Redistribution of HFSE elements during rutile replacement by titanite

Titanite growth at the expense of rutile during retrograde hydration of eclogite into amphibolite is a common phenomenon. We investigated an amphibolite sample from the Tromsø eclogite facies terrain in Northern Norway to gain insight into the trace element distribution between rutile and titanite during incomplete resorption of the rutile by titanite. Patchy compositional zoning of Al, Ti, and F in titanite relates to the presence of a fluid with variable Ti/Al and/or F during its growth. Laser ablation ICP–MS and electron microprobe data for high field strength elements (HFSE: Nb, Zr, Ta, and Hf) of rutile resorbed by titanite indicate a pronounced enrichment of these elements in the rim of a large single rutile crystal (~8 mm) and a systematic decrease towards uniform HFSE contents in the large core. HFSE contents of smaller rutile grains (~0.5 mm) and rutile inclusions (<100 μm) in the titanite overgrowth are similar or higher than in the rims of large rutile crystals. Element profiles from the rim inward demonstrate that HFSE enrichment in rutile is controlled by diffusion. HFSE ratios in diffusion-altered rutile show systematic variations compared with the uniform core composition of the large rutile. Modelling of Zr and Nb diffusion in rutile indicates that diffusion coefficients in rutile in fluid-dominated natural systems must be considerably higher than those determined experimentally at 1 bar in dry systems. Variations of HFSE contents in the newly formed titanite show no systematic spatial distribution. HFSE ratios in titanite and the rims of rutile are different, indicating different solid/fluid distribution coefficients in these minerals. Element fractionation by diffusion into the relict rutile and during fluid-mediated growth of new titanite could substantially change the HFSE budget of these minerals and could affect their use for geochemical tracing and other applications, such as Zr-based geothermobarometry.     

Meteoritic material at four Canadian impact craters

Eleven impact melt and 6 basement rock samples from 4 craters were analyzed by neutron activation for Au, Co, Cr, Fe, Ge, Ir, Ni, Os, Pd, Re and Se. Wanapitei Lake, Ontario: the impact melts show uniform enrichments corresponding to 1–2% C1-chondrite material. Interelement ratios ($\text{Co}\text{Cr}$, $\text{Ni}\text{Cr}$, $\text{Ni}\text{Ir}$) suggest that the impacting body was a Cl-, C2-, or LL-chondrite. Nicholson Lake, North West Territory: Ni, Cr and Co are distinctly more enriched than Ir and Au which tentatively suggests an olivine-rich achondrite (nakhlite or ureilite). Gow Lake, Saskatchewan and Mistastin, Labrador: small enrichments in Ir and Ni; both the low $\text{Ir}\text{Ni}$ ratios and low Cr content suggest iron meteorites, but the signals are too weak for conclusive identification.A tentative comparison of meteoritic signatures at 10 large, ≥4km craters and their presumed celestial counterparts (13 Apollo and Amor asteroids) shows more irons and achondrites among known projectile types, and a preponderance of S-type objects, having no known meteoritic equivalent, among asteroids. It is not yet clear that these differences are significant, in view of the tentative nature of the crater identifications (achondrites in particular), and the limited statistics.     

Vacuum testing of the permeability of the excavation damaged zone

Summary The vacuum permeability method provides a new approach to assessment of permeability in the near-field of rock excavations. The method, which resembles leak testing of vacuum lines, is based on the measurement and interpretation of the pneumatic response to evacuation of a rock mass. As the induced drainage area is in order of meters, the method is particularly suitable on the scale of the excavation damaged zone. The data can be evaluated either analytically or numerically. The evaluation is similar to the approach used in the analysis of drill stem tests in gas wells. Experiments on large scale laboratory models corroborated the validity of the method and the evaluation procedure. Field tests were conducted at a wide range of geomechanical conditions. The collected data indicate that there are three characteristic types of permeability distribution in the excavation damaged zone.     

