Die Ultrabasitmassive im Präkambrium des Staates Goiäs/Brasilien

The Brazilian state of Goiás and parts of Mato Grosso represent the centre of the Brazilian shield, between the Guaporé craton in the west and the São Francisco craton in the east. In contrast to opinions before, early Precambrian gneisses and migmatites form only small parts of the shield complex whereas middle and late Precambrian sequences dominate. From tectonic position, an eugeosynclinal central zone can be distinguished accompanied by younger miogeosynclinal series to the east and west. The ultrabasic massifs of Goiás can be differentiated into following types:

1. alpinotype serpentinised dunites and peridotites,
2. gabbro-pyroxenite-peridotite associations,
3. pyroxenite-metagabbro associations,
4. dunite-pyroxenite-alkalisyenite associations,
5. lamprophyre dykes.

Nos. 1, 2 and 3 are of Precambrian age whereas 4 and 5 are surely of post-Devonian, probably of Cretaceous age and can be attributed to the phase of Paraná volcanism. The most economic types at the moment (Nos. 1 and 2) yield Ni, Cu and Co in lateritic enrichment, Cr, Pt and related elements as primary constituents. Latest, the types 4 and 5 cause special interest. From their association with carbonatites they are related to the Araxá complex of Minas Gerais and anticipate mineralizations of Nb, Ta, Ti and P.     

Generation of a consistent absolute phase-center correction model for GPS receiver and satellite antennas

The development and numerical values of the new absolute phase-center correction model for GPS receiver and satellite antennas, as adopted by the International GNSS (global navigation satellite systems) Service, are presented. Fixing absolute receiver antenna phase-center corrections to robot-based calibrations, the GeoForschungsZentrum Potsdam (GFZ) and the Technische Universität München reprocessed more than 10 years of GPS data in order to generate a consistent set of nadir-dependent phase-center variations (PCVs) and offsets in the z-direction pointing toward the Earth for all GPS satellites in orbit during that period. The agreement between the two solutions estimated by independent software packages is better than 1 mm for the PCVs and about 4 cm for the z-offsets. In addition, the long time-series facilitates the study of correlations of the satellite antenna corrections with several other parameters such as the global terrestrial scale or the orientation of the orbital planes with respect to the Sun. Finally, completely reprocessed GPS solutions using different phase-center correction models demonstrate the benefits from switching from relative to absolute antenna phase-center corrections. For example, tropospheric zenith delay biases between GPS and very long baseline interferometry (VLBI), as well as the drift of the terrestrial scale, are reduced and the GPS orbit consistency is improved.     

On the radiation characteristics of Antarctic Sea Ice

Abstract

Radiative measurements were carried out continuously during a cruise from Australia to Antarctica during austral summer 1995/96. Both shortwave and longwave radiative fluxes were measured. Some of the results are:

• The incoming solar radiation had a mean value of 217 W m^–2; this was a relatively weak value due to the large amount of fractional cloud cover observed. The sun was, for a large part of the trip, above the horizon for 24 hours a day.

• The reflectivity varied widely, not only as a function of sea‐ice concentration, but also as a function of ice type.

• Snow covered pack ice gave the highest albedo values (<70%), while flooded sea ice and thin ice reflected much less (<30%).

• For each sea‐ice type, short term observations showed a good relationship between albedo and ice concentration.

• The albedo increased with decreasing solar elevation.

• The net longwave radiation was negative (mean –27 W m–2); this small absolute value is due to a high amount of fractional cloud cover. There was a weak diurnal variation with a maximum loss (–33 W m^–2) in the early afternoon.

• On the average, the net radiation was positive for 17 hours, and negative for 7 hours a day. However, the duration of a positive balance depended strongly on the surface albedo.

• For the observed albedo values, modelling results showed that the net radiation was always positive when averaged over a day. The magnitude, however, depended strongly on the surface albedo, varying by more than the factor of three.

     

Towards a Higher Comparability of Geothermometric Data obtained by Raman Spectroscopy of Carbonaceous Material. Part I: Evaluation of Biasing Factors

Raman spectroscopy of carbonaceous material (RSCM) is frequently used to determine metamorphic peak temperatures from the structural order of carbonaceous material enclosed in metasediments. This method provides a quick, robust and relatively cheap geothermometer. However, the comparability of the RSCM parameter is low as there are at least three major sources of biasing factors. These sources are the spectral curve‐fitting procedure, the sample characteristics itself and the experimental design including the used Raman system. To assess the impacts of the biasing factors on RSCM, a series of experiments was performed. The experiments showed that curve‐fitting is strongly influenced by individual operator‐bias and the degrees of freedom in the model, implying the need for a standardised curve‐fitting procedure. Due to the diversity of components (optics, light detection device, gratings, etc.) and their combinations within the Raman systems, different Raman instruments generally give differing results. Consequently, to estimate comparable metamorphic temperatures from RSCM data, every Raman instrument needs its own calibration. This demands a reference material series that covers the entire temperature calibration range. Although sample heterogeneity will still induce some variation, a reference material series combined with standardised curve‐fitting procedures will significantly increase the overall comparability of RSCM data from different laboratories.     

On Modeling Dry Deposition of Long-Lived and Chemically Reactive Species over Heterogeneous Terrain

An explicit multi-layer subgrid-scheme was developed for ameso-/-scale model to consider subgrid-scale surface heterogeneity, dry deposition, biogenic and anthropogenic emission of trace gases. Since dry deposition measurements of highly reactive trace species are scarce we try to evaluate this scheme by heuristic principles. The results of simulations conducted for a 5×5 km² resolution with and without thisscheme are evaluated by using results of a model run with 1×1 km²resolution, which is taken as a `grand thruth' and which has the same resolution as the subgrid. The explict multi-layer subgrid scheme provides a similar distribution of dry deposition fluxes as the much more computationally expensive simulation with the 1×1 km² resolution.Dry deposition fluxes determined from observations give evidence that the explicit multi-layer subgrid scheme which does not require a constant flux approximation for a layer of several decameters leads to an improvement in determining the exchange between the atmosphere and the ground.Results of simulations with a microscale model show that the inhomogeneity at forest edges leads to an increase of the turbulent transports of up to a factor 4 compared to horizontally homogeneous terrain, which is assumed to be the conditions of the subgrid cells (and which is usually the assumption for the entire grid cell in mesoscale models). Inhomogeneity inside an extended stand of trees causes an overall increase of 5–10% withhigh local extremes, i.e. such an inhomogeneity results to an underestimation of dry deposition in meso-/-scale models. The effects are most pronounced for a wind direction perpendicular to the forest edge.