Occurrence and seasonal variations of algal toxins in water, phytoplankton and shellfish from North Stradbroke Island, Queensland, Australia

A number of marine microalgae are known to produce toxins that can accumulate in shellfish and when eaten, lead to toxic and potentially fatal reactions in humans. This paper reports on the occurrence and seasonal variations of algal toxins in the waters, phytoplankton and shellfish of Southeast Queensland, Australia. These algal toxins include okadaic acid (OA), domoic acid (DA), gymnodimine (GD), pectenotoxin-2 (PTX-2) and pectenotoxin-2-seco acid (PTX-2-SA), which were detected in the sampled shellfish and phytoplankton, via HPLC-MS/MS. Dissolved OA, PTX-2 and GD were also detected in the samples collected from the water column. This was the first occasion that DA and GD have been reported in shellfish, phytoplankton and the water column in Queensland waters. Phytoplankton tows contained both the toxic Dinophysis and Pseudo-nitzschia algae species, and are suspected of being the most likely producers of the OA, PTX-2s and DA found in shellfish of this area. The number of cells, however, did not correlate with the amount of toxins present in either shellfish or phytoplankton. This indicates that toxin production by algae varies with time and the species present and that number of cells alone cannot be used as an indicator for the presence of toxins. The presence of OA and PTX-2s were more frequently seen in the summer, while DA and GD were detected throughout the year and without any obvious seasonal patterns.     

Estimating long-term soil respiration rates from carbon isotopes occluded in gibbsite

Carbon occluded in the soil gibbsite crystal structure at the Panola Mountain Research Watershed, Georgia, U.S. is presumed to be in isotopic equilibrium with the CO₂ respired from soil organics by microbes and plant roots. Fitting of the stable carbon isotopic data to a Fickian diffusion-based depth function results in an estimate of 47 gC m⁻² y⁻¹ for the long-term soil respiration rate. A numerical model that includes depth-dependent production and diffusion terms results in estimates of 28-12 gC m⁻² y⁻¹. These values range from 15 to 50 times less than the average of modern values for mixed deciduous forests in wet temperate climates. This disparity has several implications for our understanding of the geologic record of climate change, which include: (1) evidence for a cooler and seasonally drier climate during the mid-Holocene in the southeastern U.S., or (2) fluxes of carbon from the soil pool as recorded by soil mineral proxies (i.e., long-term soil respiration rates) under estimate atmosphere annual carbon flux measurements (i.e., short-term measures), and (3) the need to refine soil respiration models used to relate paleosol stable carbon isotopic measurements to paleo-atmospheric estimates.     

The stable isotopic composition (Cl/Cl) of dissolved chloride in rainwater

The stable isotopic composition of dissolved Cl^-${\text{Cl}}^{-}$ in rainwater was measured from a coastal and an interior location in eastern Canada. At the interior Bonner Lake, Ontario, site the δ³⁷Cl values of dissolved Cl^-${\text{Cl}}^{-}$ in precipitation ranged from −3.5‰ to −1.2‰ (SMOC) with an amount-weighted annual average of −2.3‰. At the coastal site, Bay D’Espoir, Newfoundland, δ³⁷Cl values of dissolved Cl^-${\text{Cl}}^{-}$ values ranged from −3.1‰ to 0.0‰ with an amount-weighted annual average of −1.3‰. These negative δ³⁷Cl values provide evidence that atmospheric HCl is ³⁷Cl depleted, presumably from acidification of sea-salt aerosols. Accordingly, dissolved Cl^-${\text{Cl}}^{-}$ in the headwaters of two montane rivers in Western Canada had similarly depleted δ³⁷Cl values. These results have implications to the interpretation of the isotopic compositions of dissolved Cl^-${\text{Cl}}^{-}$ in surface waters, formation fluids, and groundwaters.     

Small ion concentrations in and near clouds and fogs

Summary A mobile small ion and condensation nuclei laboratory was used to study small ion concentrations in and near orographic clouds, low cloud bases, and fogs. It was found that these areas of diminished visibility exist in a conductivity well, characterized by a small ion concentration of less than 200 small ions per cm³, surrounded by an area of increasing small ion concentration, until the concentration exceeds 400 small ions per cm³ 500 to 1000 feet below the base of the cloud. It was also observed that small ion concentration increases during the dissipation of fog, and oscillates with the passage of large patches of drifting fog.     

