Linked to Landscape: Assessing Urbanization in Germany through Landscape and Economic Factors

The ongoing encroachment of urban land into natural landscapes has resulted in the degradation of ecosystems throughout Europe. Understanding why the share of urban land has increased is important for managing urban growth and maintaining ecosystem services. We estimate a model of landscape change that integrates geospatial and socioeconomic data in a spatial autoregressive model to explain the variance in urban growth observed in Germany between 2000 and 2006. In doing so, we test several determinants of urbanization identified by theoretical frameworks from landscape ecology and economics, including landscape pattern and transit infrastructure. The results show that despite planning guidelines and policies to promote dense development, urban growth has been extensive. Regions with a high degree of fragmented land and the prevalence of environmental amenities are characterized by particularly strong growth, pointing to challenges in crafting landscape policies that balance economic development with environmental conservation.     

Die Matrix der Fische XVI Zweidimensionale papierchromatographische Analyse von Fischschuppenhydrolysaten und Hydrolysaten einiger weiterer Fischorgane

Summary The aminoacids in hydrolysates (HCl) of the scales of six different fish-species have been determined by partition paper chromatography (Consden andDent). The scales contain considerable amounts of protein besides hydroxyl apatit and guanin, but none or only minute quantities of carbohydrates. Some of the aminoacids in the liver, air-bladder, kidney and the body muscles of two fish species were investigated.      

Sedimentary framework of the modern Huanghe (Yellow River) delta

The geometry, stratigraphy, and structure of recently deposited Huanghe (Yellow River) Delta sediments were examined by high resolution subbottom profiles and medium-penetration boomer profiles. The results indicate that the active (post-1976) subaqueous delta advances as a single thin localized lobe with a maximum thickness of only 15 m. Calculations of sediment volumes indicate that 90% or more of the sediment supplied by the Huanghe remains within 30 km of the mouth. Sediment on the delta platform near the mouth is fine sand; elsewhere silts and clays prevail.[/p]     

Measuring snow ablation rates in alpine terrain with a mobile multioffset ground‐penetrating radar system

Ground‐penetrating radar (GPR) has become a promising technique in the field of snow hydrological research. It is commonly used to measure snow depth, density, and water equivalent over large distances or along gridded snow courses. Having built and tested a mobile lightweight set‐up, we demonstrate that GPR is capable of accurately measuring snow ablation rates in complex alpine terrain. Our set‐up was optimized for efficient measurements and consisted of a multioffset radar with four pairs of antennas mounted to a plastic sled, which was small enough to permit safe and convenient operations. Repeated measurements at intervals of 2 to 7 days were taken during the 2014/2015 winter season along 10 profiles of 50 to 200 m length within two valleys located in the eastern Swiss Alps. Resulting GPR‐based data of snow depth, density, and water equivalent, as well as their respective change over time, were in good agreement with concurrent manual measurements, in particular if accurate alignment between repeated overpasses could be achieved. Corresponding root‐mean‐square error (RMSE) values amounted to 4.2 cm for snow depth, 17 mm for snow water equivalent, and 22 kg/m³ for snow density, with similar RMSE values for corresponding differential data. With this performance, the presented radar set‐up has the potential to provide exciting new and extensive datasets to validate snowmelt models or to complement lidar‐based snow surveys.     

Dawn Mission to Vesta and Ceres

The initial exploration of any planetary object requires a careful mission design guided by our knowledge of that object as gained by terrestrial observers. This process is very evident in the development of the Dawn mission to the minor planets 1 Ceres and 4 Vesta. This mission was designed to verify the basaltic nature of Vesta inferred both from its reflectance spectrum and from the composition of the howardite, eucrite and diogenite meteorites believed to have originated on Vesta. Hubble Space Telescope observations have determined Vesta’s size and shape, which, together with masses inferred from gravitational perturbations, have provided estimates of its density. These investigations have enabled the Dawn team to choose the appropriate instrumentation and to design its orbital operations at Vesta. Until recently Ceres has remained more of an enigma. Adaptive-optics and HST observations now have provided data from which we can begin to confidently plan the mission. These observations reveal a rotationally symmetric body with little surface relief, an ultraviolet bright point that can be used as a control point for determining the pole and anchoring a geographic coordinate system. They also reveal albedo and color variations that provide tantalizing hints of surface processes.     

