Second order elasticity theory: An improved formulation of the Grüneisen parameter at high pressure

The second order theory of elasticity, in which terms to second order in strain are retained in calculating atomic bond length changes and elastic moduli, is extended to describe thermal vibration of a face-centred cubic crystal. Coupled with equations relating the pressure dependences of elastic constants, this yields a new formulation of the thermal Grüneisen parameter γ in terms of pressure P, incompressibility K and rigidity, μ

$\text{λ}\text{1}\text{2}\text{d}\text{K}\text{d}\text{P}\text{?}\text{1}\text{2}\text{+}\text{1}\text{9}\text{P}\text{K}\text{?}\text{1}\text{3}\text{?}\text{1}\text{9}\text{P}\text{K}\text{f}\text{1?}\text{2}\text{3}\text{P}\text{K}\text{?}\text{2}\text{3}\text{P}\text{K}\text{f}$

where f = 24 (3 K ? 2 P)/(3 K + 115 μ + 90 P). The factor f arises from bond interactions and the case f = 1, representing independent bonds (no interactions), yields the free-volume γ- Since we have shown earlier that the second order elasticity theory provides a convincing explanation of the elasticity of the inner core, we believe that the new formula is appropriate for the inner core. It is, however, inadequate to describe the lower mantle γ, in which atomic bond angle rigidity, not considered here, may be appreciable.     

Heavy metal inflow into the floodplains at the mouth of the river Weiße Elster (Central Germany)

From 1998 to 2002 investigations were carried out to estimate both the quantity and quality (heavy metal contents) of suspended matter loads discharged into a floodplain area measuring approx. 5 km² of the Central German river Weiße Elster, a tributary of the river Saale in the Elbe river basin. Flood sediments, suspended particulate matter, and floodplain soils were investigated especially for the main pollutants Cd, Zn, Cu, Pb, Cr, and Hg. Supplementary gamma spectroscopy examinations were performed to help to identify the age of deposits in order to estimate sedimentation rates for last decades. The recent flood sediments are contaminated by up to 33 times the geogenic background (Cd). Up to 55% of the total annual SPM load of the river Weiße Elster is relocated into the investigated retention area in the flood‐stricken year 2002. The sedimentation rates for the last 50 years vary between 0.5 mm/a and 1 mm/a in far away and rarely flooded parts and between 1 mm/a and 2 mm/a in the frequently flooded parts of the inflow of the retention area.     

Changes in tidal asymmetry in the German Wadden Sea

Ocean Dynamics - The recent morphological development of the German Wadden Sea (North Sea, Europe) has been characterized by expanding intertidal flats and deepening, narrowing tidal channels at...     

Dating of Late Pleistocene terrace deposits of the River Rhine using Uranium series and luminescence methods: Potential and limitations

Uranium-series dating of pedogenic carbonate crusts from fluvial gravels is tested using Optically Stimulated Luminescence (OSL) ages as references. OSL dating yielded ages of 30–15 ka and 13–11 ka, which correlate with the cold periods of the Last Glacial Maximum and the Younger Dryas. These ages are internally coherent and consistent with the geological background and are thus regarded as reliable. Most of the U/Th results scatter widely in the ²³⁰Th/²³²Th vs. ²³⁴U/²³²Th isochron diagram, making regression unrealistic. Semiquantitative age estimates from the data were found to be mostly older than the OSL ages and the geological context. It is suggested that a heterogeneous initial ²³⁰Th input, not relatable to a detrital component, is responsible for the observed discrepancies. This input may be due to bacterial activities and Th transport on organic colloids. It appears necessary to avoid samples where bacteria could have contributed to carbonate precipitation. Further, the relative importance of this problem decreases with sample age, so that U/Th dating of sinters is expected to be more reliable in the >100 ka age range.     

