Carbonate Sequence Stratigraphy of a Back-Arc Basin： A Case Study of the Qom Formation in the Kashan Area, Central Iran

The Qom Formation comprises Oligo-Miocene deposits from a marine succession distributed in the Central Basin of Iran. It is composed of five members designated as A-F. Little previous work exists on the sequence stratigraphy. Based on an integrated study of sequence stratigraphy with outcrop data, wells and regional seismic profiles, the Qom Formation is interpreted as a carbonate succession deposited in a mid-Tertiary back-arc basin. There are two second-order sequences (designated as SS1 and SS2) and five third-order sequences (designated as S1-S5). Five distinct systems tracts including transgressive, highstand, forced regressive, slope margin and lowstand have been recognized. The relationship between the sequences and lithologic sub-units has been collated and defined (S1 to S5 individually corresponding to A-C1, C2-C4, D-E, the lower and upper portions of F); a relative sea level change curve and the sequence stratigraphic framework have been established and described in detail. The coincidence of relative sea level change between that of the determined back-arc basin and the world indicates that the sedimentary cycles of the Qom Formation are mainly controlled by eustatic cycles. The variable combination of the systems tracts and special tectonic-depositional setting causally underpin multiple sequence stratigraphic framework styles seen in the carbonates of the back-arc basin revealing: (1) a continental margin basin that developed some form of barrier, characterized by the development of multiple cycles of carbonate-evaporites; (2) a flat carbonate ramp, which occurred on the southern shelf formed by the lack of clastic supply from nearby magmatic islands plus mixed siliciclastics and carbonates that occurred on the northern shelf due to a sufficient clastics supply from the land; and (3) a forced regressive stratigraphic stacking pattern that occured on the southern shelf and in basin lows due to the uplifting of the southern shelf. Thick and widespread aggradational framework limestone usually occurs in the initial sequences (S1 and S3) of the supersequence, which led to preferential oil reservoir deposition but a lack of source and cap rocks, whereas the retrogradational and progradational framework limestone usually occurs in the later sequences (S2 and S4-S5) of the supersequence, which results in two perfect sets of source, reservoir and cap rock assemblies, so that the limestone in sub-member C2-C4 and the F-Member can be predicted as important objects for oil exploration.     

Subsolidus Phase Relations in the System MgO-SiO_2-Cr-O and Thermodynamic Properties of Related Cr~(2+)-Containing End-members

Subsolidus phase relations have been determined in the systems SiO2-Cr-O and MgO-SiO2-Cr-O in equilibrium with metallic Cr, at 1100 to 1500℃ and 0 to 2.88 GPa. The results show that there are no ternary phases in the SiO2-Cr-O system at these conditions, i.e., only the assemblage eskolaite-Cr-metal-quartz (or tridymite) is found. In the MgO-containing system, however, extensive substitution of Cr2+ for Mg is observed in (Mg, Cr2+)2SiO4 olivine, (Mg, Cr2+)2Si2O6 pyroxene, and (Mg, Cr2+)Cr2O4 spinel. Cr3+ levels in olivine and pyroxene are below detection limits. The pyroxene is orthohombic at XCrPx2+ < 0.2, monoclinic at higher XCrPx2+ . Thestructure of the spinels becomes tetragonally distorted at XCr2+Sp >0.2. The experimental datahave been fitted to a thermodynamic model, and the authors obtained the mixing parameter (W) of Mg-Cr2+ in olivine, pyroxene and spinel, and the relation between temperatures and free energies of formation for the end-members: Cr2+-olivine (Cr2SiO4), Cr2+-pyroxene (Cr2Si2O6)     

