Annual trace element cycles in calcite–aragonite speleothems: evidence of drought in the western Mediterranean 1200–1100 yr BP

Each of two calcitic stalagmites from Grotte de Clamouse, Herault, southern France, displays a discrete aragonite layer dated at around 1100 yr BP. The layer of fanning aragonite ray crystals is immediately preceded by calcite with Mg and Sr compositions that are uniquely high for the past 3 kyr. Trace element compositions close to the boundary between original aragonite and calcite are consistent with quasi‐equilibrium partitioning of trace elements between the phases. Study of modern dripwaters demonstrates that pronounced covariation of Mg/Ca and Sr/Ca ratios in dripwater occurs owing to large amounts of calcite precipitation upflow of the drips that fed the stalagmites. Trace element to Ca ratios are enhanced during seasonally dry periods. Ion microprobe data demonstrate a pronounced covariation of trace elements, including Mg and Sr in calcite, and Sr, U and Ba in aragonite. The mean peak spacing is close to the long‐term mean of annual growth rates determined by differences in U‐series ages and so the trace element peaks are interpreted as annual. The trace element chemistry of the stalagmites on annual to inter‐annual scales thus directly reflects the amounts of prior calcite precipitation, interpreted as an index of aridity. The longer‐term context is a multi‐decadal period of aridity (1200–1100 yr BP) possibly correlated with an analogous episode in Central America. The arid period culminated in the nucleation of aragonite, but within a decade was followed by a return to precursor conditions. Copyright © 2005 John Wiley & Sons, Ltd.     

Convective flux in the solar photosphere as determined from fluctuations

The fractional convective flux πF _c (x _c /πF) is computed for the effective level x _c = logτ _c = 0.125, using bi-dimensional co-spectra for relative continuum-brightness fluctuations ΔI and radial velocity fluctuations ΔV measured for the C _i 5052.16 spectral line. A more uncertain flux for x _Fe ≈ - 0.9 is obtained for the Fe _i 5049.83 line. Since the results (Figure 1) incorporate current uncertainties in RMS _ΔI , RMS _ΔV and RMS _ΔT (x), where ΔT are photospheric temperature fluctuations, they must be considered qualitative until these uncertainties are appreciably reduced. The requirement that the fractional convective flux < 1, places restrictions on these uncertainties which suggest that current RMS _ΔT (x)'s are too large. The results confirm the importance of overshoot at the top of the solar hydrogen convection zone and suggest a non-negligible fractional convective flux throughout the lower photosphere. Qualitatively, they do not agree with the predictions of the generally-used, local, mixing-length theory or those of Parsons' (1969) modified mixing-length theory. However, qualitative agreement with the predictions of the non-local, generalized mixing-length theory of Spiegel (1963) and with the non-local theory of Ulrich (1970) cannot be considered as observational confirmation of these theories.     

Electron plasma oscillations associated with type III radio emissions and solar electrons

An extensive study of the IMP-6 and IMP-8 plasma and radio wave data has been performed to try to find electron plasma oscillations associated with type III radio noise bursts and low-energy solar electrons. This study shows that electron plasma oscillations are seldom observed in association with solar electron events and type III radio bursts at 1.0 AU. In nearly four years of observations only one event was found in which electron plasma oscillations are clearly associated with solar electrons. For this event the plasma oscillations appeared coincident with the development of a secondary maximum in the electron velocity distribution functions due to solar electrons streaming outwards from the Sun. Numerous cases were found in which no electron plasma oscillations with field strengths greater than 1 μV m^?1 could be detected even though electrons from the solar flare were clearly detected at the spacecraft. For the one case in which electron plasma oscillations are definitely produced by the electrons ejected by the solar flare the electric field strength is relatively small, only about 100 μV m^?1. This field strength is about a factor of ten smaller than the amplitude of electron plasma oscillations generated by electrons streaming into the solar wind from the bow shock. Electromagnetic radiation, believed to be similar to the type III radio emission, is also observed coming from the region of the more intense electron plasma oscillations upstream of the bow shock. Quantitative calculations of the rate of conversion of the plasma oscillation energy to electromagnetic radiation are presented for plasma oscillations excited by both solar electrons and electrons from the bow shock. These calculations show that neither the type III radio emissions nor the radiation from upstream of the bow shock can be adequately explained by a current theory for the coupling of electron plasma oscillations to electromagnetic radiation. Possible ways of resolving these difficulties are discussed.     

