青藏高原东缘古近纪粗碎屑岩沉积学及其构造意义

青藏高原东缘古近纪盆地的填图和沉积学研究表明,在青藏高原东缘区域性走滑-挤压构造背景下形成的古近纪盆地内广泛发育厚层—巨厚层状的紫红色粗碎屑岩系。其沉积特征指示为一种近源快速堆积的泥石流和辫状河道沉积体,形成于干旱炎热气候条件下的典型陆内冲积扇环境。盆地充填序列、粗碎屑岩层序、动植物化石和盆地内岩浆岩~(40)Ar-~(39)Ar年代学等综合研究结果表明,古近纪盆地内粗碎屑岩大约形成于38～29 Ma。该时期与青藏高原东缘北段(横断山地区)古近纪盆地的形成和南段(兰坪—思茅地区)大盆地的裂解时间基本一致,这很可能预示着青藏高原在晚始新世—早渐新世期间曾发生过整体的快速构造隆升。     

东秦岭北部富碱侵入岩带岩石地球化学特征及构造意义

在东秦岭北部,富碱侵入岩的侵位与空间分布受同一个区域构造带(华北陆块南缘)控制,构成一个区域性的富碱岩浆岩带。根据岩石学和岩石化学研究,岩石类型主要分为碱性正长岩、碱性花岗岩和石英正长岩三大类。富碱岩浆岩带自北而南可以划分为3个亚带:北部碱性正长岩亚带,中部碱性花岗岩亚带,南部石英正长岩亚带。3个亚带富碱岩浆在化学成分方面虽有差异,但都具有富碱高钾特征,ALK=9～15,ω(K_2O)为5％～15％,ω(K_2O)/ω(Na_2O)=1.26～8.30。岩石中的暗色矿物辉石类主要为霓辉石和霓石,角闪石类主要为钙质浅闪石、阳起石质闪石、镁质角闪石、钠钙质绿闪石,黑云母类主要为铁云母和金云母。岩石中的长石类主要为K-Na系列富K端员的微斜长石和最大微斜长石,少量钠长石,极少Na-Ca系列的斜长石。霞石类主要为钾霞石和钙霞石。根据岩石地球化学研究,有以下显示:(1)REE总量200～1100μg/g,LREE/HREE比值4～15,δEu表现为无Eu异常或轻微正负Eu异常,(La/Yb)_n值多为10～30;(2)部分岩石类型富集大离子亲石元素,不相容元素分布模式曲线总斜率为负,Ba,Nb,Zr具明显负异常,表明他们具有大陆裂谷碱性花岗岩的特征;(3)岩石Nd、Sr和Pb同位素的研究表明,富碱侵入体的源区应是以下地壳为主,带入少量地幔和上地壳物质。     

Diagenesis and Evolution of the Holocene Coquinite from the Haishan Island,Eastern Guangdong,China

The coastal hard rock with a thickness of over 5 m and a distribution area of nearly 200 ha in the Haishan Island,south China,has long drawn researchers' attention.However,there were controversies over its formation and classification,and these controversies in turn lead to the dispute of sea level changes and coastal uplift-subsidence of this area.To investigate its diagenesis and evolution,petrographic analysis,elemental geochemistry,isotopic analysis,and radiocarbon dating were used in the present stu...     

The Occurrence of Oleananes in the Beibuwan Basin and Its Application to the Study of Maturity and Oil-Source Rock Correlation

The oleanane parameter, i.e., OP （oleananes/（oleananes＋C30hopanes）） in the two sedimentary columns of the Beibuwan Basin, South China Sea, can be used to delimit the top of oil generation window, with Ro （/%） of 0.53 in Well M1 and 0.55 in Wells H1/Hd1/Hd2, respectively. Comparing with vitrinite reflectance （Ro/%）, the OP features a dynamic range and can indicate the oil generation window more precisely. By using OP and other geochemical indices, the oil-source correlation is also conducted. It suggests that the oils in wells M1 and M2 are derived from the source rocks in situ. The mudstone in Huachang uplift is not the main source rocks for oils in this area, The OP is also a useful oil-source correlation parameter in some Tertiary lacustrine basins.     

