The vulnerability of karst springs—a case study of the Hubelj spring (SW Slovenia)

The hydraulic behaviour of the karst aquifer in the Hubelj spring catchment area (SW Slovenia) was studied by using an indirect research method based on natural tracers. The variations of natural tracers (in precipitation and in groundwater) during the storm event made possible the separation of the Hubelj spring storm hydrograph by the three-component separation technique. The results produced information on the aquifer recharge, storage and discharge processes, as well as on the mechanisms that affected them. They verified the so-called epikarst hypothesis presuming that an important part of a karst aquifer recharge reaches rapidly and intensively from the epikarst zone. It was demonstrated that epikarst water could occupy up to 50% of the spring discharge during precipitation events. This phenomenon could have important consequences on protection and management of the problems of karst aquifers, including engineering problems in karst areas. With this respect the results could give way to new engineering ideas.     

Studying of liquid thermolysis products of various types of immature kerogen in sedimentary lacustrine rocks from the valjevo-Mionica basin,Serbia, and the effect of Pt<Superscript>4+</Superscript> and Ru<Superscript>3+</Superscript> ions on their yield and the hydrocarbon composition

Liquid thermolysis products of various types of immature kerogen from sedimentary lacustrine rocks from the Valjevo-Mionica basin in Serbia were studied to evaluate the generation potential of kerogen contained in the organic matter (OM) of the rocks, determine the composition of the biomarkers and alkylaromatics in the liquid thermolysis products, and elucidate the effect of Pt⁴⁺ and Ru³⁺ ions (which were added in the form of inorganic salts) on the yield and hydrocarbon composition of the liquid thermolysis products. For this purpose, representative bitumen-free samples A and B of the sedimentary rocks were subjected to thermolysis under various conditions. Rock A contains high amount of immature organic matter, which is dominated by kerogen type I/II and was generated under strongly reduced sedimentation conditions at a high salinity. Sample B is poorer in immature OM than sample A, and the OM of the former contains kerogen type II/III and was generated predominantly in a reduced environment. The content of the liquid products and the concentrations of hydrocarbons obtained in the course of thermolysis of bitumen-free sample A and the typical oil distribution of the biomarkers and alkylaromatics in the thermolysis products confirm a high generation potential of OM in this rock. In all of our experiments on the thermolysis of bitumen-free sample B, the yield of liquid products and hydrocarbons is low. According to the kerogen type, the thermolysis of this rock generates much gases. The Pt⁴⁺ and Ru³⁺ ions (added in the form of simple inorganic salts) increased the yield of liquid (kerogen type I/II) and gaseous (kerogen type II/III) products. During the thermolysis of various type of immature kerogen in the lacustrine sedimentary rocks at a temperature of 400°C, the OM attained maturation corresponding to the early catagenesis level. Saturated biomarkers and alkylaomatics in the thermolysis products of both samples display typical oil distributions. The type of the source OM most strongly affects the composition of n-alkanes and alkylnaphthalenes. The metal ions used in this research served as catalysts for the methylation process during the thermolysis of immature kerogen, regardless of its type. The effect of the Pt⁴⁺ and Ru³⁺ ions on other transformations of the hydrocarbons, for example, the destruction of high-molecular n-alkanes to low-molecular ones and on isomerization reactions in molecules of polycyclic biomarkers and alkylaromatics to thermodynamically more stable isomers in the thermolysis products is controlled, first of all, by the type of the source OM.     

Possibilities of GPS Kinematic Measurements for Geological Survey in East Slovakia

This paper deals with transformation procedures for observed GPS data from the world geodetic system WGS-84 into the national geodetic grid datum S-UTCN(system of united trigonometric cadaster network) and Baa(the Baltic Sea after adjustment).Transformation from WGS-84 into SUTCN is performed most frequently by means of the 7-element Helmert transformation with three identical points.Geodetic network was adjusted by two ways.     

