Mineralogy,petrology, chronology,and exposure history of the Chelyabinsk meteorite and parent body

Three masses of the Chelyabinsk meteorite have been studied with a wide range of analytical techniques to understand the mineralogical variation and thermal history of the Chelyabinsk parent body. The samples exhibit little to no postentry oxidation via Mössbauer and Raman spectroscopy indicating their fresh character, but despite the rapid collection and care of handling some low levels of terrestrial contamination did nonetheless result. Detailed studies show three distinct lithologies, indicative of a genomict breccia. A light‐colored lithology is LL5 material that has experienced thermal metamorphism and subsequent shock at levels near S4. The second lithology is a shock‐darkened LL5 material in which the darkening is caused by melt and metal‐troilite veins along grain boundaries. The third lithology is an impact melt breccia that formed at high temperatures (~1600 °C), and it experienced rapid cooling and degassing of S₂ gas. Portions of light and dark lithologies from Chel‐101, and the impact melt breccias (Chel‐102 and Chel‐103) were prepared and analyzed for Rb‐Sr, Sm‐Nd, and Ar‐Ar dating. When combined with results from other studies and chronometers, at least eight impact events (e.g., ~4.53 Ga, ~4.45 Ga, ~3.73 Ga, ~2.81 Ga, ~1.46 Ga, ~852 Ma, ~312 Ma, and ~27 Ma) are clearly identified for Chelyabinsk, indicating a complex history of impacts and heating events. Finally, noble gases yield young cosmic ray exposure ages, near 1 Ma. These young ages, together with the absence of measurable cosmogenic derived Sm and Cr, indicate that Chelyabinsk may have been derived from a recent breakup event on an NEO of LL chondrite composition.     

Arsenic attenuation in tailings at a former Cu–W–As mine,SW Finland

Nearly half a century after mine closure, release of As from the Ylöjärvi Cu–W–As mine tailings in groundwater and surface water run-off was observed. Investigations by scanning electron microscopy (SEM), electron microprobe analysis (EMPA), synchrotron-based micro-X-ray diffraction (μ-XRD), micro-X-ray absorption near edge structure (μ-XANES) and micro-extended X-ray absorption fine structure (μ-EXAFS) spectroscopy, and a sequential extraction procedure were performed to assess As attenuation mechanisms in the vadose zone of this tailings deposit. Results of SEM, EMPA, and sequential extractions indicated that the precipitation of As bearing Fe(III) (oxy)hydroxides (up to 18.4 wt.% As₂O₅) and Fe(III) arsenates were important secondary controls on As mobility. The μ-XRD, μ-XANES and μ-EXAFS analyses suggested that these phases correspond to poorly crystalline and disordered As-bearing precipitates, including arsenical ferrihydrite, scorodite, kaňkite, and hydrous ferric arsenate (HFA). The pH within 200 cm of the tailings surface averaged 5.7, conditions which favor the precipitation of ferrihydrite. Poorly crystalline Fe(III) arsenates are potentially unstable over time, and their transformation to ferrihydrite, which contributes to As uptake, has potential to increase the As adsorption capacity of the tailings. Arsenic mobility in tailings pore water at the Ylöjärvi mine will depend on continued arsenopyrite oxidation, dissolution or transformation of secondary Fe(III) arsenates, and the As adsorption capacity of Fe(III) (oxy)hydroxides within this tailings deposit.     

Polyorogenic reworking of ore‐controlling shear zones at the South Range of the Sudbury impact structure: A telltale story from in situ U–Pb titanite geochronology

The post‐impact orogenic evolution of the world class Ni–Cu–PGE Sudbury mining camp in Ontario remains poorly understood. New temporal constraints from ore‐controlling, epidote–amphibolite facies shear zones in the heavily mineralised Creighton Mine (Sudbury, South Range) illuminate the complex orogenic history of the Sudbury structure. In situ U–Pb dating of shear‐hosted titanite grains by LA‐ICP‐MS reveals new evidence for shear zone reworking during the Yavapai (ca. 1.77–1.7 Ga), Mazatzalian–Labradorian (1.7–1.6 Ga) and Chieflakian–Pinwarian (1.5–1.4 Ga) accretionary events. The new age data show that the effects of the Penokean orogeny (1.9–1.8 Ga) on the structural architecture of the Sudbury structure have been overestimated. At a regional scale, the new titanite age populations corroborate that the Southern Province of the Canadian Shield documents the same tectonothermal episodes that are recorded along orogenic strike within the accretionary provinces of the Southwestern United States.     

