NIR spectral trends of HED meteorites: Can we discriminate between the magmatic evolution, mechanical mixing and observation geometry effects?

The Howardite–Eucrite–Diogenite (HED) suite is a family of differentiated meteorites that provide a unique opportunity to study the differentiation of small bodies. The likely parent-body of this meteorite group, (4) Vesta is presently under study by the Dawn mission, scrutinizing its surface in the visible and NIR infrared range. Here, we discuss how well the magmatic trends observed in HED might be retrieved from NIR spectroscopy, by studying laboratory spectra of 10 HED meteorites together with spectra from the RELAB database. We show that although an exsolution process did occur for most eucrites (i.e. decomposition of a primary calcic pyroxene into a high-Ca and low-Ca pyroxene), it does not affect the “bulk pyroxene” trend retrieved from the location of the pyroxene crystal field bands (Band I with a maximum of absorption around at about 1 μm and Band II around 2 μm). Absolute values of the chemical composition appears however to deviate from the expected chemical composition. We show that mechanical mixture (i.e. impact gardening) will produce a linear mixing in the pyroxenes band position diagram (Band I position vs Band II position). This diagram also reveals that howardite are not pure mixtures of an average eucrite and average diogenite. Because asteroid surfaces are expected to show topography, we also study the effect of observation geometry on the NIR spectra of an eucrite and a diogenite by measuring the bi-directional reflectance spectra from 0.4 to 4.6 μm. Results show that these meteorites tend to act as forward scatterers, leading to a decrease of integrated band area (relative to the continuum) at high phase angles. The position of the two strong crystal field bands shows only small variability with observation geometry. Retrieval of the magmatic trends from the Band I vs Band II diagram should not be affected by observation geometry effects. Finally we performed NIR reflectance measurement on olivine diogenites. The presence of olivine can be suggested by using the Band Area Ratio vs Band I diagram, but this phase might affect the retrieval of pyroxene composition from the position of Band I and Band II.     

Late Quaternary sediment dating and quantification of lateral sediment redistribution applying230Thex: a study from the eastern Atlantic sector of the Southern Ocean

High-resolution records of the natural radionuclide²³⁰Th were measured in sediments from the eastern Atlantic sector of the Antarctic circumpolar current to obtain a detailed reconstruction of the sedimentation history of this key area for global climate change during the late Quaternary. High-resolution dating rests on the assumption that the²³⁰Th_ex flux to the sediments is constant. Short periods of drastically increased sediment accumulation rates (up to a factor of 8) were determined in the sediments of the Antarctic zone during the climate optima at the beginning of the Holocene and the isotope stage 5e. By comparing expected and measured accumulation rate of²³⁰Th_ex, lateral sediment redistribution was quantified and vertical particle rain rates originating from the surface water above were calculated. We show that lateral contributions locally were up to 6.5 times higher than the vertical particle rain rates. At other locations only 15% of the expected vertical particle rain rate were deposited.     

Monsoon triggered formation of Quaternary alluvial megafans in the interior of Oman

A vast bajada consisting of coalescing low-gradient (< 0.3°) alluvial fans exceeding 100 km in length formed along the southwestern margin of the Oman Mountains. It comprises an old fan sequence of inferred Miocene to Pliocene age termed Barzaman Formation, diagenetically highly altered to dolomitic clays, and a thin veneer of weakly cemented Quaternary gravels. A combination of remote sensing, lithological analyses and luminescence dating is used to interpret the complex aggradation history of the Quaternary alluvial fans from the interior of Oman in the context of independent regional climate records. From satellite imagery and clast analysis four fans can be discerned in the study area. While two early periods of fan formation are tentatively correlated to the Miocene–Pliocene and the Early Pleistocene, luminescence dating allows the distinction of five phases of fan aggradation during the Middle–Late Pleistocene. These phases are correlated with pluvial periods from Marine Isotope Stage (MIS) 11 through 3, when southern Arabia was affected by monsoonal precipitation. It is concluded that the aggradation of the alluvial fans was triggered by the interplay of increased sediment production during arid periods and high rainfall with enhanced erosion of hillslopes and transport rates during strong monsoon phases. However, the lack of fine-grained sediments, bioturbation and organic material implies that although the Quaternary fans are sourced by monsoonal rains they formed in a semi-arid environment. Thus, it appears that, in contrast to the Oman Mountains, the interior was not directly affected by monsoonal precipitation.     

The thermodynamics and kinetics of the hydrogen sulfide system in natural waters

The thermodynamics and kinetics of the H₂S system in natural waters have been critically reviewed. Equations have been derived for the solubility and ionization of H₂S in water and seawater as a function of salinity, temperature and pressure. Pitzer parameters for the interaction of the major cations (Na⁺, Mg²⁺ and Ca²⁺) with HS⁻ have been determined to allow one to calculate values of pK₁^* in various ionic media. The limited data available for the interaction of trace metals for HS⁻ are summarized and future work is suggested.The kinetics of oxidation of H₂S have also been examined as a function of pH, temperature, and salinity. The discrepancies in the available data are largely due to the different [O₂]/[HS−] ratios used in various studies. Over a limited pH range (6–8) the pseudo first order rate constant for the oxidation is shown to be directly proportional to the activity of HS⁻. Further studies are suggested to examine the effect of ionic media and temperature on the rate of oxidation.     