Vulnerability and risk: comparing assessment approaches

The concepts vulnerability and risk are of great importance in the fields of climate change and natural hazards. Confusion is asserted in the terminology used by the respective communities, and a large conceptual literature has not solved this problem. This affects the communication within and between the two communities and the comparison of results from vulnerability and risk assessments. This paper argues that the main difference between methods to assess vulnerability and risk in the climate and the disaster communities is not a conceptual one, but rather different terminologies are used. This point is made using a formal framework of vulnerability to climate change that makes the structure of vulnerability and risk assessments explicit. The framework distinguishes three assessment approaches in the field of vulnerability to climate change, which recur—under different labels—in the risk assessment approaches analysed. While within each community, the same terms are ambiguously used to refer to more than one assessment approach, the confusion is enhanced between the two communities by using different labels for very similar approaches. As an application of the results, similarities and differences between two assessment tools are analysed: the Dynamic Interactive Vulnerability Assessment model (DIVA) for the case of vulnerability to climate change and the CATastrophe SIMulation model (CatSim) for risk of natural hazards.     

Tectonic significance of Triassic mafic rocks in the June Complex,Sanandaj–Sirjan zone,Iran

This study concentrates on the petrological and geochemical investigation of mafic rocks embedded within the voluminous Triassic June Complex of the central Sanandaj–Sirjan zone (Iran), which are crucial to reconstruct the geodynamics of the Neotethyan passive margin. The Triassic mafic rocks are alkaline to sub-alkaline basalts, containing 43.36–49.09 wt% SiO₂, 5.19–20.61 wt% MgO and 0.66–4.59 wt% total alkalis. Based on MgO concentrations, the mafic rocks fall into two groups: cumulates (Mg# = 51.61–58.94) and isotropic basaltic liquids (Mg# = 24.54–42.66). In all samples, the chondrite-normalized REE patterns show enrichment of light REEs with variable (La/Yb)_N ratios ranging from 2.48 to 9.00, which confirm their amalgamated OIB-like and E-MORB-like signatures. Enrichment in large-ion lithophile elements and depletion in high field strength elements (HFSE) relative to the primitive mantle further support this interpretation. No samples point to crustal contamination, all having undergone fractionation of olivine + clinopyroxene + plagioclase. Nevertheless, elemental data suggest that the substantial variations in (La/Sm)_PM and Zr/Nb ratios can be explained by variable degrees of partial melting rather than fractional crystallization from a common parental magma. The high (Nb/Yb)_PM ratio in the alkaline mafic rocks points to the mixing of magmas from enriched and depleted mantle sources. Abundant OIB alkaline basalts and rare E-MORB appear to be linked to the drifting stage on the northern passive margin of the Neotethys Ocean.     

Anomalous phosphorus episodes during Callovian-Oxfordian times in the Kachchh Basin,western India: Implications for palaeoclimate,productivity, and weathering

The Upper Callovian-Oxfordian strata of the Kachchh Basin, western India, record three positive excursions of phosphorus. They have been documented in three sections of the Chari Formation from different parts of the basin. Corroboration of field and petrographic data with trends of major and trace elemental data and elemental ratios of the strata revealed that these excursions were coeval with reduced chemical weathering in the source area and significant reduction of siliciclastic influx to the depositional sites. The study also revealed the intrabasinal source of P, and minor sea-level fluctuations and resultant episodic sediment recycling as the causative factors. Considering the geographic locations of the three sections, the phosphorus anomalies seem to be controlled by a regional and/or basin-scale process, if not linked with global signals. Temporal resolution of these anomalies suggests that the processes were episodic and related to short term climate/relative sea-level cycles, the durations of which could be unraveled with high-resolution biostratigraphic data.     

Spurious Clusters in Granulometric Data Caused by Logratio Transformation

The logratio transformation aims to eliminate spurious correlations between components of compositional data. When applying this method to granulometric data, there arise numerical problems with zero (empty) components. In this paper, the method of logratio transformation with zero replacement is examined using one natural and two simulated granulometric data sets. The results show that this method generates spurious clusters, and thus it is not appropriate for the investigation of grain-size data in particular, and of compositional data with zero components in general.