The dynamics of tourist excursion ratios in Slovakia show caves from 2000 to 2014

Show caves are one of the most important targets in developing local ecotourism strategies. This work focuses on a tourism visit rate incidence through an Attractiveness Index concerning 12 selected show caves in Slovakia. Our study focuses on visitor counts published from 2000 to 2014. A set of eight criteria were selected in order to analyse and determine the appeal that each cave may have for visitors. Establishing the “degree” of appeal as an indicator of the tourism and geographic absolute attractiveness value is based on a principal components factor analysis; the resultant single factor was correlated with our selected criteria. We find a strong correlation between touristic cave attractiveness and cave locations, ease of cave passage access (vehicle and trail) infrastructures, cave location in main tourism regions, and the growth of urban areas as they encroach on show cave locations. Similar studies in valorization of show caves tourism have not been attempted in Slovakia or Eastern Europe. The data and result from this study are also clearly important from a managerial perspective. This general framework could be easily expanded to include additional attributes that might be relevant for other market segments or other vacation experiences.     

Amazonite from the alkali granite of the Avdar Massif,Mongolia

Summary The green feldspar in alkali granite from the Avdar deposit of decoration stone (150 km W of Ulan-Bator) has been identified by means of physical and chemical methods as amazonite. Its structural state corresponds to that of microcline with a high degree of triclinicity and displaying the following anomalous dimensions of the unit cell (nm):a=0.8568,b=1.2967,c=0.7217 nm, =90.732, =115.851, =87.702°;V=0.72115 nm³.The amazonite contains in increased amount of Pb (1950 ppm) as well as of Rb (1.15 mass %). The genesis of this amazonite is associated with younger metasomatic processes in the alkali granite.

---

Amazonit aus dem Alkali-Granit des Avdar-Massivs, Mongolei

Zusammenfassung Der grüne Feldspat im Alkaligranit aus der Dekorationsstein-Lagerstätte im Avdar Massiv (150 km W von Ulan-Bator) wurde auf Grund physikalischer und chemischer Methoden als Amazonit bestimmt. Sein Strukturzustand entspricht demjenigen eines Mikroklins, der eine hohe Triklinität und anomale Elementarzelle aufweist (in nm):a=0.8568,b=1.2967,c=0.7217 nm, =90.732, =115.851, =87.702°;V=0.72115 nm³.Der Amazonit hat einen erhöhten Gehalt an Pb (1950 ppm) und an Rb (1.15 Gew.-%). Die Genesis dieses Amazonits ist mit jüngeren metasomatischen Prozessen im Alkaligranit verknüpft.

---

---

With 1 Figure     

Anthropogenic influence on trace element geochemistry of healing mud (peloid) from Makirina Cove (Croatia)

Due to their balneotherapeutic features, the organic-rich sediments in Makirina Cove are an important source of healing mud. An environmental geochemistry approach using normalization techniques was applied to evaluate the anthropogenic contribution of trace metals to sediments used as healing mud. Sediment geochemistry was found to be associated with land-use change and storm events, as well as with proximity of a road with heavy traffic in the summer months. Local valley topography preferentially channels lithogenic and pollutant transport to the cove. Concentrations and distribution of trace metals indicate lithogenic (Ni, Cr, Co) and anthropogenic (Pb, Cu, Zn and Se) contributions to the sediments. The calculation of enrichment factors indicates a moderate (EFs between 2–3.5) input of anthropogenic Cu and Pb in surficial sediments to a depth of 10 cm. Patients using the Makirina Cove sediments as healing mud could be to some extent exposed to enhanced uptake of metals from anthropogenic sources via dermal contact.     

The IMF structure effects in vernal and autumnal midlatitude ionosphere

au a u naam u a nu¶rt; 1963–1973 . naam, m aum mun ma m mm nam aum n (II) na¶rt;am m u a uu ¶rt; u u,¶rt; ua ma u¶rt;, u u¶rt;a ma mn muna. mu u m ¶rt;u mam nm nmum n¶rt;auma amu m m mm II u a¶rt; ¶rt; n.     

Effects of the IMF pro- and anti-sectors in the winter midlatitude ionosphere

Summary On the basis of the 1966–73 data, the effect of the difference between pro- and anti-sectors of the IMF is found to be negligible in the winter midlatitude (Central Europe) ionosphere contrary to the dominant effect of this difference in the high-latitude ionosphere found earlier.

---

a ¶rt;a a 1966–73. u¶rt;m u m amu ¶rt; pro- u anti- mau . na a u ¶rt;um (¶rt; na) u, , a naa a, naum um u.