江南造山带雪峰隆起区元古宙浊积岩沉积构造背景的地球化学制约

江南造山带雪峰隆起区元古宙浊积岩的地球化学组成良好地反映了沉积盆地的板块构造性质,并为解释区域大地构造的性质和演化提供了有用的信息。中元古代冷家溪群和新元古代板溪群(包括下部马底驿组和上部五强溪组)地层在主元素成分上无明显区别,总体上以中等SiO2含量和K2O/Na2O比值以及较高的(Fe2O3+MgO)含量为特征。稀土元素球粒陨石标准化曲线与典型的后太古宙页岩(如PAAS或NASC)和上陆壳相似,以轻稀土富集、显著的铕负异常和重稀土平坦为特征。大离子亲石元素和铁镁族元素的含量中等。主元素和微量元素特征指示了研究区元古宙浊积岩很可能代表了一套活动大陆边缘弧后沉积盆地的产物。陆内裂谷盆地模式对于解释新元古代华南地区的构造性质和演化可能并不合适。华夏陆块与扬子陆块的拼接以及Rodinia超大陆的最终形成可能发生在约0.8Ga左右的晋宁(雪峰)造山运动期,而不是全球Grenville造山期末的四堡(东安)运动期。     

Pb/Pb and U/Pb zircon dating of subvolcanic rhyolite as a time marker for Hercynian granite magmatism and Sn mineralisation in the Eibenstock granite, Erzgebirge, Germany: Considering effects of zircon alteration

Tin mineralisation is closely related to rhyolite stocks and dykes which occur in the endo- and exocontact of the Eibenstock granite, Erzgebirge, Germany. The same structures which cut the granite control the rhyolite emplacement and the location of ore-bearing greisen bodies. Albitisation and greisenisation related to tin mineralisation as well as sericitisation and argillic alteration may be traced by changes in chemical and mineralogical composition of both rhyolite and granite wall rock. Comprehensive zircon studies by scanning electron microscopy (secondary and backscattered electron as well as cathodoluminescence imaging; EDX measurements) reveal that zircon from rhyolite and from the enclosing granite shows significant changes in chemical composition and crystallinity, including distortion of the U-Pb isotope system when affected by greisenisation. Single evaporation analysis of zircon from rhyolite with little or no greisenisation gave a ²⁰⁷Pb/²⁰⁶Pb age of 290±5 Ma, whereas zircon from little altered granite gave a ²⁰⁷Pb/²⁰⁶Pb age of 320±8 Ma. The single evaporation age of zircon from rhyolite is confirmed by ²³⁸U/²⁰⁶Pb SHRIMP ages of 297±8 Ma. The significant time gap of at least 20 Ma between granite intrusion and rhyolite formation suggests that the late magmatic evolution of the Eibenstock granite cannot be regarded as a source for tin-ore forming fluids as previously assumed.     

Basement-Cover Sequences within the UHP unit of the Dabie Shan

Field data define two lithologically distinct basement‐cover sequences within the ultrahigh‐pressure metamorphic (UHPM) unit of the Dabie Shan, eastern China. One of the cover units, the Changpu unit, comprises calc‐arenitic metasediments in stratigraphic contact with a basement consisting of gneisses of the Yangtze craton. The second cover unit, the Ganghe unit, consists of felsic‐intermediate metavolcanics and clastic metasediments. Basement exposure of the Ganghe unit is not known. Fold axes in the Ganghe unit are oblique to those of the Changpu unit, which are parallel to those of the Yangtze gneisses. Preservation of primary textures in some volcanic rocks, and tectonic separation from the Yangtze gneisses by a greenschist facies mylonite, support an interpretation of the Ganghe unit as a low‐strain domain. Protolith associations in the Ganghe and Changpu units are compatible with deposition in a rift setting and along a passive continental margin, respectively. A U–Pb single zircon age of 761 ± 33 Ma for volcanoclastic rocks of the Ganghe unit demonstrates a Neoproterozoic deposition age, concordant with inferred rifting at that time. Eclogite facies parageneses in the gneisses and both cover units, along with P–T data demonstrate regional UHPM in the Dabie Shan.     

The 1992 drill core from the Kalkkop impact crater, Eastern Cape Province, South Africa: stratigraphy, petrography, geochemistry and age

New drill core data are provided which support earlier interpretations that the Kalkkop structure, a 600–630 m wide, near-circular feature south-southwest of Graaff-Reinet in the Eastern Cape Province of South Africa, is a meteorite impact crater. Shock metamorphosed clasts in suevitic crater fill and Re---Os isotope data of this breccia indicate the presence of a minor (0.05%) meteoritic component in the suevite. The new data come from a 1992 borehole, which transected the complete crater fill and extended from about 160 to 380 m depth into the sedimentary basement belonging to the Koonap Formation of the Beaufort Group (Karoo Supergroup). Dyke breccias were found in the otherwise coherent Beaufort Group sediments forming the floor to the Kalkkop Crater. Mostly narrow zones of different breccia types, including injections of lithic impact breccia, a possible pseudotachylite veinlet and cataclasite occur predominantly in an approximately 65 m wide zone below the crater floor, with a few other cataclasite occurrences found lower down in the basement. Stratigraphical crater constraints provide information for the depth-diameter scaling and breccia volumes associated with such small, bowl-shaped impact craters formed in sedimentary targets.U---Th series dating of limestone samples from near the top and the bottom of the crater sediment fill constraints the age of the Kalkkop impact event to about 250 ± 50 ka, similar to the age of the Pretoria Saltpan impact crater, also located in South Africa. The variety of different breccia types (polymict and monomict impact breccias; local formations of pseudotachylitic and cataclastic breccias) observed in the crater fill of the Kalkkop Crater indicates the need to carefully distinguish different breccia types in order to assess the respective importance of each formation.     

