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331.
This paper reports that vibrational spectroscopic analysis on hydrogen-bonding between acetone and water comprises both experimental Raman spectra and ab initio calculations on structures of various acetone/water complexes with changing water concentrations. The optimised geometries and wavenumbers of the neat acetone molecule and its complexes are calculated by using ab initio method at the MP2 level with 6-311+G(d,p) basis set. Changes in wavenumber position and linewidth (fullwidth at half maximum) have been explained for neat as well as binary mixtures with different mole fractions of the reference system, acetone, in terms of intermolecular hydrogen bonding. The combination of experimental Raman data with ab initio calculation leads to a better knowledge of the concentration dependent changes in the spectral features in terms of hydrogen bonding. 相似文献
332.
We investigate the electronic structures of one and two monolayer iron phthalocyanine (FePc) molecules on Au(111) surfaces. The first monolayer FePc is lying flat on the Au(111) substrate, and the second monolayer FePc is tilted at ~15° relative to the substrate plane along the nearest neighbour [101-] direction with a lobe downward to the central hole of the unit cell in the first layer. The structural information obtained by first-principles calculations is in agreement with the experiment results. Furthermore, it is demonstrated that the electronic structures of FePc molecules in one-monolayer FePc/Au(111) system are perturbed significantly, while the electronic structures of FePc molecules in the second monolayer in two-monolayer FePc/Au(111) system remain almost unchanged due to the screening of the buffer layer on Au(111). 相似文献
333.
The chemical potential of electrons in a strong magnetic field is investigated. It is shown that the magnetic field has only a slight effect on electron chemical potential when B<1011 T, but electron chemical potential will decrease greatly when B>1011 T. The effects of a strong magnetic field on electron capture rates for 60Fe are discussed, and the result shows that the electron capture sharply decreases because of the strong magnetic field. 相似文献
334.
This paper studies the average fidelity of teleportation and thermal entanglement for a two-qubit Heisenberg XYZ chain in the presence of both an inhomogeneous magnetic field and a Dzyaloshinski--Moriya interaction. It shows that for a fixed Dz, the increase of bz will broaden the critical temperature at the cost of decreasing the thermal entanglement. And it can modulate the inhomogeneous magnetic field and the Dzyaloshinski--Moriya interaction for the average fidelity of teleportation to be optimal. 相似文献
335.
孤岛油田属稠油疏松砂岩油藏,生产过程中油井出砂严重,现有的涂敷砂人工井壁防砂注蒸汽后强度较低,造成防砂成功率低,注汽后高强度采液生产周期较短。为此,通过室内试验,优选出耐高温树脂、高强度骨架颗粒、偶联剂、固化剂,进行室内配方优化试验,评价固结体耐高温性能,测定其渗透率,研制出一种适用于疏松砂岩油藏注蒸汽热采井的HD-1注汽井新型防砂材料。在孤岛油田稠油注蒸汽热采区共试验72口井,成功率为91.0%,截止目前,累计产油为121 572 t,单井平均有效期为233 d。现场应用表明:HD-1注汽井新型防砂材料耐高温、强度高,防砂成功率高,有效期长,能够有效改善注蒸汽热采井的防砂效果。 相似文献
336.
平湖油气田P11储层开发是平湖油气田增储提产的重要目标,也是当前平湖油气田开发面临的难题之一。由于埋藏深,储层物性条件差,试油自然产能低下,储层流体性质复杂,气油比低,凝析油含量高,密度大,储层温度高,压力系数高,给测井解释和评价带来很大困难,对开发方案的实施提出了挑战。根据岩心分析资料,从成岩作用、沉积作用等方面对平湖组放鹤亭P11储层低渗原因进行了分析;对P11储层的测井响应特征进行了总结,对P11储层"四性"关系、孔隙度结构进行剖析,对储层孔隙度、渗透率、饱和度等参数进行了研究,得到一套适合P11储层测井解释评价的方法,为P11储层的开发提供参数依据和测井解释服务。 相似文献
337.
综合评价方法在水质评价应用中的比较研究 总被引:1,自引:0,他引:1
以黄河某取水口监测点19981999年的水质为评价对象,利用灰色关联分析法、模糊综合评价法和物元分析法分别进行了综合评价,结果表明,模糊综合评价和物元分析法的评价结果一致,"中心化"灰色关联法评价结果与上述两方法的评价结果一致. 相似文献
338.
339.
The geological processes responsible for outward growth of the Tibetan Plateau are debated.The Qilian Mountains on the northeastern margin of the plateau comprise one of the youngest structural components of the plateau whose understanding is key to deciphering the broader geological evolution of the region.Here,based on a reprocessed deep seismic profile which was originally collected during the 1990 s across the northeast margin of the western Qilian Mountains and previous geological and geophysical data,we find evidence for decoupled crustal deformation that was partitioned by a decollement,in which lowercrustal deformation featured by local duplexing preceded upper-crustal deformation featured by imbricate thrusts.Furthermore,we propose that the Asian lithospheric mantle is being underthrust beneath the western Qilian Mountains,as inferred from patterns of lower crustal deformation which is marked by the Moho geometry.Integrating these results yields a better understanding of lithospheric deformation of western Qilian Mountains,northeastern margin of the plateau during the Cenozoic. 相似文献
340.
介绍了基于SEED波形文件运行率计算的技术和实现方法,介绍了SEED文件中标识时间的特殊掩码、时间片的具体格式和程序的实现,并给出了与其相关的部分源代码. 相似文献