Stress Changes Modelled for the Sequence of Strong Earthquakes in the South Iceland Seismic Zone Since 1706

The South Iceland seismic zone is, roughly speaking, situated between two sections of the mid-Atlantic ridge, i.e., the Reykjanes Ridge southwest of Iceland and the Eastern Volcanic Zone on the island. It is a transform zone, where earthquakes are expected to occur on E-W-trending left-lateral shear faults, equivalent to conjugate, N-S-oriented right-lateral, rupture planes. In fact, earthquakes take place on en-échelon N-S-oriented faults, which is indicated by the distribution of main shock intensities, aftershocks as well as by surface fault traces. The stress field continuously generated in the fault zone by opening of the adjacent ridges is computed and superimposed on the stress field changes induced by a series of 13 earthquakes (M 6) between 1706 and 2000. The level of the pre-seismic stress field is analysed as well as the size of the area under high stress. Finally, the post-seismic stress field of June 2000 is analysed, to see where high stresses might have accumulated. The modelling indicates that the rupture planes located on separated parallel N-S-striking zones are dense enough to lead to an area-wide stress release by the series of events. The obtained pre-seismic stress level for most events is high and stable with the exception of situations when several strong shocks occur over a time span of several days, i.e., display typical main shock-aftershock patterns. The size of areas under high stress aside from of the rupture plane, i.e., where no event occurs at the specific time, is of medium to small size.     

Demarcation and Scaling of Long-term Seismogenesis

A space-time envelope of minor seismicity related to major shallow earthquakes is identified from observations of the long-term Precursory Scale Increase () phenomenon, which quantifies the three-stage faulting model of seismogenesis. The envelope, which includes the source area of the major earthquake, is here demarcated for 47 earthquakes from four regions, with tectonic regimes ranging from subduction to continental collision and continental transform. The earthquakes range in magnitude from 5.8 to 8.2, and include the 24 most recent mainshocks of magnitude 6.4 and larger in the San Andreas system of California, the Hellenic Arc region of Greece, and the New Zealand region, together with the six most recent mainshocks of magnitude 7.4 and larger in the Pacific Arc region of Japan. Also included are the destructive earthquakes that occurred at Kobe, Japan (1995, magnitude 7.2), Izmit, Turkey (1999, magnitude 7.4), and W.Tottori, Japan (2000, magnitude 7.3). The space (A _P ) in the space-time envelope is optimised with respect to the scale increase, while the time (T _P ) is the interval between the onset of the scale increase and the occurrence of the earthquake. A strong correlation is found between the envelope A _P T _P and the magnitude of the earthquake; hence the conclusion that the set of precursory earthquakes contained in the envelope is intrinsic to the seismogenic process. Yet A _P and T _P are correlated only weakly with each other, suggesting that A _P is affected by differences in statical conditions, such as geological structure and lithology, and T _P by differences in dynamical conditions, such as plate velocity. Among other scaling relations, predictive regressions are found between, on the one hand, the magnitude level of the precursory seismicity, and on the other hand, both T _P and the major earthquake magnitude. Hence the method, as here applied to retrospective analysis, is potentially adaptable to long-range forecasting of the place, time and magnitude of major earthquakes.     

MTBE in Drinking Water Production – Occurrence and Efficiency of Treatment Technologies

In Germany, the gasoline additive methyl tert‐butyl ether (MTBE) is almost constantly detected in measurable concentrations in surface waters and is not significantly removed during riverbank filtration. The removal of MTBE from water has been the focus of many studies that mostly were performed at high concentration levels and centred in understanding the mechanisms of elimination. In order to assess the performance of conventional and advanced water treatment technologies for MTBE removal in the low concentration range further studies were undertaken. Laboratory experiments included aeration, granulated activated carbon (GAC) adsorption, ozonation and advanced oxidation processes (AOP). The results show that the removal of MTBE by conventional technologies is not easily achieved. MTBE is only removed by aeration at high expense. Ozonation at neutral pH values did not prove to be effective in eliminating MTBE at all. The use of ozone/H₂O₂ (AOP) may lead to a partly elimination of MTBE. However, the ozone/H₂O₂ concentrations required for a complete removal of MTBE from natural waters is much higher than the ozone levels applied nowadays in waterworks. MTBE is only poorly adsorbed on activated carbon, thus GAC filtration is not efficient in eliminating MTBE. A comparison with real‐life data from German waterworks reveals that if MTBE is detected in the raw water it is most often found in the corresponding drinking water as well due to the poor removal efficiency of conventional treatment steps.     