Gulf of Mexico,ocean-color surface-truth measurements

In October 1977, a major remote sensing experiment was conducted in the Gulf of Mexico, in preparation for the launch of NIMBUS-7 which carried the Coastal Zone Color Scanner. Two major vessels obtained surface-truth measurements, while two jet aircraft at altitudes of 12.5 and 19.5 km obtained images of the surrounding ocean in 10 spectral bands. Measurements obtained in the surface water from the NOAA vessel Researcher of the spectral downwelling irradiances, upwelling radiances, attenuation and scattering properties are described.     

Zinc and copper levels in Belfast Lough

A survey of dissolved zinc, copper, oxygen and biochemical oxygen demand in Belfast Lough has been carried out. Zinc and to a lesser extent copper occur at elevated levels compared with a non-industrialized area of the Irish Sea. Zinc levels are particularly high in the marginal waters of the north shore of the lough. Dissolved oxygen and biochemical oxygen demand levels indicate that pollution of the lough by oxygendemanding wastes is not a serious problem.     

Centrifuge modeling of load-deformation behavior of rocking shallow foundations

Shallow foundations supporting building structures might be loaded well into their nonlinear range during intense earthquake loading. The nonlinearity of the soil may act as an energy dissipation mechanism, potentially reducing shaking demands exerted on the building. This nonlinearity, however, may result in permanent deformations that also cause damage to the building. Five series of tests on a large centrifuge, including 40 models of shear wall footings, were performed to study the nonlinear load-deformation characteristics during cyclic and earthquake loading. Footing dimensions, depth of embedment, wall weight, initial static vertical factor of safety, soil density, and soil type (dry sand and saturated clay) were systematically varied. The moment capacity was not observed to degrade with cycling, but due to the deformed shape of the footing–soil interface and uplift associated with large rotations, stiffness degradation was observed. Permanent deformations beneath the footing continue to accumulate with the number of cycles of loading, though the rate of accumulation of settlement decreases as the footing embeds itself.     

Slope aspect, slope length and slope inclination controls of shallow soils vegetated by sclerophyllous heath—links to long-term landscape evolution

On upland Triassic sandstone slopes of the western Blue Mountains, nonswamp, sclerophyllous heath (shrub-dominated vegetation) on shallow soils is commonly found downslope and adjacent to sclerophyllous forest on deeper soils. Some consider heath—and thus shallow soils—as favouring west-facing slopes, which are expected to experience drier microclimates due to insolation, strong and desiccating winds, and severe summer fires. However, our analysis of extensive areas with heath on shallow soils, based on vegetation and topographic maps, and fieldwork of uplands with various degrees of dissection, suggests that aspect is a poor predictor of shallow soils. Rather, shallow soils and heath are found on short slopes and the lower segments of longer slopes with the latter significantly steeper than forested segments.The shallow–deep soil boundary, marked by contrasting modern vegetation structures, does not signify a catchment area threshold, and correspondingly, the vegetation patterns are not in balance with distributary catchment processes, as short slopes are mantled exclusively by shallow soils. Instead, the soil depth boundary represents the propagation of base-level lowering signals, which takes place not only by the headward retreat of knickpoints but also via increased lowering of slope segments adjacent to drainage lines. This leads to steep slopes immediately adjacent to canyons, narrow gorges, and small steep valleys, that are mantled by shallow, discontinuous soils undergoing rapid erosion. These steep slopes persist in the landscape for ≥ 10 My after upland stream rejuvenation until incision of more weatherable Permian sediments, underlying the Triassic cliff-forming sandstones, triggers rapid lateral expansion of gorges. Once shallowly mantled and steeper slopes adjacent to streams are consumed by gorge widening, slopes adjacent to wide gorge clifflines reflect former upland drainage patterns rather than the redirected flow to rapidly widening gorges. Hence, modern vegetation patterns reflect a significant phase of landform development, perhaps combined with enhanced erosion during the Last Glacial Period that is compounded by a humped soil production function on bedrock.