Sound velocity,density, and related properties along a transect across the Bay of Bengal

Physical properties, sound velocity and density of 95 core samples from ten locations along a transect (parallel to 15°N latitude) across the Bay of Bengal were measured. Results indicate that sound velocities range from 1,482 to 1,679 m/s (av: 1,583 m/s) and densities from 1,338 to 1,757 kg/m³ (av: 1,527 kg/m³). It has been observed that dark colored clays and sandy clays show higher values of sound velocity and density than the average values. A comparative study of the same with that of the sediment cores collected from the Norwegian basin, Mediterranean Sea, and Hatteras, Nares Abyssal plains, western North Atlantic Ocean was done.     

On the sulphur chemistry of a super-anoxic fjord, Framvaren, South Norway

The concentrations of total carbonate (C_t), sulphate, sulphide, thiols and oxygen, the ratio between the stable sulphur isotopes ³⁴S and ³²S in sulphate and sulphide, and the density (used to calculate salinity) were determined on samples from the water column of Framvaren, a superanoxic fjord in southern Norway. From a depth of 18m (the oxic-anoxic boundary) the initial sulphate concentration, ([SO₄]_init), as calculated from salinity, is significantly higher than the sum of the measured sulphur species. This is attributed to a loss of sulphur from the water column. The amount of total carbonate produced, corrected for the initial concentration (C_t - 2.4 Sal/35) is found to be proportional to the amount of sulphate consumed, ([SO₄]_init - [SO₄]), according to the following relation C_t- 2.4 Sal/35 = 1.84 ([SO₄]_init - [SO₄]). Isotopic fractionation caused by bacterial sulphate reduction in the anoxic part of the water column produces sulphide with a δ³⁴S 40‰ lower than the δ³⁴S for sulphate at corresponding depths. The isotopic fractionation also results in δ³⁴S value for the remaining sulphate at depths below 80 m being considerably higher than the mean value for ocean water, which is close to + 20‰. The δ³⁴S values for sulphate at depths between 10 and 50 m were lower than + 20‰ which indicates oxidation of sulphide, which follows upon diffusion of sulphide from deeper parts of the water column and inflow of oxygenated seawater over the sill into the anoxic water of the fjord. A conclusive scenario of the Framvaren sulphur chemistry is presented.     

Wave transmission and reflection characteristics of a rigid surface and submerged horizontal plate

The wave transmission and reflection characteristics of a rigidly fixed surface and submerged horizontal plate were investigated experimentally in detail for a wide range of incident wave steepnesses and for different depths of submerge of the plate in deep water conditions in regular water wave fields. The experiments were conducted at the Ocean Engineering Centre, Indian Institute of Technology, Madras, India, in a wave flume 10 m long, 0.3 m wide and in a constant water depth of 0.8 m. The horizontal plate is 0.22 m thick and 1.2 m in length, covering the enrire width of the flume. From the present investigation, it is found that for a rigid surface plate, the coefficient of transmission is a minimum and the coefficient of reflection is a maximum, but the maximum value of the coefficient of energy loss occurs for plates submerged closer to the still-water level (SWL) and not for the surface plate. It is also found that the value of the coefficient of reflection increases with the increase in the value of the Reddy-Neelamani (RN) number, the ratio of horizontal water particle excursion at the bottom of the plate in its absence to the length of the plate. The coefficient of transmission is found to decrease rapidly with increase in the value of RN number up to 0.1. The wave transmission is only 5% for RN from 0.1 to 0.2. It is also found that for RN number greater than 0.04, the minimum energy dissipation is consistently about 60% of the incident wave energy.     