铀对(Ⅱ型)低熟烃源岩生烃演化的影响Ⅱ

在油、气、煤、铀多种能源矿产形成演化富集成藏(矿)过程中,有机-无机相互作用是普遍存在的,在有机质的强大吸附作用及其所提供的还原环境为铀的富集成矿起促进作用的同时,铀也改变了烃源岩的生烃演化进程。本文在Ⅱ型低熟烃源岩中加入碳酸铀酰溶液的条件下进行了生烃模拟实验,对比无铀-加铀样品生烃模拟实验产物的相关参数,以探讨油气生成过程中无机铀所起的作用。从实验结果可以看出,铀可以使产物中不饱和烃向饱和烃转化;促进长链烃的裂解,促进低分子量烃类的产生,从而使CH4的含量提高,使生成的烃类的干气化程度增加。铀可以在低温阶段促进有机质的成熟度,降低烃源岩的生烃门限,使低熟烃源岩早期生成烃类;同时在高温阶段阻止有机质过度成熟,利于所生成烃的保存。因而铀可能是未熟-低熟油气生成可能的无机促进因素之一。     

HDTMA+柱撑离子空间几何尺寸与柱撑蒙脱石层间排列方式的研究

用X射线衍射方法对不同柱撑浓度条件下制备的HDTMA^ 柱撑蒙脱石系列样品进行研究，结合有机离子的理论空间几何尺寸，提出有机柱撑离子在层间的不同排列展布方式。水平单层排列的HDTMA^ 离子可以有两种不同的排列方式并分别对应于柱撑产物的不同底面间距，水平双层排列虽然也可形成两种不同的排列方式，但是柱撑产物具有相同的底面间距，并用联锁嵌合结构解释了有机离子在水平双层和假三层排列模式下其实际总体高度要低于各单层高度数字之和。     

应用激光喇曼光谱特征参数反映有机碳质的成熟度

激光喇曼光谱技术具有测试简便和准确等优点，有机碳质物的激光喇曼光谱参数可以作为成熟度指标。并计算出镜质体反射率与激光喇曼光谱参数的回归关系式，喇曼光谱成熟度指标对应的成熟度范围为2.1%-15.0%(Ro)。     

广东温泉水-汽转化过程对室内氡浓度的影响

研究了广东省四家温泉宾馆室内温泉水及其使用过程中对氡浓度的影响。利用RAD-7测氡仪和NR667A测氡义连续测量室内外氡浓度和水氡浓度,发现室内氡浓度受地基土壤、建筑物类型、利用方式(是否洗浴、洗浴时间长短等)、通风状况等诸多因素的影响。无人入住时宾馆室内氡浓度的变化说明土壤氡的渗入是底层房间室内氡的重要影响因素。当在浴室内使用温泉水洗浴时,浴室内平均氡浓度比没有用温泉水时高出1～8．3倍,客房内氡浓度比没有用温泉水洗浴时高出1．2～8．3倍。在使用温泉水时,某些宾馆室内氡浓度超标,可能对宾馆工作人员造成潜在的健康危害,应采取管理措施或技术手段降低其暴露水平。     

Re-Os and U-Pb Geochronology of the Erlihe Pb-Zn Deposit,Qinling Orogenic Belt,Central China,and Constraints on Its Deposit Genesis

The Erlihe Pb-Zn deposit is an important mine of the Pb-Zn metallogenic zone in the South Qinling Orogen.It has been considered a sedimentary exhalative deposit in previous investigations because the ore body occurs concordantly at the transitional location of an upright fold.Re and Os isotopic analyses for paragenetic pyrites with sphalerite and galena from the ore body have been used to determine the timing of mineralization and to trace the source of metallogenic materials.The Re-Os isotopic data of f...     

