南极树粉孢属真菌胞外多糖的分离纯化及结构表征

研究南极树粉孢属(Oidiodendron truncatum)真菌所产胞外多糖的理化性质和结构特征。采用阴离子交换柱层析和凝胶柱层析对南极树粉孢属(Oidiodendron truncatum)真菌胞外多糖进行了系统的分离纯化,从中得到4个均一的组分(AFW1,AFW2,AFS1和AFS2),并结合红外、气质及核磁等技术对它们的结构进行了解析。结果表明:AFW1和AFW2为中性多糖,AFS1和AFS2中含有少量的蛋白;AFW1和AFS1是由甘露糖、葡萄糖和半乳糖3种单糖组成的结构复杂的杂多糖;AFW2和AFS2则仅由葡萄糖组成,其中AFW2属线性(-1,6-葡聚糖,而AFS2属于C-3位有分支的α-1,6-葡聚糖。     

海洋浮游藻色素分析和化学分类研究进展

综述了海洋浮游藻色素分析和化学分类研究的最新进展。指出目前以色谱柱串联技术为基础的高分辨高效液相色谱质谱联用已经成为色素分析方法的主要发展趋势。利用此方法对藻类特征色素进行再分析有助于获得对藻类色素分布的新认识。CHEMTAX是在宏观上对浮游藻进行化学分类的良好工具,采用多次运算的方式可以减少其对初始色素比值的依赖,使结果向"真实值"收敛,提高结果的准确性。指出研究以特征色素比值组合为基础的浮游藻精细化学分类方法,以及将以色素分析为基础的浮游藻化学分类应用于了解浮游藻功能类群在生源要素和生物矿物质等的生物地球化学循环过程中的作用是未来的发展趋势。     

HOGGH:一种WMSN网络的路由优化算法

研究WMSN(Wireless Multimedia Sensor Network)的洞路由算法优化问题。基于启发式思想,提出1种WM-SN的洞路由优化算法HOGGH(Heuristic Optimization algorithm for Geographic Greedy Hole-bypassing routing)。该算法对路由算法生成的路径进行探测,从中寻找波峰节点,再根据探测到的信息计算波峰节点之间的优化增益率,对优化增益率高的波峰节点之间的路径进行路径优化,从而达到对整条路径的优化。仿真实例说明了该算法的有效性。     

Volcanically Driven Terrestrial Environmental Perturbations during the Carnian Pluvial Episode in the Eastern Tethys

The Carnian Pluvial Episode (CPE) fingerprints global environmental perturbations and biological extinction on land and oceans and is potentially linked to the Wrangellia Large Igneous Province (LIP). However, the correlation between terrestrial environmental changes and Wrangellia volcanism in the Ordos Basin during the CPE remains poorly understood. Records of negative carbon isotopic excursions (NCIEs), mercury (Hg), Hg/TOC, and Hg enrichment factor (HgEF) from oil shales in a large-scale terrestrial Ordos Basin in the Eastern Tethys were correlated with marine and other terrestrial successions. The three significant NCIEs in the study section were consistently correlated with those in the CPE successions of Europe, the UK, and South and North China. The U-Pb geochronology indicates a Ladinian–Carnian age for the Chang 7 Member. A comprehensive overview of the geochronology, NCIE correlation, and previous bio- and chronostratigraphic frameworks shows that the Ladinian–Carnian boundary is located in the lower part of Chang 7 in the Yishicun section. HgEF may be a more reliable proxy for tracing volcanic eruptions than the Hg/TOC ratio because the accumulation rates of TOC content largely vary in terrestrial and marine successions. The records of Hg, Hg/TOC, HgEF, and NCIEs in the Ordos Basin aligned with Carnian successions worldwide and were marked by similar anomalies, indicating a global response to the Wrangellia LIP during the CPE. Anoxia, a warm-humid climate, enhancement of detrital input, and NCIEs are synchronous with the CPE interval in the Ordos Basin, which suggests that the CPE combined with the regional Qinling Orogeny should dominate the enhanced rate of terrigenous input and paleoenvironmental evolution in the Ordos Basin.     

