Crystal-Melt Separation and the Development of Isotopic Heterogeneities in Hybrid Magmas

If a magma is a hybrid of two (or more) isotopically distinctend-members, at least one of which is partially crystalline,separation of melt and crystals after hybridization will leadto the development of isotopic heterogeneities in the magmaas long as some of the pre-existing crystalline material (antecrysts)retains any of its original isotopic composition. This holdstrue whether the hybridization event is magma mixing as traditionallyconstrued, bulk assimilation, or melt assimilation. Once a magma-scaleisotopic heterogeneity is formed by crystal–melt separation,it is essentially permanent, persisting regardless of subsequentcrystallization, mixing, or equilibration events. The magnitudeof the isotopic variability resulting from crystal–meltseparation can be as large as that resulting from differentialcontamination, multiple isotopically distinct sources, or insitu isotopic evolution. In one model, a redistribution of one-thirdof the antecryst cargo yielded a crystal-enriched sample with⁸⁷Sr/⁸⁶Sr of 0·7058, whereas the complementary crystal-poorsample has ⁸⁷Sr/⁸⁶Sr of 0·7068. In other models, crystal-richsamples are enriched in radiogenic Sr. Isotopic heterogeneitiescan be either continuous (controlled by the modal distributionof crystals and melt) or discontinuous (when there is completeseparation of crystals and liquid). The first case may be exemplifiedby some isotopically zoned large-volume rhyolites, formed bythe eruptive inversion of a modally zoned magma chamber. Inthe latter case, the isotopic composition of any (for example)interstitial liquid will be distinct from the isotopic compositionof the bulk crystal fraction. The separation of such an interstitialliquid may explain the presence of isotopically distinct late-stageaplites in plutons. Crystal–melt separation provides anadditional option for the interpretation of isotopically zonedor heterogeneous magmas. This option is particularly attractivefor systems whose chemical variation is otherwise explicableby fractionation-dominated processes. Non-isotopic chemicalheterogeneities can also develop in this fashion. KEY WORDS: isotopic heterogeneity; zoning; hybrid magma; crystal separation; Sr isotopes; aplite; rhyolite     

Comparison of arsenic concentrations in simultaneously-collected groundwater and aquifer particles from Bangladesh,India, Vietnam,and Nepal

One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.     

Characterization and cycling of atmospheric mercury along the central US Gulf Coast

Concentrations of atmospheric Hg species, elemental Hg (Hg^°), reactive gaseous Hg (RGM), and fine particulate Hg (Hg-PM_2.5) were measured at a coastal site near Weeks Bay, Alabama from April to August, 2005 and January to May, 2006. Mean concentrations of the species were 1.6 ± 0.3 ng m⁻³, 4.0 ± 7.5 pg m⁻³ and 2.7 ± 3.4 pg m⁻³, respectively. A strong diel pattern was observed for RGM (midday maximum concentrations were up to 92.7 pg m⁻³), but not for Hg^° or Hg-PM_2.5. Elevated RGM concentrations (>25 pg m⁻³) in April and May of 2005 correlated with elevated average daytime O₃ concentrations (>55 ppbv) and high light intensity (>500 W m⁻²). These conditions generally corresponded with mixed continental-Gulf and exclusively continental air mass trajectories. Generally lower, but still elevated, RGM peaks observed in August, 2005 and January–March, 2006 correlated significantly (p < 0.05) with peaks in SO₂ concentration and corresponded to periods of high light intensity and lower average daytime O₃ concentrations. During these times air masses were dominated by trajectories that originated over the continent. Elevated RGM concentrations likely resulted from photochemical oxidation of Hg^° by atmospheric oxidants. This process may have been enhanced in and by the near-shore environment relative to inland sites. The marine boundary layer itself was not found to be a significant source of RGM.     

Biofacies analysis of Upper Cretaceous deposits in the Ust-Yenisei region: Implications of palynomorphs

The results of palynomorph biofacies analysis in the Upper Cretaceous deposits of the Ust-Yenisei region are presented. The established facies confinement and indicative features of separate palynomorph groups are used, along with identified dinocyst morphotypes and taxa, in paleogeographic reconstructions. Seven palynomorph associations characterizing continental, coastal-marine, shallow-and deep-water facies are distinguished based on quantitative proportions between morphological groupings and individual taxa. As boundaries between distinguishable biostratigraphic and facies subdivisions do not coincide, dinocysts were likely insignificantly dependent in distribution on facies in the West Siberian epicontinental basin at least. On the other hand, distribution trends of particular dinocyst morphotypes and other microphytofossils are correlative with transgressive-regressive cycles and can be used for reconstruction of paleoenvironments.     

