Natural Attenuation of Perchlorate in Denitrified Groundwater

Monitoring of a well‐defined septic system groundwater plume and groundwater discharging to two urban streams located in southern Ontario, Canada, provided evidence of natural attenuation of background low level (ng/L) perchlorate (ClO₄^?) under denitrifying conditions in the field. The septic system site at Long Point contains ClO₄^? from a mix of waste water, atmospheric deposition, and periodic use of fireworks, while the nitrate plume indicates active denitrification. Plume nitrate (NO₃^?‐N) concentrations of up to 103 mg/L declined with depth and downgradient of the tile bed due to denitrification and anammox activity, and the plume was almost completely denitrified beyond 35 m from the tile bed. The ClO₄^? natural attenuation occurs at the site only when NO₃^?‐N concentrations are <0.3 mg/L, after which ClO₄^? concentrations decline abruptly from 187 ± 202 to 11 ± 15 ng/L. A similar pattern between NO₃^?‐N and ClO₄^? was found in groundwater discharging to the two urban streams. These findings suggest that natural attenuation (i.e., biodegradation) of ClO₄^? may be commonplace in denitrified aquifers with appropriate electron donors present, and thus, should be considered as a remediation option for ClO₄^? contaminated groundwater.     

Numerical Modeling of Ice Fog in Interior Alaska Using the Weather Research and Forecasting Model

An ice microphysics parameterization scheme has been modified to better describe and understand ice fog formation. The modeling effort is based on observations in the Sub-Arctic Region of Interior Alaska, where ice fog occurs frequently during the cold season due to abundant water vapor sources and strong inversions existing near the surface at extremely low air temperatures. The microphysical characteristics of ice fog are different from those of other ice clouds, implying that the microphysical processes of ice should be changed in order to generate ice fog particles. Ice fog microphysical characteristics were derived with the NCAR Video Ice Particle Sampler during strong ice fog cases in the vicinity of Fairbanks, Alaska, in January and February 2012. To improve the prediction of ice fog in the Weather Research and Forecasting model, observational data were used to change particle size distribution properties and gravitational settling rates, as well as to implement a homogeneous freezing process. The newly implemented homogeneous freezing process compliments the existing heterogeneous freezing scheme and generates a higher number concentration of ice crystals than the original Thompson scheme. The size distribution of ice crystals is changed into a Gamma distribution with the shape factor of 2.0, using the observed size distribution. Furthermore, gravitational settling rates are reduced for the ice crystals since the crystals in ice fog do not precipitate in a similar manner when compared to the ice crystals of cirrus clouds. The slow terminal velocity plays a role in increasing the time scale for the ice crystals to settle to the surface. Sensitivity tests contribute to understanding the effects of water vapor emissions as an anthropogenic source on the formation of ice fog.     

Geochemical characterization of karst groundwater in the cradle of humankind world heritage site,South Africa

The karst of the Cradle of Humankind World Heritage Site plays a major role in the assimilation or carrying of acid mine drainage, sewage effluent return flow and agricultural run-off. Infiltration of contaminated water has altered the chemical composition of the natural waters of the karst system. A multivariate statistical method in combination with conventional geochemical and spatial analysis was applied on groundwater and surface water quality samples to determine the spatial extent of hydrochemical impacts from different anthropogenic sources. The application of hierarchical cluster analysis of the major ions (148 samples) recognised three distinct hydrochemical regimes. Cluster 1 is moderately mineralized, especially with regard to chloride, nitrate and sulphate, cluster 2 has a low mineralization with all elements well within the recommended drinking water limits of South Africa and cluster 3 represents highly mineralized samples taken in the vicinity of decanting mineshafts. The cluster solution is confirmed by a simple mixing model, indicating varying contributions of three identified end members (acid mine drainage, treated sewage effluents and pristine dolomitic groundwater) to the groundwater quality in the catchment. The combination of statistical, geochemical and spatial methods in conjunction with end-member mixing analysis provides a reliable method to understand the processes responsible for the groundwater quality variations and to assist in the identification of anthropogenic impacts.     

Progressive failure of sheeted rock slopes: the 2009–2010 Rhombus Wall rock falls in Yosemite Valley,California, USA