The role of metal sulfates in thermochemical sulfate reduction (TSR) of hydrocarbons: Insight from the yields and stable carbon isotopes of gas products

The mechanism of thermochemical sulfate reduction (TSR) was investigated by separately heating n-C₂₄ with three different sulfates (CaSO₄, Na₂SO₄, MgSO₄) in sealed gold tubes at 420 °C and measuring the stable carbon isotope values of hydrocarbon (C₁-C₅) and non-hydrocarbon (CO₂) products. Extensive TSR was observed with the MgSO₄ reactant as reflected by increasing concentrations of H₂S, ¹³C depleted CO₂ and relatively low concentrations of H₂ (compared to the control). H₂S yields were already very high at the first monitoring time (12 h) when the temperature had just reached 420 °C, suggesting that TSR had commenced well prior to this temperature. Only trace amounts of n-C₂₄ and secondary C₃-C₅ alkanes were detected at 12 h, reflecting the efficient TSR utilization of the reactant and lower molecular weight alkane products. Ethane levels were still relatively high at 12 h, but declined thereafter as it was subject to TSR in the absence of higher molecular weight alkanes which had already been utilized. Methane yields were consistently high throughout the 48 h MgSO₄ treatment. The temporal decrease in the concentrations of alkanes available for TSR may also contribute to the sharp enhancement of CO₂ after 36 h. Absence or dampening of the molecular and isotopic trends of MgSO₄ TSR was observed with Na₂SO₄ and CaSO₄ respectively, directly reflecting the levels of TSR reached using these sulfate treatments.For all treatments, the δ¹³C values of C_1-5n-alkanes showed an increase with both molecular weight and treatment time. MgSO₄ TSR led to a 5-10‰ increase in the δ¹³C values of the C₁-C₅ hydrocarbons and a 20‰ decrease in the δ¹³C value of CO₂. The significant ¹³C depletion of the CO₂ may be due to co-production of ¹³C enriched MgCO₃, although this remains unproven as the δ¹³C of MgCO₃ was not measured. The difference in the δ¹³C values of ethane and propane (Δδ¹³C_EP) increased in magnitude with the degree of TSR, and this trend could be used to help evaluate the occurrence and extent of TSR in subsurface gas reservoirs.     

江西省龟峰丹霞地貌景观类型与成因分析

龟峰丹霞地貌区位于信江盆地南缘,地处扬子板块与华夏板块的结合带.景区内丹霞地貌景观类型齐全,成景层位为上白垩统龟峰群的河口组和塘边组.河口组以紫红、砖红色砾岩、砂岩为主,塘边组以紫红色砂岩、粉砂岩、泥岩为主.本文介绍了区内丹霞地貌类型,并结合对该区地质特征研究,提出岩性差异、地层产状、构造发育和水流影响为龟峰丹霞地貌形成的主要因素.     

西秦岭断裂构造系统基本特征及其对地质灾害的控制 作用

通过对青藏高原东北缘西秦岭地区断裂构造系统的特征及与滑坡、泥石流等地质灾害关系的分析研究,探讨了断裂构造系统对滑坡、泥石流等地质灾害的形成和分布的控制作用。认为虽然滑坡、泥石流等地质灾害是内外动力地质作用复杂的联合作用的结果,但断裂构造系统及其活动性对滑坡、泥石流等地质灾害形成具有关键性的作用,这种作用方式有直接和间接之分。西秦岭地区典型的滑坡、泥石流等的形成大多与断裂构造及其活动密切相关,主要表现在:(1)断裂构造发育的区域一般是滑坡、泥石流高发区;(2)断裂带活动为滑坡和泥石流的发生提供了物源和结构条件;(3)断裂的地震活动是诱发滑坡的关键因素;(4)断裂带的长期活动形成的构造破碎带和地形高差易于为流水的侵蚀而形成泥石流沟和陡坡地形。因此在对滑坡、泥石流等地质灾害研究中,不应孤立的认识单个滑坡、泥石流的形成与发展,而应把其放在区域地质环境演化中去认识,尤其是把区域断层格架、断层带结构和断层活动性研究作为地质灾害形成与发展的关键影响因素深入研究,从而为科学认识崩塌、滑坡、泥石流等地质灾害的形成过程、制定科学的灾害的防御和治理方案提供科学依据。     

