The agricultural utility of lithic-mulch gardens: Past and present

The mulching of agricultural fields and gardens with stones, pebbles, volcanic ash and similar lithic materials is a variant agricultural strategy uniquely suited to the constraints of a dryland environment. While the agricultural literature contains reports on limited experiments with stone or gravel mulch, data regarding the employment of lithic mulch are lacking. This paper works to bridge this gap by comparing empirical data collected from prehistoric pebble-mulch gardens in the Galisteo Basin (New Mexico) to contemporary agricultural experiments with lithic mulch. Such past-present and experimental-real world comparisons allow us to more fully address the effectiveness of lithic mulching as an agricultural strategy. It is affirmed that lithic mulch is applied to garden plots, especially during periods of drought, in order to reduce soil erosion from wind and water, increase soil temperature to extend the growing season, increase water infiltration, and reduce the evaporative loss of water from wind and sun. The cumulative effect of this soil and water conserving technique is an increase in crop biomass and crop yield.     

An intercomparison of seawater filtration procedures

Filtration systems, used for the preparation of coastal seawater samples for trace analysis, have been intercompared to determine the extent of contamination arising during the filtration process. The results show that all the systems intercompared are able to provide uncontaminated filtrates for copper, nickel, cobalt and manganese and, with two exceptions, for cadmium and iron, at levels that would be encountered in uncontaminated coastal waters.     

The effect of ionic interactions on the oxidation of metals in natural waters

The effect of ionic interactions of the major components of natural waters on the oxidation of Cu(I) and Fe(II) has been examined. The various ion pairs of these metals have been shown to have different rates of oxidation. For Fe(II), the chloride and sulfate ion pairs are not easily oxidized. The measured decrease in the rate constant at a fixed pH in chloride and sulfate solutions agrees very well with the values predicted. The effect of pH (6 to 8) on the oxidation of Fe(II) in water and seawater have been shown to follow the rate equation

$\text{-d in [Fe(II)]/dt = k}{}_1\text{β}{}_1\text{α}{}_{\mathrm{Fe}}\text{/[H}{}^{\mathrm{+}}\text{] + k}{}_2\text{β}{}_2\text{α}{}_{\mathrm{Fe}}\text{/[H}{}^{\mathrm{+}}\text{]}{}^2$

where k₁ and k₂ are the pseudo first order rate constants, β₁ and β₂ are the hydrolysis constants for Fe(OH)⁺ and Fe(OH)⁰. The value of α_FE is the fraction of free Fe²⁺. The value of k₁ (2.0 ±0.5 min^?1) in water and seawater are similar within experimental error. The value of k₂ (1.2 × 10⁵ min^?1) in seawater is 28% of its value in water in reasonable agreement with predictions using an ion pairing model.For the oxidation of Cu(I) a rate equation of the form

$\text{?d ln [Cu(I)]/dt = k}{}_0\text{α}{}_{\mathrm{Cu}}\text{+ k}{}_1\text{β}{}_1\text{α}{}_{\mathrm{Cu}}\text{[Cl]}$

was found where k₀ (14.1 sec^?1) and k₁ (3.9 sec^?1) are the pseudo first order rate constants for the oxidation of Cu⁺ and CuCl⁰, β₁ is the formation constant for CuCl⁰ and α_Cu is the fraction of free Cu⁺. Thus, unlike the results for Fe(II), Cu(I) chloride complexes have measurable rates of oxidation.     

Particulate pollution monitoring in the Elefsis Gulf: The role of mineral magnetic studies

Measurements of ‘quadrature’ susceptibility (X_q) at low and high frequency on seabottom sediments of the Gulf of Elefsis supplement the results derived from the study of magnetic susceptibility (X) and saturation isothermal remanent magnetization (SIRM) (Scoullos et al., 1979) and make possible the distinction between the background soil erosional fraction and that of anthropogenic combustion origin. New devices speed up the on-site appraisal of the impact of discharges on marine sediment quality.     

Thermal histories of the core and mantle

Recognition that the cooling of the core is accomplished by conduction of heat into a thermal boundary layer (D″) at the base of the mantle, partly decouples calculations of the thermal histories of the core and mantle. Both are controlled by the temperature-dependent rheology of the mantle, but in different ways. Thermal parameters of the Earth are more tightly constrained than hitherto by demanding that they satisfy both core and mantle histories. We require evolution from an early state, in which the temperatures of the top of the core and the base of the mantle were both very close to the mantle solidus, to the present state in which a temperature increment, estimated to be ～ 800 K, has developed across D″. The thermal history is not very dependent upon the assumption of Newtonian or non-Newtonian mantle rheology. The thermal boundary layer at the base of the mantle (i.e., D″) developed within the first few hundred million years and the temperature increment across it is still increasing slowly. In our preferred model the present temperature at the top of the core is 3800 K and the mantle temperature, extrapolated to the core boundary without the thermal boundary layer, is 3000 K. The mantle solidus is 3860 K. These temperatures could be varied within quite wide limits without seriously affecting our conclusions. Core gravitational energy release is found to have been remarkably constant at ～ 3 × 10¹¹ W. nearly 20% of the core heat flux, for the past 3 × 10⁹ y, although the total terrestrial heat flux has decreased by a factor of 2 or 3 in that time. This gravitational energy can power the “chemical” dynamo in spite of a core heat flux that is less than that required by conduction down an adiabatic gradient in the outer core; part of the gravitational energy is used to redistribute the excess heat back into the core, leaving 1.8 × 10¹¹ W to drive the dynamo. At no time was the dynamo thermally driven and the present radioactive heating in the core is negligibly small. The dynamo can persist indefinitely into the future; available power 10¹⁰ y from now is estimated to be 0.3 × 10¹¹ W if linear mantle rheology is assumed or more if mantle rheology is non-linear. The assumption that the gravitational constant decreases with time imposes an implausible rate of decrease in dynamo energy. With conventional thermodynamics it also requires radiogenic heating of the mantle considerably in excess of the likely content of radioactive elements.     