Sensitivity of nitrate concentration-discharge patterns to soil nitrate distribution and drainage properties in the vertical dimension

We propose a conceptual model that examines the ‘variable source area’ (VSA) and ‘nitrate flushing’ hypothesis in the vertical direction, and use this approach to explain nitrate concentration–discharge relationships in a semi-arid watershed. We use an eco-hydrology simulation model (RHESSys) to show that small changes in the vertical distribution of nitrate mass and their interaction with soil hydraulic conductivity can result in abrupt changes in the nitrate concentration–discharge relationship. We show that the estimated concentration–discharge relationship is sensitive to the parameters governing soil vertical nitrate distribution and soil hydraulic conductivity, at both patch scale and watershed scale, where lateral redistribution of water and nitrate is also accounted for. Given heterogeneity in nitrogen inputs, uptake processes, soil drainage and storage processes, substantial variation in parameters that describe rate of changes in vertical distribution of soil nitrate and hydraulic properties is likely both within and between watersheds. Thus, we argue that vertical ‘variable source area’ processes may be as important as lateral VSA in determining concentration discharge relationships.     

An experimental study of the formation of cubanite (CuFe2S3) in primitive meteorites

The low‐temperature form of CuFe₂S₃, cubanite, has been identified in the CI chondrite and NASA Stardust mission collections. The presence of this mineral constrains the maximum temperature to 210 °C since the time of its formation. However, until now, the conditions under which cubanite forms were less well constrained. In order to refine the history of the time‐varying, low‐temperature fluids which existed on the CI‐chondrite parent body and Comet 81P/Wild 2 (Wild 2), we synthesized cubanite. The experimental synthesis of this mineral was achieved, for the first time, under low‐temperature aqueous conditions relevant to the CI‐chondrite parent body. Using a variant of in situ hydrothermal recrystallization, cubanite formed in aqueous experiments starting with temperatures of 150 and 200 °C, pH approximately 9, and oxygen fugacities corresponding to the iron‐magnetite buffer. The composition and structure of the cubanite were determined using electron microprobe and transmission electron microscopy techniques, respectively. The combined compositional, crystallographic, and experimental data allow us to place limits on the conditions under which the formation of cubanite is feasible, which in turn constrains the nature of the fluid phase on the CI‐chondrite parent body and Wild 2 when cubanite was forming.     

Microstructural evidence for a disequilibrium condensation origin for hibonite‐spinel inclusions in the ALHA77307 CO3.0 chondrite

Two hibonite‐spinel inclusions (CAIs 03 and 08) in the ALHA77307 CO3.0 chondrite have been characterized in detail using the focused ion beam sample preparation technique combined with transmission electron microscopy. These hibonite‐spinel inclusions are irregularly shaped and porous objects and consist of randomly oriented hibonite laths enclosed by aggregates of spinel with fine‐grained perovskite inclusions finally surrounded by a partial rim of diopside. Melilite is an extremely rare phase in this type of CAI and occurs only in one inclusion (CAI 03) as interstitial grains between hibonite laths and on the exterior of the inclusion. The overall petrologic and mineralogical observations suggest that the hibonite‐spinel inclusions represent high‐temperature condensates from a cooling nebular gas. The textural relationships indicate that hibonite is the first phase to condense, followed by perovskite, spinel, and diopside. Texturally, melilite condensation appears to have occurred after spinel, suggesting that the condensation conditions were far from equilibrium. The crystallographic orientation relationships between hibonite and spinel provide evidence of epitaxial nucleation and growth of spinel on hibonite surfaces, which may have lowered the activation energy for spinel nucleation compared with that of melilite and consequently inhibited melilite condensation. Hibonite contains abundant stacking defects along the (001) plane consisting of different ratios of the spinel and Ca‐containing blocks within the ideal hexagonal hibonite structure. This modification of the stacking sequence is likely the result of accommodation of excess Al in the gas into hibonite due to incomplete condensation of corundum from a cooling gas under disequilibrium conditions. We therefore conclude that these two hibonite‐spinel inclusions in ALHA77307 formed by high‐temperature condensation under disequilibrium conditions.