大直径钻孔灌注桩桩身倾斜数值模拟分析研究

本文验证了有限差分法模型模拟大直径钻孔灌注桩的可靠性。在此基础上对某工程灌注桩底部分桩身发生倾斜的情况进行了FLAC3D模拟,分析了其承载力及稳定性的变化,从而得出在一定倾斜范围内,桩的承载力及稳定性变化不会对工程实际产生太大的影响。     

青藏高原东北缘龙首山晚新生代多阶段构造隆升的盆地记录

龙首山地区位于青藏高原与阿拉善地块的结合部位,其盆山演化过程和断裂带扩展模式的恢复对揭示青藏高原新生代北东向生长具有重要意义。本文基于龙首山南北两麓3个新近系沉积剖面的构造特征和5个砂岩样品的碎屑锆石U-Pb同位素LA-ICP-MS年龄结果,重建了青藏高原东北缘龙首山地区晚新生代的盆山演化过程。研究结果显示,龙首山地区晚新生代沉积-构造演化经历了3个主要阶段：（1）~14Ma,龙首山南缘断裂带活化,阿拉善地块南缘沿此断裂逆冲于张掖盆地之上,张掖盆地开始接收阿拉善地块的物源;（2）~5Ma,龙首山南缘断裂带的次级断裂开始发育,使龙首山南侧山麓白垩系开始剥露并为张掖盆地提供物源,同时,龙首山北缘断裂带活化并导致潮水盆地发生挠曲沉降,接收龙首山的物源;（3）5~2.5Ma,龙首山北缘断裂带的次级断裂开始发育,导致龙首山北麓白垩系开始剥露并为潮水盆地提供物源。通过对龙首山周缘盆地沉积相和物源开展分析,本研究反演了龙首山地区中新世以来的断裂带活动和山体隆升过程,表明在14~2.5Ma,随着龙首山南缘断裂、北缘断裂的活化和次级断裂的发育,龙首山经历了3次强烈的隆升,这对揭示青藏高原北东向的扩展过程具有重要的指示意义。

     

雄安新区牛东断裂带碳酸盐岩热储探测及其对地热勘探的启示

雄安新区在暂不考虑开采砂岩热储地热资源的前提下,探明碳酸盐岩热储东部边界断裂牛东断裂带的分布位置与地热资源品质,对新区地热资源开发利用规划的编制与整体能源利用布局均有着重要意义。以雄安新区高铁片区第一口碳酸盐岩热储勘探井D09孔的探测数据为依据,结合地震剖面解释成果,分析了牛东断裂带内碳酸盐岩热储的空间展布特征、储集层物理性质与单井产能参数,并简述其对地热勘探的指导意义。探测结果表明,牛东断裂带的碳酸盐岩热储主要为蓟县系雾迷山组含硅质的白云岩,分布在断裂西侧基岩宽缓背斜顶部,层状稳定,厚约2000m,顶板埋深1000~1200m,井口水温约70℃,单井水量约102m3/h。D09孔揭示,在距风化壳顶部678m的地层内共发育122个裂隙带,累计厚度达251.20m,裂隙发育率37%,平均孔隙度9.26%,裂隙发育率与平均孔隙度明显比断裂带外地热井高出50%。D09孔与牛东断裂带周缘地热井的地层地温梯度、地热水水化学特征、储集层导水系数等对比分析表明,垂直断距达7000m的牛东断裂带是一条导水导热的盆内隐伏型深断裂,其限定了雄安新区碳酸盐岩热储含水系统的东部边界,构成了西侧牛驼镇凸起的导水通道与东侧霸县凹陷油气运移的阻隔屏障,控制了牛驼镇凸起面积达1000km2的整装地热田的形成。