Trace gas measurements during aircraft flights in the tropopause region over Europe and North Africa

During aircraft flights in May 1981 from Munich (40°N) to north of the Spitsbergen Islands (82°N) and to Monrovia, Liberia (6°N), air samples were obtained in the altitude range of 8 to 11 km and during the ascents and descents near the airports. These samples have been analyzed for the trace gas mixing ratios of CH₄, CO and N₂O. The results of these analyses are presented and discussed.The results provide new evidence of tropospheric-stratospheric exchange events in the vicinity of the subpolar and subtropical tropopause foldings and possibly show a case of transport of CO-enriched air in the upper troposphere above the North Atlantic Ocean.     

Use of Pitzer's equations to determine the media effect on the formation of lead chloro complexes

The spectrophotometric measurements of chloro complexes of lead in aqueous HCl, NaCl, MgCl₂ and CaCl₂ solutions at 25°C have been analyzed using Pitzer's specific interaction equations. Parameters for activity coefficients of the complexes PbCl⁺, PbCl₂⁰ and PbCl₃^? have been determined for the various media. Values of $\text{K}{}_1\text{= 30.0 ± 0.6}$, $\text{K}{}_2\text{= 106.7 ± 2.1}$ and $\text{K}{}_3\text{= 73.0 ± 1.5}$ were obtained for the cumulative formation constants. [$\text{Pb}{}^{\mathrm{2+}}\text{+ nCl}{}^{\mathrm{?}}\text{→ PbCl}{}_{\mathrm{n}}{}^{\mathrm{2?n}}\text{)}$]. These values are in reasonable agreement with literature data. The Pitzer parameters for the PbCl ion pairs in various media were used to calculate the speciation of Pb²⁺ in an artificial seawater solution.     

The southern agglomeration zone of the GDR — Regional structure and development

Agglomeration areas in the GDR are those regions, which are characterized by an above average level of regional concentration of productive forces and their conditions of reproduction. The economic potential concentrated in these regions represents a large part of the national economy. It is possible to describe the territorial structure of these agglomeration areas by general indices (agglomeration core — agglomeration field — agglometation fringe; polycentric node-band-structure), but also the individual features of each one of these regions are to be attended. They are expressed for the first time by several forms of localization of plants and by the structure of settlements and settlement networks. The present main tendencies in the development of the agglomeration regions are:

They succeeded in minimizing the regional disparities of productivity between different agglomeration regions and within them, and in stabilizing the economic position of these regions by systematic measures for investment and rationalization and the hereby influenced structural changes.

At present and up to 1990 the completion of housing programme is of foremost importance by which the main activities will shift from the urban fringe to the centres of the cities; provincial towns and smaller settlements will also participate in this programme.

The main target of these activities is to remove imperfect structures and other burning problems of the agglomeration regions step by step. Geographical Institutes are dealing with the management of these tasks too.     

Possible influences of solar radiation variations on the atmospheric circulation in the northern hemisphere of the earth

The strength of the circumpolar zonal circulation of the atmosphere in the northern hemisphere, expressed by an index calculated from the air pressure gradient between 35° N and 65°N, shows a remarkable secular change in this century in the years 1935 to 1938, and probably again in the years after 1970. A contemporary change and parallel course with a high positive correlation can be found in a solar radiation index calculated by means of sunspot numbers and solar faculae areas. A good correlation was also found between this solar radiation index and a series of UV measurements on Mt. Wilson. The possible mechanism of action in the atmosphere will be discussed, and it is shown that this solar radiation index is also correlated with circulation parameters in the troposphere and stratosphere over Europe. There are indications of a decrease of the action from the upper to the lower atmosphere. The consequences of this secular change of circulation for the climatic history in the 20th century in Europe are presented and from that a hypothetical retrospective view of the European climatic history before the 20th century, based on the total series of sunspot numbers, is briefly discussed. In a general view with smoothed data it can be concluded that the sun seems to determine the basic structure of the north hemispheric circulation in middle latitudes, if a strong influence of sunspots and solar faculae on the solar radiation is assumed.     

Transport rate of drifting snow and the mean wind speed profile

Transport rates, measured by weighing snow blown into a filter fabric trap, were greater over hard snow or ice than for the same wind speed over soft, fresh snow surfaces. Analysis of wind speed profiles from nine blizzards showed that friction between moving particles and the surface was less, and particle speeds were greater over hard surfaces. Transport rates at a given wind speed increased rapidly as aerodynamic roughness decreased in the rough-smooth transition region. Bagnold's theory for bed load transport provided a useful framework for the analysis.