The two-point correlation of galaxy groups: probing the clustering of dark matter haloes

We analyse the two-point correlation function (2PCF) of galaxy groups identified from the 2-degree Field Galaxy Redshift Survey with the halo-based group finder recently developed by Yang et al. With this group catalogue we are able to estimate the 2PCFs for systems ranging from isolated galaxies to rich clusters of galaxies. The real-space correlation length obtained for these systems ranges from ∼4 to ∼15  h ⁻¹ Mpc, respectively. The observed correlation amplitude (and the corresponding bias factor) as a function of group abundance is well reproduced by associating galaxy groups with dark matter haloes in the standard Λ-cold dark matter model. Redshift distortions are clearly detected in the redshift-space correlation function, the degree of which is consistent with the assumption of gravitational clustering and halo bias in the cosmic density field. In agreement with previous studies we find a strong increase of the correlation length with the mean intergroup separation. Although well-determined observationally, we show that current theoretical predictions are not yet accurate enough to allow for stringent constraints on cosmological parameters. Finally, we use our results to explore the power-law nature of the 2PCF of galaxies. We split the 2PCF into one- and two-group terms, equivalent to the one- and two-halo terms in halo occupation models, and show that the power-law form of the 2PCF is broken, when only including galaxies in the more massive systems.     

North Atlantic control on precipitation pattern in the eastern Mediterranean/Black Sea region during the last glacial

Based on proxy records from western Black Sea cores, we provide a comprehensive study of climate change during the last glacial maximum and late-glacial period in the Black Sea region. For the first time we present a record of relative changes in precipitation for NW Anatolia based on variations in the terrigenous supply expressed as detrital carbonate concentration. The good correspondence between reconstructed rainfall intensity in NW Anatolia and past western Mediterranean sea surface temperatures (SSTs) implies that during the glacial period the precipitation variability was controlled, like today, by Mediterranean cyclonic disturbances. Periods of reduced precipitation correlate well with low SSTs in the Mediterranean related to Heinrich events H1 and H2. Stable oxygen isotopes and lithological and mineralogical data point to a significant modification in the dominant freshwater/sediment source concomitant to the meltwater inflow after 16.4 cal ka BP. This change implies intensification of the northern sediment source and, with other records from the Mediterranean region, consistently suggests a reorganization of the atmospheric circulation pattern affecting the hydrology of the European continent. The early deglacial northward retreat of both atmospheric and oceanic polar fronts was responsible for the warming in the Mediterranean region, leading simultaneously to more humid conditions in central and northern Europe.     

Hydrogeophysical Methods for Analyzing Aquifer Storage and Recovery Systems

Hydrogeophysical methods are presented that support the siting and monitoring of aquifer storage and recovery (ASR) systems. These methods are presented as numerical simulations in the context of a proposed ASR experiment in Kuwait, although the techniques are applicable to numerous ASR projects. Bulk geophysical properties are calculated directly from ASR flow and solute transport simulations using standard petrophysical relationships and are used to simulate the dynamic geophysical response to ASR. This strategy provides a quantitative framework for determining site‐specific geophysical methods and data acquisition geometries that can provide the most useful information about the ASR implementation. An axisymmetric, coupled fluid flow and solute transport model simulates injection, storage, and withdrawal of fresh water (salinity ～500 ppm) into the Dammam aquifer, a tertiary carbonate formation with native salinity approximately 6000 ppm. Sensitivity of the flow simulations to the correlation length of aquifer heterogeneity, aquifer dispersivity, and hydraulic permeability of the confining layer are investigated. The geophysical response using electrical resistivity, time‐domain electromagnetic (TEM), and seismic methods is computed at regular intervals during the ASR simulation to investigate the sensitivity of these different techniques to changes in subsurface properties. For the electrical and electromagnetic methods, fluid electric conductivity is derived from the modeled salinity and is combined with an assumed porosity model to compute a bulk electrical resistivity structure. The seismic response is computed from the porosity model and changes in effective stress due to fluid pressure variations during injection/recovery, while changes in fluid properties are introduced through Gassmann fluid substitution.     

Palynomorphe und organisches Material aus den Raibler Schichten einer oberostalpinen Schuppe der Iberger Klippen (Kanton Schwyz, Schweiz)

A palynology and organic matter study has been carried out on samples of the Upper Triassic Raibl beds from an Upper Austroalpine thrust sheet, preserved in the area of the Iberg Klippen (Laucherenst?ckli). The palynological assemblages indicate an early Carnian (Julian) age. Comparison with well calibrated successions from the Southern Alps suggests a correlation with the Late Julian ammonoid zone Austrotrachyceras austriacum. The lithofacies of the studied sections suggests a substantial similarity to Raibl beds of the Upper Austroalpine of the Northern Calcareous Alps and those of the Silvretta- and the S-charl nappe of the Grisons. The minute Upper Austroalpine thrust sheet represents the westward extension of series with similar facies, which are still preserved in the Northern Calcareous Alps of Liechtenstein and western Austria (Vorarlberg). According to the Thermal Alteration Scale (TAS) of Batten (1996) the observed medium brown colors of the pollen grains correspond to a value of 4/5, which is equivalent to vitrinite reflectance (VR) values of 0.7–0.9 %R_o. In comparison with other sites in Liechtenstein, Vorarlberg and the Upper Austroalpine of Central Grisons (Silvretta and S-charl nappe) with measured VR values of > 2%R_o the organic matter of the studied samples shows only minor thermal alteration, indicating that the Upper Austroalpine thrust sheets of Iberg represent the highest part of the nappe stack in Central Switzerland, formerly covered by a comparatively thin overburden.