Evidence for phosphorus limitation in carbonate sediments of the seagrass Syringodium filiforme

The seagrass Syringodium filiforme was examined in an ecological analysis of plant nutrient requirements and nutrient resource availability. Assessment of the sediment geochemistry in a San Salvador Island seagrass bed indicated that phosphorus was not readily accessible to the plants. Ammonium regeneration in the fine-grained carbonate sediments was high, and interstitial concentrations averaged ca. 100 μM while phosphate replenishment to interstitial water was low, and concentrations were generally less than 2 μM. Analysis of the seagrass leaf tissue content (C : N : P = 1390 : 47 : 1, atomic wt) suggested that nitrogen and phosphorus were both depleted relative to carbon. However, this high N : P for S. filiforme and the low concentration of phosphate available in the interstitial water established the likelihood that plant acquisition of phosphorus was limited. The finding of high root biomass relative to leaf biomass in these seagrass beds corroborates this evidence by depicting a method of plant adaptation that increases nutrient absorptive root surface area.     

Magmatic evolution of Late Cenozoic volcanic rocks of the Lau Ridge,Fiji

Three main groups of lavas are exposed on islands of the Lau Ridge: the Lau Volcanic Group (LVG), 14.0–5.4 Ma, are predominantly andesite; Korobasaga Volcanic Group (KVG), 4.4–2.4 Ma, are predominantly basalt and Mago Volcanic Group (MVG), 2.0–0.3 Ma, are basalt-hawaiite. LVG and KVG lavas are mostly medium-K tholeiitic rocks with high LILE/HFSE ratios characteristic of islands ares, while MVG lavas are ne-normative alkalic rocks with high LILE and HFSE, characteristic of ocean island basalts. LVG lavas have high ?_Nd (+8.0–+8.4) and low ⁸⁷Sr/⁸⁶Sr (0.70273–0.70349) similar to N-MORB, whereas KVG lavas have slightly more radiogenic values (?_Nd=+7.5?+8.4; ⁸⁷Sr/⁸⁶Sr=0.70323-0.70397). MVG lavas form an isotopically distinct group having lower ?_Nd (+4.6–+4.9) and (⁸⁷Sr/⁸⁶Sr ranging from 0.70347–0.70375). LVG lavas were erupted in a primary oceanic island arc (Vitiaz arc) during the Miocene. Basaltic lavas were derived by approximately 19% partial melting of mantle wedge peridotite with only minor subduction component. Andesites and dacites were produced by low-pressure plagioclase-pyroxene-titanomagnetite dominated crystal fractionation. KVG lavas were erupted during the period immediately prior to or during the initial stages of rifting in the Lau Basin, and, like LVG lavas, show significant chemical differences at the northern and southern ends of the Lau Ridge. Lavas at the northern end (type (ii)) appear to be derived from a more depleted source than LVG but with a greater amount of subduction component. Those at the southern end (type (i)) probably came from a slightly more enriched source with less subduction component. MVG basalts and hawaiites were derived from an enriched mantle with little or no subduction input. The hawaiites (type (i)) could not have been derived from the basalts (type (ii)), and the two magma types must have come from different sources, indicating mantle heterogeneity. The lack of subduction influence indicates the MVG lavas are tectonically unrelated to the present-day Tonga arc, and the lack of depletion indicators suggests they have tapped a different (new?) part of the mantle wedge. This may reflect introduction of sub-Pacific mantle through the present Tonga-Lau subduction system.     