Multipole expansions for wave diffraction and radiation in deep water

A multipole expansion of the velocity potential is described for two- and three-dimensional wave diffraction and radiation problems. The velocity potential is expressed in terms of a series of multipole potentials. The wave terms and the local disturbance terms are represented by separated multipole potentials. Floating bodies and submerged bodies are treated in the same way. This approach differs from that of some other authors, who considered floating bodies and submerged bodies separately and derived entirely different multipoles. Semi-analytical solutions for a circular cylinder in two-dimensional motions are given. It is found that the local disturbance decays rapidly and steadily. The general application of the multipole expansion to arbitrary geometries is also presented, based on a method coupling multipoles to a boundary integral expression. Numerical results for several floating and submerged cylinders are presented.     

Estimates of the characteristics of the horizontal turbulent exchange in the northwestern part of the Pacific Ocean

Estimates of the characteristics of the horizontal turbulent exchange (coefficients of horizontal exchange, scales of deviations of the velocity of geostrophic currents from the background flows, and horizontal scales of perturbations) in the upper ocean layer were obtained on the basis of the data of expeditions held in 1978 and 1980 in the northwestern part of the Pacific Ocean. It is shown that the characteristics of the horizontal turbulent exchange strongly depend on the structure of the background flows, and one of the causes of their variability is related to tropical cyclones. A tendency to a decrease (to different degrees) of the turbulent coefficients in the wake of a tropical cyclone is noted.     

On the relevance of iron adsorption to container materials in small-volume experiments on iron marine chemistry: Fe-aided assessment of capacity, affinity and kinetics

Iron chemistry in seawater has been extensively studied in the laboratory, mostly in small-volume sample bottles. However, little has been reported about iron wall sorption in these bottles. In this paper, radio-iron ⁵⁵Fe was used to assess iron wall adsorption, both in terms of capacity, affinity and kinetics. Various bottle materials were tested. Iron sorption increased from polyethylene/polycarbonate to polymethylmetacrylate (PMMA)/high-density polyethylene/polytetrafluoroethylene to glass/quartz, reaching equilibrium in a 25–70 h period. PMMA was studied in more detail: ferric iron (Fe(III)) adsorbed on the walls of the bottles, whereas ferrous iron (Fe(II)) did not. Considering that in seawater the inorganic iron pool mostly consists of ferric iron, the wall will be a factor that needs to be considered in bottle experiments.The present data indicate that for PMMA with specific surface (S)-to-volume (V) ratio S/V, both iron capacity (42 ± 16 × 10^− 9 mol/m² or 1.7 × 10^− 9 mol/L recalculated for the S/V-specific PMMA bottles used) and affinity (log K_Fe'W = 11.0 ± 0.3 m²/mol or 12.4 ± 0.3 L/mol, recalculated for the S/V-specific PMMA bottles used) are of similar magnitude as the iron capacity and -affinity of the natural ligands in the presently used seawater and thus cannot be ignored.Calculation of rate constants for association and dissociation of both Fe'L (iron bound to natural occurring organic ligands) and Fe'W (iron adsorbed on the wall of vessels) suggests that the two iron complexes are also of rather similar kinetics, with rate constants for dissociation in the order of 10 ⁻⁴–10^− 5 L/s and rate constants for association in the order of 10⁸ L/(mol s). This makes that iron wall sorption should be seriously considered in small-volume experiments, both in assessments of shorter-term dynamics and in end-point observations in equilibrium conditions. Therefore, the present data strongly advocate making use of iron mass balances throughout in experiments in smaller volume set-ups on marine iron (bio) chemistry.     

Chalk shore platform erosion in the vicinity of sea defence structures and the impact of construction methods

