Nuclear and incommensurate magnetic structure of NaFeGe2O6 between 5?K and 298?K and new data on multiferroic NaFeSi2O6

The compound NaFeGe₂O₆ was grown synthetically as polycrystalline powder and as large single crystals suitable for X-ray and neutron-diffraction experiments to clarify the low temperature evolution of secondary structural parameters and to determine the low temperature magnetic spins structure. NaFeGe₂O₆ is isotypic to the clinopyroxene-type compound aegirine and adopts the typical HT-C2/c clinopyroxene structure down to 2.5?K. The Na-bearing M2 polyhedra were identified to show the largest volume expansion between 2.5?K and room temperature, while the GeO₄ tetrahedra behave as stiff units. Magnetic susceptibility measurements show a broad maximum around 33?K, which marks the onset of low-dimensional magnetic ordering. Below 12?K NaFeGe₂O₆ transforms to an incommensurately modulated magnetic spin state, with k?=?[0.323, 1.0, 0.080] and a helical order of spins within the M1-chains of FeO₆ octahedra. This is determined by neutron-diffraction experiments on a single crystal. Comparison of NaFeGe₂O₆ with NaFeSi₂O₆ is given and it is shown that the magnetic ordering in the latter compound, aegirine, also is complex and is best described by two different spin states, a commensurate one with C2??/c?? symmetry and an incommensurate one, best being described by a spin density wave, oriented within the (1 0 1) plane.     

Taxonomic analysis of the Quaternary archaeofauna found at The Lapa do Santo site,Lagoa Santa region,Brazil

The Lapa do Santo archaeological site, located in the Lagoa Santa region, Brazil, represents an important hunter-gatherer occupation dated from the Early and Middle Holocene. Prior studies of archaeofauna dating to this period are few and most of them only provide basic faunal identification with limited information on taphonomic processes. The main goal of this study is to identify the archaeofauna, record the taphonomic processes, and make inferences about its natural (interpreted as the death of the animal in the rockshelter area due to natural causes or due to predation) or anthropic origins. No extinct species (including megamastofauna) were identified. Taxonomic analysis indicated that most faunal remains consist of taxa that may be of mixed origin (natural or anthropic), such as microvertebrates and carnivorous mammals. The Cervidae are the main vertebrate family found in the studied material and these are likely the result of hunting. The Cervidae Ozotoceros support the presence of a fauna that is typical of savannah environments, although the assemblage contains mostly generalist fauna that can thrive in a variety of environments. Very few remains showed clear evidence for taphonomic processes related to human interaction, such as burnt bones.     

兰州马衔山北缘断裂地震潜势评估

马衔山北缘断裂为晚第四纪活动的左旋逆走滑断裂,是对兰州市影响最大的控震断裂,自东向西可分为内官营段、马衔山段、七道梁段和雾宿山段4条次级断层段.其中雾宿山段为1125年兰州7级地震的发震断层段,其特征地震平均复发间隔为2 250～3 590年,最晚离逝时间为882年,在未来关注的200年内再次发生强震的可能性较小;马衔山段特征地震平均复发间隔约为3 120年,历史上曾发生过多次中等破坏性地震,其潜在地震危险性值得关注;七道梁段和内官营段未获得古地震复发间隔等参数,但历史上均发生过中等破坏性地震,未来仍存在中等破坏性地震发生的可能,其地震复发间隔可近似地参考马衔山断裂带上相应震级地震的平均值.     

A new approach to identify the sensitivity and importance of physical parameters combination within numerical models using the Lund–Potsdam–Jena (LPJ) model as an example

Daily global solar irradiation (R _s) is one of the main inputs in environmental modeling. Because of the lack of its measuring facilities, high-quality and long-term data are limited. In this research, R _s values were estimated based on measured sunshine duration and cloud cover of our synoptic meteorological stations in central and southern Iran during 2008, 2009, and 2011. Clear sky solar irradiation was estimated from linear regression using extraterrestrial solar irradiation as the independent variable with normalized root mean square error (NRMSE) of 4.69 %. Daily R _s was calibrated using measured sunshine duration and cloud cover data under different sky conditions during 2008 and 2009. The 2011 data were used for model validation. According to the results, in the presence of clouds, the R _s model using sunshine duration data was more accurate when compared with the model using cloud cover data (NRMSE = 11. 69 %). In both models, with increasing sky cloudiness, the accuracy decreased. In the study region, more than 92 % of sunshine durations were clear or partly cloudy, which received close to 95 % of total solar irradiation. Hence, it was possible to estimate solar irradiation with a good accuracy in most days with the measurements of sunshine duration.     