Effects of Recent Instability on Cultivated Area Along the Euphrates River in Iraq

We used MODIS NDVI data to determine whether there was a significant change in cultivated area along the Euphrates River in Iraq after the Iraq War compared to before and during the war. Results revealed that mean cultivated area was largest during the pre–Iraq War period (2000–2003) with 99,115 Mha, reduced some during the early Iraq War period (2003–2006) to 83,480 Mha, reduced even further during the late Iraq War period (2007–2011) to 53,813 Mha due to drought, and increased slightly during the post–Iraq War period (2012–2015) to 69,161 Mha, although not returning to previous highs of the pre–Iraq War or early Iraq War periods. Statistical analysis with the Kruskal–Wallis test revealed that the small cultivated area during the post–Iraq War period was more closely related to the late Iraq War and drought period than previous periods, indicating that recent instability, such as political turmoil following the departure of U.S. troops, violent militant extremism, lack of economic investment, and environmental degradation, has had a similar effect on cultivated area as a devastating drought.     

Detection of mRNA sequences homologous to the human glutathione peroxidase and rat cytochrome P-450IVA1 genes in Mytilus edulis

In this study we have used cloned gene probes for human glutathione peroxidase (GPX), rat cytochrome P-450IVA1 and rat cytochrome P-450IIE1 to detect homologous sequences in RNA from the hepato-pancreas of Mytilus edulis. The presence of sequences hybridising to the GPX and P-450IVA1 probes, but not to the P-450IIE1 probe, confirms the ancient origin of the former genes and indicates that conserved-sequence DNA probes from higher organisms can be used to examine the structure and function of genes of environmental interest in marine organisms.     

Lipid biomarkers of deep-sea hydrothermal vent polychaetes—Alvinella pompejana, A. caudata, Paralvinella grasslei and Hesiolyra bergii

The lipid composition was determined for 5 species of polychaete annelids collected by the Deep Submergence Vehicle ALVIN from high temperature chimneys at the 2500 m depth hydrothermal vent field of the East Pacific Rise. These are the first lipid biomarker analyses reported for these hydrothermal vent polychaetes. Lipid content was low in all samples (1.6–35.9 mg g^–1 wet mass) and was dominated by polar lipid (78–90% of total lipid) with 8–19% sterol (ST), and very low storage lipid (triacylglycerol and wax ester). Total polyunsaturated fatty acids (PUFA) were moderately high (22–31% of total fatty acids (FA)) with extremely low or no docosahexaenoic acid (DHA, 22:6(n-3)). Eicosapentaenoic acid (EPA, 20:5(n-3)) levels were 5–6% in Alvinella pompejana and A. caudata and 10.3–13.7% in an errantiate polychaete (likely Hesionidae) and Hesiolyra bergii. There were greater PUFA and a greater EPA/AA (AA is arachidonic acid, 20:4(n-6)) ratio in the anterior versus the posterior half of A. pompejana, which may correlate to the strong temperature gradient reported in its tube. Total nonmethylene interrupted diunsaturated fatty acids (NMID) were 4–9% of total FA for most polychaete species and included several 20:2 and 22:2 components. The principal monounsaturated fatty acids (MUFA) included 18:1(n-7)c (14–19%), 16:1(n-7)c (2.6–10%) and 20:1(n-11)c (3–7% of total FA). These polychaete species may desaturate and elongate the bacterial-derived 18:1(n-7)c to obtain the essential FA EPA and AA. The major ST in the polychaetes is cholesterol (89–98% of total ST) with less cholesterol in the gut contents of A. pompejana. Other ST included 24-ethylcholesterol (1.5–5% of total ST) with lesser amounts of 24-methylenecholesterol, desmosterol, lathosterol, 24-methylcholesterol, 24-ethylcholesterol, and the stanols dehydrocholestanol and cholestanol. The high ST levels could play a role in thermal adaptation of membranes at the hydrothermal vent environment. Differences in the FA profiles separated the closely related species A. pompejana and A. caudata from Paralvinella grasslei, H. bergii, and the errantiate polychaete (likely Hesionidae).