic in shallow groundwater of Bangladesh: investigations from three different physiographic settings

Occurrences of arsenic (As) in the Bengal Basin of Bangladesh show close relationships with depositional environments and sediment textures. Hydrochemical data from three sites with varying physiography and sedimentation history show marked variations in redox status and dissolved As concentrations. Arsenic concentration in groundwater of the Ganges Flood Plain (GFP) is characteristically low, where high Mn concentrations indicate redox buffering by reduction of Mn(IV)-oxyhydroxides. Low DOC, \( {\text{HCO}}^{ - }_{3} \), \( {\text{NH}}^{ + }_{4} \) and high \( {\text{NO}}^{ - }_{3} \) and \( {\text{SO}}^{{2 - }}_{4} \) concentrations reflect an elevated redox status in GFP aquifers. In contrast, As concentration in the Ganges Delta Plain (GDP) is very high along with high Fe and low Mn. In the Meghna Flood Plain (MFP), moderate to high As and Fe concentrations and low Mn are detected. Degradation of organic matter probably drives redox reactions in the aquifers, particularly in MFP and GDP, thereby mobilising dissolved As. Speciation calculations indicate supersaturation with respect to siderite and vivianite in the groundwater samples at MFP and GDP, but groundwater in the GFP wells is generally supersaturated with respect to rhodochrosite. Values of log P_CO2 at MFP and GDP sites are generally higher than at the GFP site. This is consistent with Mn(IV)-redox buffering suggested at the GFP site compared to Fe(III)-redox buffering at MFP and GDP sites.