The Indian Ocean’s asymmetric effect on the coupling of the Northwest Pacific SST and anticyclone anomalies during its spring–summer transition after El Niño

By comparing different climatologies in El Niño decaying summer with regard to the presence of Indian Ocean Basin (IOB) warming, we studied the effect of IOB warming on the Northwest Pacific sea surface temperature (SST) anomalies and the coupling process with the surface wind. Zonal asymmetric coupling feedback in the west and east of the Northwest Pacific were caused by the asymmetric spring–summer transition of the background tropical atmospheric circulation. Although the westward wind anomaly caused by the remote effect of IOB warming is found in the whole Northwest Pacific, reversal of the mean background surface winds in the western part leads to negative wind-evaporation SST (WES), whereas sustained trade winds lead to positive WES in the eastern part. The east–west SST gradient resulting from this zonal asymmetric evolution of SST sets off more positive feedback that strengthens the local anticyclone easterly anomalies.     

Effect of the addition of granitic powder to an acidic soil from Galicia (NW Spain) in comparison with lime

The impact of diffuse pollution, agricultural land use and climate change on the long-term response of subsurface–surface water quality is not well understood, but is a prerequisite for evaluation of water management options. The goal of this study is to model geochemical evolution of water chemistry from the infiltration through soil into the unsaturated zone, transport through bedrocks and granular aquifers to a river in order to identify zones of steep concentration gradients and high dynamics under transient flow conditions. A numerical model was constructed comprising a 2-D 1,500 m × 150 m vertical cross-section of typical sedimentary rock formations, a glacio-fluvial quaternary gravel aquifer in the valley and soil layers. The model coupled saturated/un-saturated flow and reactive transport under steady state and transient conditions. Geochemical interactions, include intra-aqueous kinetic reactions of oxygen with dissolved organic matter, as well as kinetics of carbonate dissolution/precipitation. This model section was chosen to provide insight in to the principal processes and time scales affecting water chemistry along different flow paths. The numerical simulator MIN3P was used, a finite volume program for variably saturated subsurface flow and multi-component reactive transport. The results show that subsurface water residence times range from approximately 2 to 2,000 years. Different zones are to be expected with respect to the development of mineral equilibria; namely, purely atmospherically influenced, as well as open and closed system carbonate dissolution. Short-term responses to daily averaged changes in precipitation, however, are only visible to some extent in the shallower and near-river parts of flow system and solute loads. This can most likely be explained by directional changes in flow paths, indicating that equilibrium geochemical condition predominate at the hillslope scale, i.e. water quality depends on transport pathways rather than on kinetic effects. The extent of reducing conditions is controlled by the presence of organic-rich layers (i.e. peat deposits), the dissolution kinetics of aquifer organic matter and the subsequent mixing with oxygenated water by hydrodynamic dispersion.     

青藏高原北部中强以上地震震兆异常的分级特征研究

通过对青藏高原北部中强以上地震前普遍出现的地震活动异常进行了系统的分析和总结,发现各地震活动前兆异常参数与主震震级有分级特征,其结果对未来青藏高原北部中强以上地震的预测具有一定的实用和参考价值.     

Turbulent flux observations and modelling over a shallow lake and a wet grassland in the Nam Co basin,Tibetan Plateau

The Tibetan Plateau plays an important role in the global water cycle and is strongly influenced by climate change. While energy and matter fluxes have been more intensely studied over land surfaces, a large proportion of lakes have either been neglected or parameterised with simple bulk approaches. Therefore, turbulent fluxes were measured over wet grassland and a shallow lake with a single eddy-covariance complex at the shoreline in the Nam Co basin in summer 2009. Footprint analysis was used to split observations according to the underlying surface, and two sophisticated surface models were utilised to derive gap-free time series. Results were then compared with observations and simulations from a nearby eddy-covariance station over dry grassland, yielding pronounced differences. Observations and footprint integrated simulations compared well, even for situations with flux contributions including grassland and lake. The accessibility problem for EC measurements on lakes can be overcome by combining standard meteorological measurements at the shoreline with model simulations, only requiring representative estimates of lake surface temperature.     

