Formation and evolution of Emeishan basalt saprolite in vadose zones of Touzhai landslide source rockmass

In order to explain the formation process of slope hazards, and to identify the key factors leading to instability of a slope, Emeishan basalt saprolite in vadose zones of the Touzhai landslide in Zhaotong, Yunnan, was studied. The formation and evolution of Emeishan basalt saprolite was examined using, amongst other techniques, field investigations, thin section analysis, scanning electron microscopy (SEM) observations, chemical analysis, physical and water-physical property tests of rock masses. Field observations revealed that the majority of the weathered rock blocks were presented as a concentric layer structure in which an internal corestone was enveloped with several layers of external saprolized crust. Chemical and mineralogical analysis identified that iron was the most sensitive element and that the weathering progress usually started with the oxidation of Fe²⁺ to Fe³⁺ in rock blocks. Alkaline elements such as Si, Ca, Mg, Na and K were also dissolved and Fe and Al were concentrated in saprolized crusts. Results indicated that loss on ignition (LOI) also increased significantly. SEM results showed that the weathering intensity of the basalt blocks decreased gradually from the outside to the inside, and the mineral morphology significantly differed on both sides of the weathering front. The saprolized crusts presented cellular microstructure features due to the generation of micropore and clay minerals. Thin section analysis showed that plagioclase was relatively more stable than pyroxene and chlorite during weathering. With a centripetal propagation of the weathering front, saprolized crusts became thicker and corestones became smaller; fresh Emeishan basalt blocks gradually turned into saprolized blocks. Due to the loose structure and low strength of saprolite, the quality of the Emeishan basalt mass significantly deteriorated, this being a potentially important factor which caused the Touzhai landslide to occur.     

A back-propagation neural-network-based displacement back analysis for the identification of the geomechanical parameters of the Yonglang landslide in China

Xigeda formation is a type of hundred-meter-thick lacustrine sediments of being prone to triggering landslides along the trunk channel and tributaries of the upper Yangtze River in China. The Yonglang landslide located near Yonglang Town of Dechang County in Sichuan Province of China, which was a typical Xigeda formation landslide, was stabilized by anti-slide piles. Loading tests on a loading-test pile were conducted to measure the displacements and moments. The uncertainty of the tested geomechanical parameters of the Yonglang landslide over certain ranges would be problematic during the evaluation of the landslide. Thus, uniform design was introduced in the experimental design, and by which, numerical analyses of the loading-test pile were performed using Fast Lagrangian Analysis of Continua (FLAC^3D) to acquire a database of the geomechanical parameters of the Yonglang landslide and the corresponding displacements of the loading-test pile. A three-layer back-propagation neural network was established and trained with the database, and then tested and verified for its accuracy and reliability in numerical simulations. Displacement back analysis was conducted by substituting the displacements of the loading-test pile to the well-trained three-layer back-propagation neural network so as to identify the geomechanical parameters of the Yonglang landslide. The neural-network-based displacement back analysis method with the proposed methodology is verified to be accurate and reliable for the identification of the uncertain geomechanical parameters of landslides.     

Tracing environmental lead sources on the Ao mountain of China using lead isotopic composition and biomonitoring

Atmospheric lead(Pb) and other trace metals can transport over long distance and deposit on remote alpine ecosystems. In this work, the soil profiles, litter and dominant mosses along a large altitude were collected on Ao Mountain, Central China, to obtain the spatial distributions of Pb in these materials, decipher the possible factors controlling the distribution, and quantitatively distinguish the natural versus anthropogenic sources of Pb through the Pb isotopic tracing and biomonitoring. The results show that soil Pb concentrations(mg/kg) decreased significantly with depth, and they were markedly higher in the O(42.6± 2.7) and A(36.4 ± 2.2) horizons than in the litter(7.20 ± 1.9) and mosses(28.0 ± 3.9). The Pb enrichment in the surface soils(O and A horizons),litter and mosses existed in the relatively high altitudes, which was attributed to the influences from atmospheric wet deposition, plants, soil physicochemical properties and human activity. ThePb isotopic ratios identified the Pb sources as originating mainly from Chinese coal combustion,mining and smelting. Atmospheric Pb from southeastern, southwestern and northwestern regions could be deposited in the alpine ecosystem by long distance atmospheric transport. The anthropogenic Pb reached over 50% in the O and A horizons, and over 70% in the litter and mosses, which corresponded to the concentrations of 26.9, 17.7, 5.92 and 21.2 mg/kg, respectively. The results indicate that the mutual effects of climate and regional human activity could increase the Pb accumulation in remote alpine ecosystems.     