Progressive rock‐fall failures in natural rock slopes are common in many environments, but often elude detailed quantitative documentation and analysis. Here we present high‐resolution photography, video, and laser scanning data that document spatial and temporal patterns of a 15‐month‐long sequence of at least 14 rock falls from the Rhombus Wall, a sheeted granitic cliff in Yosemite Valley, California. The rock‐fall sequence began on 26 August 2009 with a small failure at the tip of an overhanging rock slab. Several hours later, a series of five rock falls totaling 736 m³ progressed upward along a sheeting joint behind the overhanging slab. Over the next 3 weeks, audible cracking occurred on the Rhombus Wall, suggesting crack propagation, while visual monitoring revealed opening of a sheeting joint adjacent to the previous failure surface. On 14 September 2009 a 110 m³ slab detached along this sheeting joint. Additional rock falls between 30 August and 20 November 2010, totaling 187 m³, radiated outward from the initial failure area along cliff (sub)parallel sheeting joints. We suggest that these progressive failures might have been related to stress redistributions accompanying propagation of sheeting joints behind the cliff face. Mechanical analyses indicate that tensile stresses should occur perpendicular to the cliff face and open sheeting joints, and that sheeting joints should propagate parallel to a cliff face from areas of stress concentrations. The analyses also account for how sheeting joints can propagate to lengths many times greater than their depths behind cliff faces. We posit that as a region of failure spreads across a cliff face, stress concentrations along its margin will spread with it, promoting further crack propagation and rock falls. Published in 2012. This article is a US Government work and is in the public domain in the USA.     

The use of plastic debris as nesting material by a colonial seabird and associated entanglement mortality

Entanglement with plastic debris is a major cause of mortality in marine taxa, but the population-level consequences are unknown. Some seabirds collect marine debris for nesting material, which may lead to entanglement. Here we investigate the use of plastics as nesting material by northern gannets Morus bassanus and assess the associated levels of mortality. On average gannet nests contained 469.91 g (range 0-1293 g) of plastic, equating to an estimated colony total of 18.46 tonnes (range 4.47-42.34 tonnes). The majority of nesting material was synthetic rope, which appears to be used preferentially. On average 62.85 ± 26.84 (range minima 33-109) birds were entangled each year, totalling 525 individuals over eight years, the majority of which were nestlings. Although mortality rates are high, they are unlikely to have population-level effects. The use of synthetic fibres as nesting material is a common strategy among seabirds, but the impacts of entanglement warrants further investigation.     

Development of tools to estimate conveyance losses in the Truckee River, USA

A method to estimate stream conveyance losses, including stream bank seepage and evapotranspiration from riparian areas, was developed for the Truckee River in California and Nevada (USA). Aquifer diffusivity is the primary variable required to compute aquifer head and seepage. Head and seepage conceptual models developed in previous studies were calibrated using stream stage and aquifer head at five sites along the Truckee River. The equations for head require numerical convolution to solve. It was found that head is insensitive to diffusivity and a single value for diffusivity provides good results at all study sites. Also, because releases from storage are usually prescribed as a step increase in flow for a given period of time followed by a step decrease in flow, an analytic solution for volume of seepage can be used in place of numerical convolution. Under typical operating conditions, seepage volume represents a small fraction of the total reservoir releases. Uncertainty in seepage estimates can be reduced with increased accuracy in hydraulic conductivity. This work demonstrates a valuable technique to estimate conveyance losses under natural and managed stream flow.     

Mineralogical and geochemical investigations of silicate-rich mine waste from a kyanite mine in central Virginia: implications for mine waste recycling

A kyanite mine in central Virginia produces a silicate-rich waste stream which accumulates at a rate of 450,000–600,000 tons per year. An estimated 27 million tons of this waste stream has accumulated over the past 60 years. Grain size distribution varies between 1.000 and 0.053 mm, and is commonly bimodal with modes typically being 0.425 and 0.250 mm and uniformity coefficients vary from 2.000 to 2.333. Hydraulic conductivity values vary from 0.017 to 0.047 cm/s. Mineralogy of the waste stream consists of quartz, muscovite, kyanite and hematite. Muscovite grains have distinct chemical compositions with significant Na₂O content (1.12–2.66 wt%), TiO₂ content (0.63–1.68 wt% TiO₂) and Fe content, expressed as Fe₂O₃ (up to 1.37 wt%). Major element compositions of samples were dominated by SiO₂ (87.894–90.997 wt%), Al₂O₃ (6.759–7.741 wt%), Fe₂O₃ (1.136–1.283 wt%), and K₂O (0.369–0.606 wt%) with other components being <1.000 wt%. Elements of environmental concern (V, Cr, Ni, Cu, Zn, As, Ag, Sn, Sb, Ba, Hg, Tl, and Pb) were detected; however, the concentrations of all elements except Ni were below that of the kyanite quartzites in the region from which the waste is derived. Both major and trace element compositions indicate minimal variation in composition. The waste stream has potential for recycling. Muscovite is suitable for recycling as a paint pigment or other industrial applications. Muscovite and hematite are commonly intergrown and are interpreted to be material where much of the elements of environmental concern are concentrated. Reprocessing of the waste stream to separate muscovite from other components may enable the waste stream to be used as constructed wetland media for Virginia and nearby states. Recycling of this mine waste may have a positive impact on the local economy of Buckingham County and aid in mitigation of wetland loss.