Erosion of the intertidal chalk platform in the vicinity of groynes and seawalls is evident to the naked eye along many stretches of the engineered coastline of southeast England, leading to undermining and eventually failure of these structures. However, quantification of the magnitude and spatial extent of the erosion has been difficult to date because of a lack of data about the past elevation of the platform. The application of softcopy photogrammetry makes it possible to recreate past platform elevations from historic air photographs and to compare these with elevations from modern air photographs. Coastal sea defence structures have been installed along the chalk coast east of Brighton at various dates over the past 70 years. During this period, the construction methods have changed from predominantly manual labour to a reliance on heavy machines. The analysis of erosion patterns around structures built since the 1970s using heavy machinery show that surface lowering is 4 to 25 times greater in the vicinity of these structures than across the platform as a whole. In contrast, there is no similar pattern of increased erosion around structures built using predominantly manual labour in the 1930s. A four fold increase in average surface lowering is found also along a vehicle trackway that crosses the mid platform. Depressions developed by enhanced lowering in the front of seawalls generate their own dynamic of increased erosion by trapping pebbles and cobbles that enhance the abrasion of the chalk through bedload transport under standing waves in front of the walls.     

On the use of poorly soluble hygroscopic substances for modification of warm clouds and fogs

From analysis of the relationships between the equilibrium state of condensation nuclei and the relative humidity, a conclusion is made concerning the preferred use of poorly soluble substances for the generation of artificial condensation nuclei (ACN) designed for modification of warm clouds and fogs with the purpose of their dissipation and precipitation formation. The advantage of poorly soluble substances over commonly used soluble salts is that the finely dispersed part of the spectrum of the poorly soluble ACN does not deliquesce and so is not involved in the formation of cloud droplets. For experimental testing of the conclusions, preference was given to cement, whose main soluble substance is calcium oxide with a solubility of about 1 g/l. The spectrum of dispersed cement particles was measured and compared with the spectra of pyrotechnic flares widely used for modification at present. The process of formation of the cloud droplet spectra was simulated in the aerosol chamber of the Institute of Experimental Meteorology by decreasing the preliminarily generated excess pressure. It was found in these experiments that, compared to the spectra of particles formed on background condensation nuclei, the introduction of dispersed cement leads to the broadening of spectra and to a decrease in the concentration of droplets. Even at the early stage of condensation, droplets with radii of ∼20 μm appear. In this case, no “overseeding” phenomenon is observed, which, for soluble substances, manifests itself in an increase in the concentration of cloud droplets with a large ACN concentration. These effects indicate that, according to the existing concepts about the mechanism of warm-cloud modification with hygroscopic substances, the introduction of poorly soluble ACN (in particular, dispersed cement) below the base of cumulus clouds should stimulate coagulation processes and accelerate rain-formation processes. Considerations are given that the introduction of poorly soluble ACN into the already existing cumulus or stratocumulus clouds or fogs should also result in the acceleration of precipitation-formation processes or cloud dispersal. Comparison of cement powder with the well-known means of warm-cloud and fog modification is carried out. Original Russian Text ? N.P. Romanov, A.S. Drofa, N.S. Kim, A.V. Savchenko, G.F. Yaskevich, 2006, published in Izvestiya AN. Fizika Atmosfery i Okeana, 2006, Vol. 42, No. 1, pp. 80–91.     

Estimation of the long-term variability of hydrophysical characteristics of the Black Sea based on the assimilation of the climatic hydrological fields L and altimetry data

To study the long-term variability of the thermohaline and dynamic characteristics of the Black Sea, we use three versions of climatic fields, namely, the fields reconstructed in the model according to the old (1903–1982) and new (1903–2003) hydrological climatic data arrays of temperature and salinity and according to the data of satellite altimetry. The analysis of the altimetry-based climatic fields confirms the distinctions (established earlier according to the old and new data arrays) in the seasonal variability of the integral characteristics of temperature and salinity and in the structures of hydrophysical fields in the sea. It is shown that, in the winter-spring season, the thermohaline fields reconstructed according to the new and altimetry data arrays are characterized by a small elevation of the halocline (pycnocline) and the upper boundary of the cold intermediate layer. In all seasons, the altimetry-based surface geostrophic currents contain numerous mesoscale eddies with different signs of rotation. Moreover, in all seasons, the Rim Current reconstructed according to the altimetry data is characterized by a narrower jet almost along the entire its length. This jet is especially intense near the coasts of West Anatolia. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 4, pp. 3–17, July–August, 2006.