Particulate protein measurement in oceanographic samples by dye binding

A modified version of the Coomassie Brilliant Blue dye binding protein assay has been developed for oceanographic samples and intercalibrated with the widely used Lowry assay. Particulate protein measurements were made at seven stations in the Gulf of Maine using the method. Measurements were made on cell-free homogenates. Protein concentration ranged from 2 to 212 μg l^?1 (0.02–0.68 μg at N l^?1) and averaged 58 μg l^?1. ETS activity, chlorophyll and particulate nitrogen were significantly correlated with protein concentrations.     

Literal solution for Hill's lunar problem

A computer program for the manipulation of power series in several variables is used to find the first order solution to Hill's lunar problem. The ratiom of the mean motion of the Sun to that of the Moon is kept as a formal parameter. The series inm are known to converge very poorly. It is shown how efficient algorithms among them the Lie transformation allow us to compute the series inm as far as they are needed. When the series are evaluated at Brown's numerical value form the results achieve or exceed his accuracy.     

Mercos — A simple Teflon sampler for ultratrace metal analysis in seawater

This paper describes an uncomplicated sampling technique for ultratrace element analysis of coastal and surface seawaters (maximum depth 100 m). The sampler system is very easy to operate. To prevent contamination problems, interchangeable 500-ml Teflon bottles are used as both sampling and storage vessels. The seawater samples are stabilized in situ by preacidifying the sampling bottles. For the determination of mercury in seawater the desired system has been developed: sampling bottle = storage bottle = reaction vessel.     

The stability of the Lagrangian point L4

The Hamiltonian function of the restricted problem of three bodies near the triangular Lagrangian point is normalized through sixth order terms with the help of MACSYMA. The same calculations were done previously with an algebraic processor in order to establish the stability at a critical value of the mass ratio.     

THE KRAMER CREEK,COLORADO METEORITE: A NEW L4 CHONDRITE

The Kramer Creek, Colorado, chondrite was found in 1966 and identified as a meteorite in 1972. Bulk chemical analysis, particularly the total iron content (20.36%) and the ratio of Fe_total/SiO₂ (0.52), as well as the compositions of olivine (Fa_21.7) and orthopyroxene (Fs_18.3) place the meteorite into the L-group of chondrites. The well-defined chondritic texture of the meteorite, the presence of igneous glass in the chondrules and of low-Ca clinopyroxene, as well as the slight variations in FeO contents of olivine (2.4% MD) and orthopyroxene (5.6% MD) indicate that the chondrite belongs to the type 4 petrologic class.     

Rms-value and power spectrum of the photospheric intensity-fluctuations

The power spectrum and the rms-value of the granular intensity fluctuations were studied using granulation photographs of excellent quality obtained during the JOSO site testing campaign 1979 at Izaña. The observed power spectrum was corrected using various effective modulation transfer functions of the system: telescope+aberrations+atmospheric seeing, assuming different contributions of the atmospheric seeing. With this procedure a lower and upper limit for the ‘true’ power spectrum of the granular intensity fluctuations and thus for the rms-value could be derived: 7.2% <I _rms <12% at λ = 550 nm, with a most probable value of I _rms = 10.5%. We checked the validity of the upper limit by applying to our data a MTF (Deubner and Mattig, 1975), which certainly must lead to an overcorrection. This procedure lead to I _rms = 13.4%. Thus we can state that the true rms-value of the granular intensity fluctuations does certainly not exceed 13% at λ = 550 nm.     

Application of the integral variation method to satellite orbit prediction

The Integral Variation (IV) method is a technique to generate an approximate solution to initial value problems involving systems of first-order ordinary differential equations. The technique makes use of generalized Fourier expansions in terms of shifted orthogonal polynomials. The IV method is briefly described and then applied to the problem of near Earth satellite orbit prediction. In particular, we will solve the Lagrange planetary equations including the first three zonal harmonics and drag. This is a highly nonlinear system of six coupled first-order differential equations. Comparison with direct numerical integration shows that the IV method indeed provides accurate analytical approximations to the orbit prediction problem.Advanced Systems Studies; Bldg. 254EElectro-Optical Systems Laboratory; Bldg. 201.