Geomorphologic map of the 1<Superscript>st</Superscript> Mutnaya River,Southeastern Kamchatka,Russia

The Kamchatka Peninsula–situated in the Pacific “Ring of Fire”–has 29 active and over 400 extinct volcanoes. Since it is situated in the northeastern extremity of Russia, in subarctic climate, the volcanic landforms are overprinted by the 446 glaciers. This research focuses on the 1^stMutnaya catchment which drains the southern slopes of two active volcanoes: Avachinsky and Koryaksky. Those volcanoes are a permanent threat for the cities of Petropavlovsk and Elizovo, which are the 2 of 3 cities of the peninsula. Hence, most of the studies carried out in the area dealt with the natural hazards and only few focus on landscape evolution. Thus, the purpose of this study was to elaborate a cartographic approach which integrates classic geomorphology with state of the art GIS and remote sensing techniques. As result, different landforms and related processes have been analysed and included in the first general geomorphologic map of the 1^stMutnaya catchment.     

Limit equilibrium method (LEM) of slope stability and calculation of comprehensive factor of safety with double strength-reduction technique

When the slope is in critical limit equilibrium(LE) state, the strength parameters have different contribution to each other on maintaining slope stability. That is to say that the strength parameters are not simultaneously reduced. Hence, the LE stress method is established to analyze the slope stability by employing the double strengthreduction(DSR) technique in this work. For calculation model of slope stability under the DSR technique, the general nonlinear Mohr–Coulomb(M–C) criterion is used to describe the shear failure of slope. Meanwhile, the average and polar diameter methods via the DSR technique are both adopted to calculate the comprehensive factor of safety(FOS) of slope. To extend the application of the polar diameter method, the original method is improved in the proposed method. After comparison and analysis on some slope examples, the proposed method's feasibility is verified. Thereafter, the stability charts of slope suitable for engineering application are drawn. Moreover, the studies show that:(1) the average method yields similar results as that of the polardiameter method;(2) compared with the traditional uniform strength-reduction(USR) technique, the slope stability obtained using the DSR techniquetends to be more unsafe; and(3) for a slope in the critical LE state, the strength parameter φ, i.e., internal friction angle, has greater contribution on the slope stability than the strength parameters c, i.e., cohesion.     

Distributed estimation and analysis of precipitation recharge coefficient in strongly-exploited Beijing plain area,China

The precipitation recharge coefficient(PRC), representing the amount of groundwater recharge from precipitation, is an important parameter for groundwater resources evaluation and numerical simulation. It was usually obtained from empirical knowledge and site experiments in the 1980 s. However, the environmental settings have been greatly modified from that time due to land use change and groundwater over-pumping, especially in the Beijing plain area(BPA). This paper aims to estimate and analyze PRC of BPA with the distributed hydrological model and GIS for the year 2011 with similar annual precipitation as long-term mean. It is found that the recharge from vertical(precipitation + irrigation) and precipitation is 291.0 mm/yr and 233.7 mm/yr, respectively, which accounts for 38.6% and 36.6% of corresponding input water. The regional mean PRC is 0.366, which is a little different from the traditional map. However, it has a spatial variation ranging from –7.0% to 17.5% for various sub-regions. Since the vadose zone is now much thicker than the evaporation extinction depth, the land cover is regarded as the major dynamic factor that causes the variation of PRC in this area due to the difference of evapotranspiration rates. It is suggested that the negative impact of reforestation on groundwater quantity within BPA should be well investigated, because the PRC beneath forestland is the smallest among all land cover types.     

Global water vapor content decreases from 2003 to 2012: An analysis based on MODIS data

Water vapor in the earth′s upper atmosphere plays a crucial role in the radiative balance, hydrological process, and climate change. Based on the latest moderate-resolution imaging spectroradiometer(MODIS) data, this study probes the spatio-temporal variations of global water vapor content in the past decade. It is found that overall the global water vapor content declined from 2003 to 2012(slope b = –0.0149, R = 0.893, P = 0.0005). The decreasing trend over the ocean surface(b = –0.0170, R = 0.908, P = 0.0003) is more explicit than that over terrestrial surface(b = –0.0100, R = 0.782, P = 0.0070), more significant over the Northern Hemisphere(b = –0.0175, R = 0.923, P = 0.0001) than that over the Southern Hemisphere(b = –0.0123, R = 0.826, P = 0.0030). In addition, the analytical results indicate that water vapor content are decreasing obviously between latitude of 36°N and 36°S(b = 0.0224, R = 0.892, P = 0.0005), especially between latitude of 0°N and 36°N(b = 0.0263, R = 0.931, P = 0.0001), while the water vapor concentrations are increasing slightly in the Arctic regions(b = 0.0028, R = 0.612, P = 0.0590). The decreasing and spatial variation of water vapor content regulates the effects of carbon dioxide which is the main reason of the trend in global surface temperatures becoming nearly flat since the late 1990 s. The spatio-temporal variations of water vapor content also affect the growth and spatial distribution of global vegetation which also regulates the global surface temperature change, and the climate change is mainly caused by the earth's orbit position in the solar and galaxy system. A big data model based on gravitational-magmatic change with the solar or the galactic system is proposed to be built for analyzing how the earth's orbit position in the solar and galaxy system affects spatio-temporal variations of global water vapor content, vegetation and temperature at large spatio-temporal scale. This comprehensive examination of water vapor changes promises a holistic understanding of the global climate change and potential underlying mechanisms.     