Correlation of the Jurassic-Cretaceous siliceous-volcanogenic sediments in northwestern surroundings of the Pacific (Koryak Upland)

In distribution areas of the Pekul’neiveem and Chirynai formations customary distinguishable in the Koryak Upland, complicated tectonostratigraphic units are composed of alternating thrust sheets of different lithologic composition and age, which are juxtaposed because of widespread thrust faulting, as is proved by the radiolarian analysis. Nineteen radiolarian assemblages of different age are first established here in the Lower Jurassic-Hauterivian succession of siliceous-volcanogenic sediments. In the Lower Jurassic interval, the lower and upper Hettangian, lower and upper Sinemurian, and Pliensbachian beds are recognized. Paleontological characterization is also presented for the Aalenian (or Toarcian?-Aalenian), upper Bajocian, lower and upper Bathonian, and Callovian beds of the Middle Jurassic. Within the Upper Jurassic, the Oxfordian-early Kimmeridgian, late Kimmeridgian-early Tithonian, Tithonian, and late Tithonian-early Berriasian radiolarian assemblages are distinguished. The late Berriasian-early Valanginian, middle-late Valanginian, and Hauterivian radiolarian assemblages are first recognized or compositionally revised. Radiolarians and lithofacies data are used to correlate the tectonostratigraphic units and individualize the jasper-alkali basaltic (lower Hettangian), chert-terrigenous (Hettangian-Sinemurian), jasper-cherty (Pliensbachian-Aalenian), jasper (Bajocian-Hauterivian), jasper-basaltic (upper Bajocian-Valanginian), Fe-Ti basaltic (upper Bajocian-Bathonian), tuffitejasper-basaltic (Bathonian-Hauterivian), and terrigenous-volcanogenic (Bajocian-Valanginian) sequences. The correlation results are extrapolated into other continental areas flanking the Pacific, i.e., to the western Kamchatka, northern and northwestern coastal areas of the Sea of Okhotsk, where the analogous radiolarian assemblages are characteristic of comparable allochthonous units of terrigenous-siliceous-volcanogenic sediments.     

Campanian-Maastrichtian radiolarians from the Malokuril’skaya Formation,the Shikotan Island

The results of radiolarian analysis confirm the Campanian-Maastrichtian age of the Malokuril’skaya Formation in the Shikotan Island. The Campanian-Maastrichtian age of the formation is implied simultaneously by radiolarians and inoceramids. The studied Campanian and Campanian-Maastrichtian radiolarian assemblages include abundant specimens representing genus Prunobrachium, characteristic of which was bipolar distribution in cold-water to temperate basins. The new occurrence site of prunobrachids is established at the latitude of 43°N, the Far East of Russia.     

Geochronology of Pliocene volcanism in the Dzhavakheti Highland (the Lesser Caucasus). Part 1: Western part of the Dzhavakheti Highland

Isotopic-geochronological study of the Pliocene magmatic activity in western part of the Dzhavakheti Highland (northwestern region of the Lesser Caucasus) is carried out. The results obtained imply that the Pliocene magmatic activity lasted in this part of the highland approximately 2 million years from 3.75 to 1.75–1.55 Ma. As is established, the studied volcanic rocks correspond in composition mostly to K-Na subalkaline and more abundant normal basalts. Time constraints of main phases in development of basic volcanism within the study region are figured out. We assume that individual pulses of silicic to moderately silicic volcanism presumably took place in the Dzhavakheti Highland about 3.2 and 2.5 Ma ago.     

On the global stratotype section and point of the Triassic base

A unique succession of volcanogenic deposits with representative paleontological remains characterizing the Permian-Triassic boundary interval in the North Siberian platform and Taimyr is described. The succession is suitable for selecting a standard for the Triassic base in nonmarine deposits. Abundant and diverse fossils occurring in the succession evidence that volcanism responsible for origin of the plateau basalt province in Siberia was not a brief epoch of paroxysmal eruptions, which eliminated everything alive. Throughout the formation history of relevant plateau basalts, the organic world of the plateau and around existed and gradually evolved.     

Planktonic foraminifers in the southern Bering Sea: Changes in composition and productivity during the Late Pleistocene-Holocene

Taxonomic composition and distribution of planktonic foraminifers are studied in section of Core GC-11 that penetrated through Upper Quaternary sediments of the Bowers Ridge western slope, the southern Bering Sea. As is shown, structure of foraminiferal assemblage and productivity have varied substantially during the last 32000 calendar years in response to changes in surface water temperatures and water mass circulation in the northern part of the Pacific, the Bering Sea included. The productivity was maximal during deglaciation epoch, being notably lower in the Holocene and minimal at the glaciation time.     

New fusulinids of the Moscovian Stage found in Iran

The described fusulinids of the Moscovian Stage are found in the Asad-Abad section of the Sanandaj-Sirjan tectonic zone of Iran. Five successive fusulinid assemblages are distinguished. Three lower of them belong to the Kashirian Substage, the other two to the Podolskian Substage. The section studied is correlated with most complete sections of the Moscovian Stage in the western Tethys. Two new species Fusulinella (Moellerites) pygmea and Putrella primaris are identified; in addition to nominative taxon, the latter includes new subspecies P. primaris compacta.