草酰胺合铜(Ⅱ)单核配合物的热分解动力学研究

应用TG-DTG-DTA热分析技术研究了N，N’-双(2-氨丙基)草酰胺合铜(Ⅱ)单核配合物在空气气氛中的热行为；分别用微分法(Achar法)和积分法(Coats-Redfen法)对其非等温TG数据进行了解析。通过对热分解动力学参数的对比分析，提出了该配合物热分解反应机理；根据TG曲线计算出了E，lnA和S^*，并由动力学补偿效应获得了E与lnA的数学表达式。     

三疣梭子蟹雌雄隔离养殖技术研究

在193亩池塘中开展三疣梭子蟹雌雄分养和雌雄混养对比试验。其中雌雄分养面积93亩，亩产商品蟹182公斤，平均壳宽12．6厘米，平均个体重230．1克，成活率40．2％。与雌雄混养相比，亩产量提高了53．6％，成活率提高了1.51倍。专家鉴定认为，梭子蟹雌雄分养，方式新颖，效果明显，技术水平属国内先进。     

塞曼石墨炉原子吸收法直接测定海水中的铬

海水基体对Cr有增感作用。本文研究了抗坏血酸、柠檬酸三铵、酒石酸、乙酸铵等有机基体改进剂对消除基体干扰效果。前二者均有效地消除基体干扰,但1％抗坏血酸 1％柠檬酸三铵混合试剂的效果更好,它不仅可以消除基体干扰,还可降低背景及噪声,Cr的吸收峰也较平滑。本法准确,相对偏差在0.7—4.4％范围内。回收率在92—109％范围内。若海水Cr含量低于定量下限时,可采用多次进样法。     

Influence of large-diameter pipe pile driving on surrounding marine soils and adjacent submarine pipelines

Abstract

With the large-scale development and utilization of ocean resources and space, it is inevitable to encounter existing submarine facilities in pile driving areas, which necessitates a safety assessment. In this article, by referring to a wharf renovation project as a reference, the surrounding soil response and buried pipe deformation during pile driving in a near-shore submarine environment are investigated by three-dimensional (3D) numerical models that consider the pore water effect. Numerical studies are carried out in two different series: one is a case of a single pile focusing on the effect of the minimum plane distance of the pile–pipe, and the other is a case of double piles focusing on the effect of the pile spacing.     

Action mechanism of geotextile-reinforced cushion under breakwater on soft ground

Various measures including material experiments, centrifuge modeling tests and FEM numerical analyses were performed to study systematically the action mechanism of the geotextile-reinforced cushion under breakwater on soft ground and the effects of the strata characterization and the reinforcement condition on the stability of the breakwater-ground system. In the aspect of controlling the deformation, the geotextile-reinforced cushion under breakwater constrains the lateral displacement of both the embankment and the ground. From the viewpoint of stress, the reinforcement suppressed the range of high stress level in the system. In general, the weaker the ground is and the greater the modulus of the geotextile is, the more effective the reinforcement is. The tensile force in the geotextile is greater in the range of the main part of the embankment.     

青岛文昌鱼的生活史──年龄、生长和死亡研究

于１９８９年８月－１９９０年７月对青岛文昌鱼的生活史进行研究。结果表明：（１）青岛文昌鱼种群由４个齿组组成，它至少生产４ａ以上，甚至可达６ａ左右。（２）在Ⅰ、Ⅱ齿时生长较快，平均年生长１３－１５ｍｍ，Ⅲ龄后生长速度减慢，即使同一年龄组的文晶鱼，在不同季节其生长速度也不同。（３）在冬春采集的文昌鱼中Ⅲ龄组的峰值较小。（４）繁殖季节过后，老龄文昌鱼因衰老而死亡。     

Study on the characteristics of the marine boundary layer in the Equatorial Pacific

ＳｔｕｄｙｏｎｔｈｅｃｈａｒａｃｔｅｒｉｓｔｉｃｓｏｆｔｈｅｍａｒｉｎｅｂｏｕｎｄａｒｙｌａｙｅｒｉｎｔｈｅＥｑｕａｔｏｒｉａｌＰａｃｉｆｉｃ￥ＺｈａｎｇＺｉｙｕａｎｄＺｈｏｕＭｉｎｇｙｕ（ＲｅｃｅｉｖｅｄＡｕｇｕｓｔ２１，１９９３；ａｃｃｅｐｔｅｄ...