Characteristics and cause analysis of heavy haze in Changchun City in Northeast China

Northeast China has been reported as having serious air pollution in China with increasing occurrences of severe haze episodes. Changchun City, as the center of Northeast China, has longstanding industry and is an important agricultural base. Additionally, Changchun City has a long winter requiring heating of buildings emitting pollution into the air. These factors contribute to the complexity of haze pollution in this area. In order to analyze the causes of heavy haze, surface air quality has been monitored from 2013 to 2015. By using satellite and meteorological data, atmospheric pollution status, spatio-temporal variations and formation have been analyzed. Results indicated that the air quality in 88.9% of days exceeding air quality index(AQI) level-1 standard(AQI 50) according to the National Ambient Air Quality Standard(NAAQS) of China. Conversely, 33.7% of the days showed a higher level with AQI 100. Extreme haze events(AQI 300) occurred frequently during agricultural harvesting period(from October 10 to November 10), intensive winter heating period(from Late-December to February) and period of spring windblown dust(April and May). Most daily concentrations of gaseous pollutants, i.e., NO_2(43.8 μg/m~3), CO(0.9 mg/m~3), SO_2(37.9 μg/m~3), and O_3(74.9 μg/m~3) were evaluated within level-1 concentration limits of NAAQS standards. However, particulate matter(PM_(2.5) and PM10) concentrations(67.3 μg/m~3 and 115.2 μg/m~3, respectively) were significantly higher than their level-1 limits. Severe haze in spring was caused by offsite transported dust and windblown surface soil. Heavy haze periods during fall and winter were mainly formed by intensive emissions of atmospheric pollutants and steady weather conditions(i.e., low wind speed and inversion layer). The overlay emissions of widespread straw burning and coal combustion for heating were the dominant factors contributing to haze in autumn, while intensive coal burning during the coldest time was the primary component of total emissions. In addition, general emissions including automobile exhaust, road and construction dust, residential and industrial activities, have significantly increased in recent years, making heavy haze a more frequent occurrence. Therefore, both improved technological strategies and optimized pollution management on a regional scale are necessary to minimize emissions in specified seasons in Changchun City, as well as comprehensive control measures in Northeast China.     

Genotoxic potential of copper oxide nanoparticles in the bivalve mollusk <Emphasis Type="Italic">Mytilus trossulus</Emphasis>

Copper oxide nanoparticles (CuO-NPs) are among the most widely used metal oxide nanoparticles, which increases the chance of their being released into the marine environment. As the applications of these particles have increased in recent years, their potential impact on the health of marine biota has also increased. However, the toxicological effects of these NPs in the marine environment are poorly known. In the present study, the DNA damaging potential of CuO-NPs in the marine eastern mussel Mytilus trossulus was evaluated and compared to that of dissolved copper exposures. Genotoxicity was assessed by the single cell gel electrophoresis (comet) assay in mussel gill and digestive gland cells. The results showed that copper in both forms (CuO-NPs and dissolved copper) was accumulated to different extents in mussel tissues. The mussel exposed to the dissolved copper attained higher concentrations of copper in the gills than in the digestive gland. In contrast to these results, it was found that CuO-NPs could induce much higher copper accumulation in the digestive gland than in the gills. A clear and statistically significant increase in DNA damage was found in both tissues of the Cu-exposed group compared to the control mussels. Our results indicated that the CuO-NP exposure produced remarkable effects and increased DNA damage significantly in mussel gill cells only. It should be noted that the digestive gland cells were prone to accumulation following CuO-NPs when compared to the gill cells, while the gill cells were more sensitive to the genotoxic effects of CuO-NPs. These results also suggested the need for a complete risk assessment of engineered particles before its arrival in the consumer market.