扫描电镜—能谱在单个包裹体物质组成研究中的应用

利用扫描电镜－能谱对四川冕宁稀土矿床早期萤石的单个流体－熔融包裹体的成分进行了分析,发现包裹体内流体相离子以Ｎａ、Ｃａ、Ｂａ为主,阴离子以ＳＯ４、Ｆ、Ｃｌ米,有意义的是在包裹体中发现了Ｌａ、Ｃｅ、Ｎｄ等稀土元素,其中矿化元素素铈的含量最高,研究结果进一步证明四川冕宁稀土矿床是一个与盐熔体有关的热液矿床。     

方石英的亚稳态形成机制探讨

方石英形成于石英或鳞石英热力学稳定区是一种普遍的现象，并基本上是由非晶态SiO2转变而成。方石英的这种亚稳态形成机制可用Ostwald分步规则这一动力学经验规律来阐述；而引起非晶态SiO2转变成方石英的速率常数大大高于方石英转变成石英或鳞石英的速率常数的本质是非晶态SiO2局部中程有序结构与β—方石英的动态无序结构的相似性；这种相似性使非晶态SiO2结晶过程中β—方石英的有效成核速率大大增加，并最终导致亚稳态方石英的形成。非晶态SiO2中所含的杂质元素有利于降低方石英的形成温度，加速反应进程，但对于亚稳态方石英的形成没有决定作用，除非这些杂质元素有利于方石英结构的稳定性。     

哀牢山-金沙江碱性岩带南段云南金平八一村钾质碱性花岗岩锆石SHRIMP U-Pb年龄

云南省金平县八一村钾质碱性花岗岩中的锆石由岩浆锆石和岩浆复合型锆石(老核新壳锆石)组成，以后者居多。锆石定年结果表明，岩浆锆石和岩浆复合型锆石的新壳SHRIMP U-Pb年龄为37Ma，反映岩浆上侵定位时的结晶时间，相当于始新世晚期。锆石老核获得的最大年龄为510Ma和177Ma，相当于晚寒武世和中侏罗世，表明该岩体保存有寒武纪和侏罗纪地质事件信息，而42～48Ma年龄可能是混合年龄。最后对锆石的成因和花岗岩的成岩机制等进行了初步探讨。     

重金属在碳酸钙—水界面间的沉淀反应特征

首先进行Cu^2 ,Pb^2 和Cd^2 等重金属离子溶液与方解石和轻质碳酸钙间的沉淀反应实验，然后对方解石与重金属离子的反应产物作了SEM观察与EDS能谱分析，研究表明，在本文的实验条件下，重金属与碳酸钙间的表面反应主要表现为表面沉淀，其中，Cd^2 离子在界面中的行为还涉及晶格扩散作用。     

云南大平糜棱岩化碱性花岗岩岩石地球化学特征及成因讨论

本文在野外工作基础上,系统研究了云南大平糜棱岩化碱性花岗岩岩石结构构造、矿物组成、主微量元素和锆石特征等。根据岩体本身还残留有层理,在糜棱岩化之前的岩石具花岗变晶结构和含有反映区域变质成因的钠铁闪石造岩矿物,以及锆石高度富集和显示有一定层位等,认为云南大平糜棱岩化碱性花岗岩为沉积变质成因。     

Seismic Velocity Structure and Composition of the Continental Crust of Eastern China

On the basis of a one-by-one latitude-longitude grid three-dimensional seismic velocity model, the crustal P-wave velocity structure in eastern China (105-125°E and 18-41°N) is obtained, and a set of geotherms for each grid is established for P-T correction on P-wave velocities. The average depths of sub-crustal layers and their average P-wave velocities of 18 tectonic units in eastern China are exhibited. Our result presents a 32-34 km thick crust beneath eastern China, which is thinner than previous studies, with an average velocity of 6.54 km/s, corresponding to a 5 kg/m3 variation in crustal mean density. The thicker upper but thinner middle and lower crust results in a lower average seismic velocity of eastern China. An intermediate crustal composition with a SiO2 content of 59.7 wt% has been estimated. However, there exists a significant lateral variation in the crustal structures among the tectonic units of eastern China. The structure and composition features of some regions in eastern China in