Radial Velocities of Six Early Type Evolved Stars

Many early-type main sequence stars are known spectroscopic binaries, while early type spectroscopic binaries with evolved components are rather rare and well-determined masses are available only in some cases. For this reason a program to study stars with suspected variable velocity among early-type evolved stars has been initiated some time ago. In the present paper 54 coudé spectra for a sub-group formed of six early-type stars, namely HD 7902, HD 28446, HD 42087, HD 187983, HD 195592 and HD 208501 have been measured and the results of these plates have been presented.     

Mesoscale Heat Transport Over Complex Terrain By Slope Winds – A Conceptual Model And Numerical Simulations

Vertical heat fluxes induced by mesoscale thermally driven circulations maycontribute significantly to the subgrid-scale fluxes in large-scale models (e.g.,general circulation models). However, they are not considered in these modelsyet. To gain insight into the importance and possible parameterisation of themesoscale flux associated with slope winds, an analytical (conceptual) modelis developed to describe the relationship between the mesoscale heat flux andatmospheric and land-surface characteristics. The analytical model allows usto evaluate the mesoscale flux induced by slope winds from only a few profilemeasurements within a domain. To validate the analytical model the resultingheat flux profiles are compared to profiles of highly resolved wind and temperaturefields obtained by simulations with a mesoscale numerical model.With no or moderate synoptic wind the mesoscale heat flux generated by the slopewind circulation may be as large as, or even larger than, the turbulent fluxes at thesame height. At altitudes lower than the crest of the hills the mesoscale flux is alwayspositive (upward). Generally it causes cooling within the boundary layer and heatingabove. Despite the simplifications made to derive the analytical model, it reproducesthe profiles of the mesoscale flux quite well. According to the analytical model, themesoscale heat flux is governed by the temperature deviation at the slope surface, thedepth of the slope-wind layer, the large-scale lapse rate, and the wavelength of thetopographical features.     

Experimental investigation of zoisite–clinozoisite phase equilibria in the system CaO–Fe2O3–Al2O3–SiO2–H2O

The system Ca₂Al₃Si₃O₁₁(O/OH)-Ca₂Al₂FeSi₃O₁₁(O/OH), with emphasis on the Al-rich portion, was investigated by synthesis experiments at 0.5 and 2.0 GPa, 500-800 °C, using the technique of producing overgrowths on natural seed crystals. Electron microprobe analyses of overgrowths up to >100 µm wide have located the phase transition from clinozoisite to zoisite as a function of P-T-X_ps and a miscibility gap in the clinozoisite solid solution. The experiments confirm a narrow, steep zoisite-clinozoisite two-phase loop in T-X_ps section. Maximum and minimum iron contents in coexisting zoisite and clinozoisite are given by X_ps^zo (max) = 1.9*10 ^{- 4} T+ 3.1*10 ^{- 2} P - 5.36*10 ^{- 2}{\rm X}_{{\rm ps}}^{{\rm zo}} {\rm (max) = 1}{\rm .9*10}^{ - 4} T{\rm + 3}{\rm .1*10}^{ - 2} P - {\rm 5}{\rm .36*10}^{ - 2} and X_ps^czo (min) = (4.6 * 10 ^{- 4} - 4 * 10 ^{- 5} P)T + 3.82 * 10 ^{- 2} P - 8.76 * 10 ^{- 2}{\rm X}_{{\rm ps}}^{{\rm czo}} {\rm (min)} = {\rm (4}{\rm .6} * {\rm 10}^{ - {\rm 4}} - 4 * {\rm 10}^{ - {\rm 5}} P{\rm )}T + {\rm 3}{\rm .82} * {\rm 10}^{ - {\rm 2}} P - {\rm 8}{\rm .76} * {\rm 10}^{ - {\rm 2}} (P in GPa, T in °C). The iron-free end member reaction clinozoisite = zoisite has equilibrium temperatures of 185ᇆ °C at 0.5 GPa and 0ᇆ °C at 2.0 GPa, with (H_r⁰=2.8ǃ.3 kJ/mol and (S_r⁰=4.5ǃ.4 J/mol2K. At 0.5 GPa, two clinozoisite modifications exist, which have compositions of clinozoisite I ~0.15 to 0.25 X_ps and clinozoisite II >0.55 X_ps. The upper thermal stability of clinozoisite I at 0.5 GPa lies slightly above 600 °C, whereas Fe-rich clinozoisite II is stable at 650 °C. The schematic phase relations between epidote minerals, grossular-andradite solid solutions and other phases in the system CaO-Al₂O₃-Fe₂O₃-SiO₂-H₂O are shown.