全球贸易自由化对中国和世界经济的影响

全球贸易自由化是当前和未来世界经济发展不可避免的趋势,2001年开始的多哈回合贸易自由化多边谈判和最近刚刚取消的“多种纤维协定”（MFA）将在全球贸易自由化进程中发挥重要的作用。本研究的目的是通过一些案例分析,揭示贸易自由化对中国和世界经济的影响。采用全球贸易模型,我们分析了MFA和在多哈回合初期欧盟、美国和凯恩斯集团分别提出的贸易自由化提案。研究结果表明,虽然取消MFA对一些国家纺织部门带来冲击,但它极大地促进了大多数国家经济的发展,改善了全球福利;多哈谈判过程中提出的各种贸易自由化提案都在不同程度上促进世界经济的发展,但其影响大小依次为凯恩斯提案、美国提案和欧盟提案;贸易自由化对经济的影响在不同部门和不同国家间存在显著差别;更大程度的贸易自由化不但符合全球共同利益,也符合中国国家利益;中国在推动全球贸易自由化过程中应发挥更积极和更大的作用。     

Biomediation of calcrete at the gold anomaly of the Barns prospect,Gawler Craton,South Australia

Anomalously high Au concentrations (2.5 to 50 ppb) in regolith carbonate accumulations, such as calcrete and calcareous sands in aeolian sand dunes overlying Au mineralisation of the Gawler Craton, South Australia, show a marked covariance of Au with K, Mg and most notably Ca. This relationship appears to be linked to the authigenic formation of smectites and carbonates within the aeolian dunes in the region. However, little is known about the processes involved in the formation of carbonates under semi-arid and arid conditions. In this study the geochemical properties of aeolian dunes along several depth profiles of 2 to 4 m are investigated in order to assess the relationship between Au mobility and calcrete formation. In the profiles a strongly systematic relationship between Au and the increasing Ca–Mg contents at depth highlights the close association between the enrichment of Au in the calcrete and the underlying hydrothermal mineralisation. Intense calcrete formation and concurrent Au enrichment also occurs in the vicinity of roots penetrating the dune. Thin section petrography and cathodoluminescence show that most of the calcrete in the regolith profiles is micritic; some sparic crystallites have also been identified. To demonstrate the presence of microbial processes that may mediate the formation of calcrete, samples from a depth profile in the dune were taken under sterile conditions. After amendment with urea and incubation of up to 24 h, up to 18 mg/l of NH₄⁺ were detected in near surface samples. At depth of 2.3 m 1 mg/l NH₄⁺ were detected compared to a control that contained below 0.05 mg/l NH₄⁺. These results suggest that the genesis of calcrete and pedogenic carbonate in the area may be partly biologically mediated via processes such as the metabolic breakdown of urea by resident microbiota which generates a pH and pCO₂ environment conducive to the precipitation of carbonate. In the process of urea breakdown organic Au complexes such as Au-amino acid complexes may become destabilised in solution and Au may be co-precipitated, resulting in the fine, non-particulate distribution of Au throughout the micritic calcrete carbonate. In conclusion, this study suggests a coupled mechanism of biologically mediated and inorganic mechanisms that lead to the formation of Au-in-calcrete anomalies.     

Oxidation of pyrite during extraction of carbonate associated sulfate

The sulfur isotopic composition of carbonate associated sulfate (CAS) has been used to investigate the geochemistry of ancient seawater sulfate. However, few studies have quantified the reliability of δ³⁴S of CAS as a seawater sulfate proxy, especially with respect to later diagenetic overprinting. Pyrite, which typically has depleted δ³⁴S values due to authigenic fractionation associated with bacterial sulfate reduction, is a common constituent of marine sedimentary rocks. The oxidation of pyrite, whether during diagenesis or sample preparation, could thus adversely influence the sulfur isotopic composition of CAS. Here, we report the results of CAS extractions using HCl and acetic acid with samples spiked with varying amounts of pyrite. The results show a very strong linear relationship between the abundance of fine-grained pyrite added to the sample and the resultant abundance and δ³⁴S value of CAS. This data represents the first unequivocal evidence that pyrite is oxidized during the CAS extraction process. Our mixing models indicate that in samples with much less than 1 wt.% pyrite and relatively high δ³⁴S_pyrite values, the isotopic offset imparted by oxidation of pyrite should be much less than ? 4‰. A wealth of literature exists on the oxidation of pyrite by Fe³⁺ and we believe this mechanism drives the oxidation of pyrite during CAS extraction, during which the oxygen used to form sulfate is taken from H₂O, not O₂. Consequently, extracting CAS under anaerobic conditions would only slow, but not halt, the oxidation of pyrite. Future studies of CAS should attempt to quantify pyrite abundance and isotopic composition.