An innovative mode of groundwater recharge to a buried esker aquifer is considered. The current conceptual model affords a natural safeguard to underlying aquifers from the overlying muds. A hypothesis of groundwater recharge to a buried esker aquifer via preferential pathways across its overlying muds is tested here by heuristic numerical one-dimensional and two-dimensional modeling simulations. The hypothesis has been tested against two other conventionally accepted scenarios involving: (1) distal esker outcrop areas and (2) remote shallow-bedrock recharge areas. The main evidence comes from documented recharge pressure pulses in the overlying mud aquitard and in the underlying esker hydraulic-head time series for the Vars-Winchester esker aquifer in Eastern Ontario, Canada. These perturbations to the potentiometric surface are believed to be the aquifer response to recharge events. The migration rate of these pressure pulses is directly related to the hydraulic diffusivity of the formation. The measured response time and response amplitude between singular radar precipitation events and well hydrographs constituted the heuristic model calibration targets. The main evidence also includes mud-layering deformation (water escape features) which was observed in seismic surveys of the over-esker muds. These disturbed stratigraphic elements provide a realistic mechanism for migrating water to transit through the muds. The effective hydraulic conductivities of these preferential pathways in the muds were estimated to be between 2?×?10?6 and 7?×?10?6 m/s. The implications of these findings relate to the alleged natural safeguard of these overlying muds. 相似文献
ABSTRACTIn the European Alps, high mountain environments are subject to major impacts resulting from climate change, which strongly affect human activities such as mountaineering. The purpose of the study was to examine changes in access routes to 30 high mountain huts in the Western Alps since the 1990s. Data were derived from the use of two different methods, geo-historical studies and a questionnaire, and were used to identify both the climate-related processes affecting the climbing routes and the strategies implemented by public entities, Alpine clubs, guide companies, and hut keepers to maintain acceptable safety and technical conditions. The case studies revealed issues affecting three access routes and the results from the questionnaire showed that the main processes affecting access routes were loss of ice thickness and retreat from the front of the glaciated areas. Commonly, in situ equipment was installed to facilitate access for mountaineers and/or a part of a route was relocated to a safer area. The authors conclude that in most cases, the measures were effective but they were limited by financial, ethical and legal issues, especially in protected or classified areas that could jeopardise their durability and effectiveness. 相似文献
Oxygen and total dissolved inorganic carbon (DIC) fluxes at the water–sediment interface were measured using benthic chambers to assess the short-term variations of community respiration (CR) in the back reef sediments of Reunion Island (Indian Ocean). Benthic CR had a daily cycle of minimal (6:00 AM) and maximal values (6:00 PM), showing increases of oxygen and DIC fluxes of 2.8- and 3.8-fold, respectively. Average CR values were observed at midday and midnight. The evolution of fluxes was positively related to oxygen concentration in ambient water, but not to temperature changes. In the study area, high daytime primary production augments the amount of energy available for community metabolism and increases benthic respiration. The benthic communities are therefore subjected to short-term variable environmental conditions with oxygen supersaturation during the day, and moderately hypoxic conditions at the end of the night. 相似文献
Hypervelocity collisions of solid bodies occur frequently in the solar system and affect rocks by shock waves and dynamic loading. A range of shock metamorphic effects and high‐pressure polymorphs in rock‐forming minerals are known from meteorites and terrestrial impact craters. Here, we investigate the formation of high‐pressure polymorphs of α‐quartz under dynamic and nonhydrostatic conditions and compare these disequilibrium states with those predicted by phase diagrams derived from static experiments under equilibrium conditions. We create highly dynamic conditions utilizing a mDAC and study the phase transformations in α‐quartz in situ by synchrotron powder X‐ray diffraction. Phase transitions of α‐quartz are studied at pressures up to 66.1 and different loading rates. At compression rates between 0.14 and 1.96 GPa s?1, experiments reveal that α‐quartz is amorphized and partially converted to stishovite between 20.7 GPa and 28.0 GPa. Therefore, coesite is not formed as would be expected from equilibrium conditions. With the increasing compression rate, a slight increase in the transition pressure occurs. The experiments show that dynamic compression causes an instantaneous formation of structures consisting only of SiO6 octahedra rather than the rearrangement of the SiO4 tetrahedra to form a coesite. Although shock compression rates are orders of magnitude faster, a similar mechanism could operate in impact events. 相似文献
The filling history of the Níspero deeply buried Lower Cretaceous carbonate reservoir (below 4000 m) from the south part of Gulf of Mexico was studied using a combination of data from petrography, stable isotopes and fluid inclusions and compared with a one-dimensional burial model to derive timing. 相似文献
In this study, we investigate the Lesser Antilles forearc basin, focusing on the late Pliocene to Pleistocene sedimentary archives in order to track the occurrence of extreme events triggered by enhanced subduction‐related tectono‐volcanic activity. We identify late Piacenzian deposits covering a major regional erosional surface, displaying sedimentary dykes and large marine boulders embedded in a mixed continental–marine matrix, characteristic of tsunamites. We interpret this episode of platform emersion and the successive cataclysmic deposits as resulting from enhanced tectonic activity at the interface of the subduction zone, synchronous with the initiation of the Lesser Antilles volcanic arc. We then discuss the implications in terms of the mechanical behaviour of the Lesser Antilles subduction zone. 相似文献
Dissolution experiments of a tholeiite basalt glass carried out at different pH and T (up to 300°C) using a rotatingdisc apparatus show that, depending on pH and T, dissolution can be controlled by one of the following steps: (1) surface reaction; (2) transport of reactants in solution; and (3) mixed reaction. The activation energies of these different processes were found to be 60, 9 and 15–50 kJ mol−1, respectively. Taking account of these results, it appears likely that surface reactions are not rate limiting for the hydrolysis of most crystalline silicate minerals in hydrothermal and metamorphic processes, and that caution should be exercised when predicting rate of reactions at high temperatures solely on the basis of activation energies measured at low temperatures.
Comparison of experimental and theoretical potentiometric titrations of the basalt glass and its constituent oxides indicates that the adsorption of H+ and OH− ions at the basalt surface is metal cation specific and that the net adsorption can be predicted from the sole knowledge of the acidity constants of the network-forming constituent oxides. We found that in the acidic pH region dissolution is promoted by the adsorption of H+ on al and Fe surface sites while in the basic region, dissolution is promoted by the adsorption of OH− on Si sites. The combination of the two distinct types of surface sites, Al and Fe on the one hand, and Si on the other hand, results in a dissolution rate minimum at a pH-value between the pHzpc of the two groups of oxide components. Linear regressions with a slope n=3.8 are observed both in acid and alkaline solutions in logarithmic plots of the rate of dissolution vs. the surface charge. The value of n, which represents the number of protonation or hydroxylation steps prior to metal detachment, has been found equal to the mean valence of the network-forming metals.
Combining concepts of surface coordination chemistry with transition state theory afforded characterisation of the activated complexes involved in basalt dissolution processes. From the values obtained for the thermodynamic properties of activation for basalt dissolution it is assumed that the activated complexes formed during the H2O-promoted dissolution of the basalt glass are more tightly bonded than those formed during H+- or OH−-promoted dissolution. 相似文献