Ab initio prediction of 29Si-NMR chemical shifts

The ability of several ab initio models to predict experimental ²⁹Si-NMR chemical shift is examined. The shielding values of trimethylsilyl chloride (A), t-butyldimethylsilyl chloride (B) and allytrimethylsilane (C) are calculated by GIAO, CSGT and IGAIM methods, using HF/6–31G^*, B3LYP/6-31G^*, HF/6–311+G^**, B3LYP/6–311+G^** and MPW1PW91/6–311+G^** models respectively. The ²⁹Si chemical shifts calculated by GIAO method using HF/6–311+G^** model are highly in agreement with those obtained experimentally. All of the models above reproduce the trends of chemical shifts in all cases studied, suggesting that the models are of practical value.     

Last glacial terrestrial vegetation record of leaf wax n-alkanols in the northern South China Sea: Contrast to scenarios from long-chain n-alkanes

Long-chain n-alkanols and n-alkanes in core sediments from the northern South China Sea (SCS) were measured to make a comparison during terrestrial vegetation reconstruction from ~42 ka to ~7 ka. The results showed that terrestrial vegetation record from long-chain n-alkanes matched well with previous studies in nearby cores, showing that more C₄ plants developed during the Last Glacial Maximum (LGM) and C₃ plants dominated in the interglacial period. However, these scenarios were not revealed by terrestrial vegetation reconstruction using long-chain n-alkanols, which showed C₃ plant expansion during the LGM. The discrepancy during the interglacial period could be attributed to the aerobic degradation of functionalized long-chain n-alkanols in the oxygen-rich bottom water, resulting in poor preservation of terrestrial vegetation signals. On the other hand, the different advantages of functionalized n-alkanols and non-functional n-alkanes to record local and distal vegetation signals, respectively, may offer a potential explanation for the contradiction during the LGM when the SCS was characterized by low-oxygen deep water. Nevertheless, large variations on n-alkyl lipid compositions in C₃/C₄ plants could play a part in modulating sedimentary long-chain n-alkanols and n-alkanes toward different vegetation signals, thereby suggesting that caution must be taken in respect to the terrestrial vegetation reconstruction using long-chain n-alkanes and long-chain n-alkanols.     

Application research of narrow band Internet of things buoy and surface hydrodynamics monitoring

This paper applies the narrow band Internet of things communication technology to develop a wireless network equipment and communication system, which can quickly set up a network with a radius of 100 km on water surface. A disposable micro buoy based on narrow-band Internet of things and Beidou positioning function is also developed and used to collect surface hydrodynamic data online. In addition, a web-based public service platform is designed for the analysis and visualization of the data collected by buoys. Combined with the satellite remote sensing data, the study carries a series of marine experiments and studies such as sediment deposition tracking and garbage floating tracking.     

海湾扇贝肝素样多糖分离方法的研究

于1992年1月-1993年2月，对从海湾扇贝中提取获得的糖胺聚糖（GAG）用乙醇和溴化十六烷基三甲铵（CTAB）分级分离，并对所得制品用琼脂糖凝胶电泳和高效液相色谱验证，以研究一种简便、快速的分离提纯方法。结果表明，扇贝GAG水溶液在乙醇量60％时分离获得的级分，其GAG－GTAB给合物再用2.0 mol/LNaCl溶液解离得到的主要级分，琼脂糖凝胶电泳和高效液相色谱均显示出单一区带，红外光谱类似干肝素的。证明这一提纯过程是一简便、快速的分离提纯方法。     

Stress and deformation of offshore piles under structural and wave loading

Various offshore structures, especially large structures such as Tension Leg Platforms (TLP), are usually supported by concrete piles as the foundation elements. The stress distribution within such a large structure is a dominant factor in the design procedure of an offshore pile. To provide a more accurate and effective design for offshore foundation systems under axial and lateral wave loads, a finite element model is employed herein to determine the stresses and displacements in a concrete pile under similar loading conditions. A parametric study is also performed to examine the effects of the stress distribution due to the changing loading conditions.     

辽东半鸟南部寒武系与奥陶系的界线

在辽南瓦房店市长兴岛镇二龙山、长岭子等地的寒武纪—奥陶纪冶里组上部首次发现Saukia,Calvinella等属种的化石,确定了Saukia—Calvinella组合带,为晚寒武世凤山阶最顶部的化石带。此外在该带之上采到了微体化石Ulahconusbeimadaoensis,该化石属种为奥陶纪早期的标准分子。据此重新厘定了辽南地区寒武系与奥陶系的界线。     

往复活塞式制冷压缩机性能系数的曲面回归方程

采用非线性二乘法对国产１２．５系列往复活塞式制冷压缩机的实测性能数据进行拟合，得出描述该系列制冷压缩机性能系数与运行工况之间相关关系的曲面回归方程，为制冷系统的数值计算、动态特性模拟和优化设计提供数学模型。     

Study of a comprehensive assessment method of the environmental quality of soil in industrial and mining gathering areas

Industrial and mining activities have been recognized as major sources of heavy metal contamination in soil. Here, we developed a comprehensive assessment method for the soil environment in industrial and mining gathering areas based on the pressure–state–response model. Using this method, we assessed the environmental quality of soil in a typical industrial and mining gathering area in Tianjin City, China. The results are as follows: (1) The comprehensive environmental quality index of the soil in the study area was 0.532, which corresponds to an alert state and shows that the soil environment is generally poor. (2) The pressure, state, and response indexes were 0.609, 0.634, and 0.163, respectively, which suggests that the pressure in the soil environment of the study area is barely acceptable, and the state is merely passable. Furthermore, the response measures are not ideal. (3) The low response index scores indicate poor production processes, low pollutant treatment level, and unsatisfactory level of management by the enterprises in the study area. (4) The distribution of soil risks was found to be inseparably related to that of contamination sources and land use types. Furthermore, the distribution was uneven to a certain degree. Finally, we propose recommendations for the optimization, adjustment, and management of typical industrial and mining gathering areas with petrochemical, metallurgy, and other heavily polluting enterprises.     

关于因特网3S服务平台的搭建

3S集成 ,特别是广域网的 3S动态集成 ,是地理信息产业的发展趋势和方向 ,其归宿应该是数字地球。 3S集成系统用户应用服务平台搭建技术在概念层面与因特网 (万维网 )技术融合。开放的面向用户动态跟踪和导航用途的 3S集成系统 ,与因特网通信接口技术和用户界面技术相关。因特网 3S集成系统的功能及其运行效率是其具有实用价值的基础。     

EXPERIMENTAL STUDY ON SOIL MOISTURE USING DUAL-FREQUENCY MICROWAVE RADIOMETER

1INTRODUCTIONSoil is the basis of human's living. Soil moisture plays asignificant role in studying the matter and energy ex-changes in global hydrology sphere. The evaporation ofsoil moisture has an influence on the water vapor cycle.Meanwhile soil moisture is also one of the firsthandmeasurable parameters in crop yield estimation and wa-ter resources management (JACKSON et al., 1993). Theinfluence of the interaction of land and atmosphere onsoil moisture can bring about anomalous cli…