长江中下游地区早白垩世埃达克质岩的大地构造背景及其成矿意义

长江中下游地区是中国重要的铜资源基地之一。该成矿带广泛发育与Cu-Au成矿作用密切相关的早白垩世火成岩。大多数与成矿有关的中酸性侵入岩具有类似埃达克岩的地球化学特征,即富集Sr而贫HREE(如:Y和Yb);但它们具有负的εNd(t)值和相对富集的Sr同位素初始比值(>0.704.),因此,被称为埃达克质岩。根据岩石化学数据,研究区埃达克质侵入岩多数属于高钾钙碱性系列,部分属于钙碱性系列;而火山岩和A型花岗岩类由于其高钾和富铁特征而属于钾质碱性系列。岩石地球化学资料显示,与成矿作用有关的中酸性埃达克质侵入岩经历了复杂的成岩过程,至少包括在深位岩浆房(>35～40 km深度)的分离结晶和在高位岩浆房内的分离结晶或AFC过程两个阶段。同时不排除有下地壳直接熔融形成的埃达克质熔体参与的可能性。富钾的火山岩则是原生岩浆在深位岩浆房(>40-50 km深度)经镁铁矿物的分离结晶过程演化而来。基于长江中下游地区及其邻区的区域地质构造、早白垩世岩浆岩的岩石化学和地球化学特征和岩浆活动的时空演变特征的综合分析,推测该成矿带在早白垩世早期处于大陆边缘岩浆弧内陆一侧,岩浆活动与古太平洋板块的斜向俯冲作用有关;晚期由于俯冲板片迁移(变陡),岩浆岩具有弧后环境特征。俯冲板片上部所释放的超临界流体提高了地幔     

鄂东南铜山口、殷祖埃达克质（adakitic）侵入岩的地球化学特征对比：（拆沉）下地壳熔融与斑岩铜矿的成因

鄂东南地区铜山口花岗闪长斑岩体是与斑岩铜钼矿床共生的岩体,但殷祖花岗闪长岩体是与金属成矿无关的岩体。铜山口和殷祖侵入岩的元素地球化学特征与埃达克岩的地球化学特征非常类似,如高Al2O3、Sr含量与La/Yb、Sr/Y比值,富Na2O(Na2O/K2O>1.0),亏损Y与Yb,极弱负Eu异常-正Eu异常以及正Sr异常等。但是铜山口和殷祖侵入岩也存在 明显的差别:前者比后者更偏酸性,但具有较高的K2O,MgO,Cr,Ni和Sr含量,较低的Y和Yb含量,轻重稀土元素分异更明显,并主要显示出正铕异常,区别于后者的极弱负Eu异常-不明显Eu异常。这表明铜山口埃达克质侵入岩的岩浆来源可能比殷祖埃达克质侵入岩的岩浆来源更深:前者可能由拆沉的下地壳熔融形成,残留物主要含石榴子石;而后者可能由增厚的下地壳熔融形成,残留物可能为石榴子石±斜长石±角闪石。另外,热的地幔上涌,底辟(diapir)进入下地壳,导致含角闪石的榴辉岩发生熔融也可形成铜山口埃达克质岩浆。铜山口埃达克质岩浆在穿过地幔的过程中,将会与地幔橄榄岩发生交换反应:一方面由于受橄榄岩的混染而使得岩浆的MgO,Cr和Ni增高;另一方面岩浆中的Fe2O3不断加入到地幔中,导致地幔的氧逸度(fo2)增高,地幔中金属硫化物被氧化并进入岩浆中,富含Cu-Mo等成矿物质的岩浆上升很容易形成斑岩铜钼矿     

桑干地区高压麻粒岩中石榴石和斜长石的连续激光探针~(40)Ar~-~(39)Ar等时年龄及其地质意义

采用微区激光探针４０Ａｒ－３９Ａｒ定年方法, 对华北桑干地区高压基性麻粒岩中变质石榴石和斜长石直接进行了原位微区年代测定。石榴石变斑晶是高压麻粒岩相变质作用形成的矿物,石榴石周围后成合晶反应边组合中的斜长石是石榴石减压分解的产物。石榴石斑晶的４０Ａｒ－３９Ａｒ等时线年龄为２５１０ Ｍａ, 证明高压变质作用发生在太古宙末。斜长石４０Ａｒ－３９Ａｒ等时线年龄为１９６８Ｍａ, 代表石榴石在中压麻粒岩相条件下分解的时代。它们之间年龄相差大于５００Ｍａ, 说明高压麻粒岩可能没有经历近等温减压的ＰＴ轨迹。后成合晶组合很可能代表中压麻粒岩相变质作用的叠加。这一结果对探讨华北克拉通桑干地区早期地壳的构造演化具有重要意义。