Molecular identification and culture observation on <Emphasis Type="Italic">Acrochaete leptochaete</Emphasis> (Chaetophoraceae,Chlorophyta) from China

Acrochaete leptochaete (Huber) Nielsen (Chaetophoraceae, Chlorophyta) was isolated from the macroalgae Chaetomorpha collected from intertidal pools in Rongcheng, Shandong, China. 18S rDNA combined with ITS regions were used to ascertain the morphological identification of the isolated material. Based on the unialgal culture, asexual reproduction and growth characteristics of A. leptochaete were investigated over wide ranges of temperature and irradiance. Results revealed that asexual reproduction of A. leptochaete could be realized by biflagellate zoospores. The zoospores germinated directly to give self- replicating generations. Zoospore germination was bipolar. A temperature range from 13-21°C and a lower irradiance of 36 μmol/(m2·s) were most favorable for the growth of A. leptochaete. Thallus organization, an important taxonomic criterion for the genus Acrochaete, was affected markedly by temperature and irradiance. Our results extend the knowledge about the species’ general biology and its morphological plasticity. For classification and identification of a simple microphytic algae like A. leptochaete, which are traditionally placed in the class Chaetophoraceae, we propose that molecular tools associated with culture observations are applied.     

A particle conveyor belt process in the Columbia River estuary: Evidence from chlorophyll<Emphasis Type="Italic">a</Emphasis> and particulate organic carbon

Using both the photosynthetically active chlorophylla (chla) content of the organic carbon fraction of suspended particulate matter (chla/POC) and the percentage of photosynthetically, active chla in fluorometrically measured chla plus pheophytina (% chla), we determined that under specified hydrodynamic conditions, neap-spring tidal differentiation in particle dynamics could be observed in the Columbia River estuary. During summer time neap tides, when river discharge was moderate, bottom chla/POC remained relatively unchanged from riverine chla/POC over the full 0–30 psu salinity range, suggesting a benign trapping environment. During summertime spring tides, bottom chla/POC decreased at mid range salinities indicating resuspension of chla-poor POC during flood-ebb transitions. Bottom % chla during neap tides tended to average higher than that during spring tides, suggesting that neap particles were more recently hydrodynamically trapped than those on the spring tides. Such differentiation supported the possibility of operation of a particle conveyor belt process, a process in which low-amplitude neap tides favor selective particle trapping in estuarine turbidity maxima (ETM)., while high-amplitude spring tides favor particle resuspension from the ETM. Untrapped river-derived particles at the surface would continue through the estuary to the coastal ocean on the neap tide; during spring tide some particles eroded from the ETM would combine with unsettled riverine particles in transit toward the ocean. Because in tensified biogeochemical activity is associated with ETM, these neap-spring differences may be critical to maintenance and renewal of populations and processes in the estuary. Very high river discharge (15, 000 m³ s⁻¹) tended to overwhelm neap-spring differences, and significant oceanic input during very low river discharge (5,000 m³ s⁻¹) tended to do the same in the estuarine channel most exposed to ocean input. During heavy springtime phytoplankton blooms, development of a thick bottom fluff layer rich in chla also appeared to negate neapspring differentiation because spring tides apparently acted to resuspend the same rich bottom material that was laid down during neap tides. When photosynthetic assimilation numbers [μgC (μgchl,a)⁻¹h⁻¹] were measured across, the full salinity range, no neap-spring differences and no river discharge effects occurred, indicating that within our suite of measurements the compositional distinction of suspended particulate material was mainly a function of chla/POC, and to a lesser extent % chla. Even though these measurements suggest the existence of a conveyor belt process, proof of actual operation of this phenomenon requires scalar flux measurements of chla properties in and out of the ETM on both neap and spring tides.