Controlling factors and environmental implications of mercury contamination in urban and agricultural soils under a long-term influence of a chlor-alkali plant in the North–West Portugal

This study aims at assessing the extent of total mercury (Hg) contamination in urban and agricultural soils under long-term influence of a chlor-alkali plant, located at about 1 km away from a town centre. Moreover, it aims at identifying the main factors controlling Hg contents’ distribution and associated potential hazards to environment and human health. The median value of total Hg for soil surface layer (0–10 cm) was 0.20 mg/kg (data ranging from 0.050 to 4.5 mg/kg) and for subsurface layer (10–20 cm) 0.18 mg/kg (data ranging from 0.046 to 3.0 mg/kg). The agricultural area showed higher Hg concentrations (ranging from 0.86 to 4.5 mg/kg) than urban area (ranging from 0.05 to 0.61 mg/kg), with some results exceeding target values set by the Dutch guidelines. Mercury concentrations observed in the studied area are more likely to be associated with the influence of the chlor-alkali plant and with the use of historically contaminated sludges and water from a nearby lagoon in agriculture, than to the impacts of urban development. The statistical correlations between Hg concentrations and soil properties suggest that anthropogenic metal sources should influence the spatial distribution more than the geological properties. Although the Hg emissions were drastically reduced 10 years ago, the area under influence of the chlor-alkali plant is still facing potential health and environmental threats arising from soil contamination.     

Applicability of sediment transport models to evaluate medium term evolution of tidal inlet systems

This paper derives local formulae to estimate bed roughness and suspended transport and present a method to calculate net sediment transport at tidal inlet systems, combining field data and a range of well established empirical formulations. To accomplish this, measurements spanning a spring-tidal cycle of mean water levels, waves, near-bed flow turbulence and bed forms were obtained from the Ancão Inlet, Ria Formosa lagoon system, Portugal. High-resolution hydrodynamic data were gathered using acoustic equipments and by measuring sediment properties (grain-size diameter and bed form dimensions) under fair-weather conditions. The results compared favourably with available direct and indirect field observations of sediment transport rates. The approach appears to be robust and widely applicable and so can be applied to the same conditions in any tidal inlet system. This is of particular importance when attempting to understand sediment transport at inlet mouths, and has practical applications in a range of coastal engineering and coastal management areas concerned with navigation safety, coastal erosion, ecosystem health and water quality. The study discusses the applicability of the method on evaluating system flushing capacity, giving important insights on multiple inlet evolution, particularly with regard to their persistence through time. The methodological framework can be applied to assess the long-term stability of single- and multiple-inlet systems, provided that estimates of sediment storage at ebb-tidal deltas are available and sediment transport estimates during storm events are statistically considered.     

A simplified approach for flood vulnerability assessment of historic sites

In the last decades, floods have increased in frequency all over the world due to diverse phenomena such as climate change, extended urbanization, land use, etc. Their social, cultural, economic and environmental impacts have also grown significantly, highlighting the need for the development of further studies and improved methods to manage and mitigate flood risk, mainly in urban areas. Historic sites need particular attention in this field, not only because the high and irreplaceable cultural value of these areas, but also taking into account that the constructive typologies that they host are particularly vulnerable to natural hazards. In consequence of that, the analysis of the phenomena, the evaluation of their consequences and the adoption of adequate mitigation and preparedness measures are presently a fundamental societal challenge. Having this in mind, the present paper aims at proposing an innovative methodology focused on the assessment of flood vulnerability in historic sites through the evaluation of a set of exposure and sensitivity indicators. From the analysis of these indicators, it is possible to obtain a Flood Vulnerability Index capable of measuring the spread of flood vulnerability over an extended area. The historic centre of Guimarães, in Portugal, declared by UNESCO as a World Heritage Site in 2001, is used here as a pilot case study to apply and discusses the preliminary version of the approach. Although some improvements are still needed, this approach can be already used to provides preliminary vulnerability scenarios and to point the way to the definition of more efficient and customized strategies for managing and mitigating flood risk in historic sites. Moreover, with further improvements and calibrations resorting to larger and more diverse data, it will be possible to reduce some of the uncertainties currently involved in the assessment process and to make its application wider and more robust.

     

Measuring the Permeability of Open-Framework Gravel

Open-framework gravel has permeability, k, above the measurement range of most laboratory constant-head permeameters because the head difference across the length of conventional permeameters is too small to be measured. Here we addressed the challenge of measuring the high k by using a 3 m long permeameter. The head difference over this length was of the order of 10⁻² to 10⁻³ m, which we could measure to the nearest 10⁻⁵ m. We collected data over the range of linear, laminar flow to nonlinear, laminar flow to verify that k was measured using data collected within the Darcian regime. We measured k between 4000 and 100,000 Darcies among experiments using different sediments.     

Estimating the Vehicle‐Miles‐Traveled Implications of Alternative Metropolitan Growth Scenarios: A Boston Example

This study demonstrates the potential value, and difficulties, in utilizing large‐scale, location aware, administrative data together with urban modeling to address current policy issues in a timely fashion. We take advantage of a unique dataset of millions of odometer readings from annual safety inspections of all private passenger vehicles in Metropolitan Boston to estimate the vehicle‐miles‐traveled (VMT) implication of alternative metropolitan growth scenarios: a sprawl‐type “let‐it‐be” scenario and a smart‐growth‐type “winds‐of‐change” scenario. The data are georeferenced to 250 × 250 m grid cells developed by MassGIS. We apply a greedy algorithm to assign Traffic Analysis Zone (TAZ) level household growth projections to grid cells and then use spatial interpolation tools to estimate VMT‐per‐vehicle surfaces for the region. If new growth households have similar VMT behavior as their neighbors, then the let‐it‐be scenario will generate 12–15% more VMT per household compared to the winds‐of‐change scenario. However, even the “wind‐of‐change” scenario, will result in new households averaging higher VMT per household than the Metro Boston average observed in 2005. The implication is that urban growth management can significantly reduce GHG but, by itself, will not be sufficient to achieve the GHG emission reduction targets set by the State for the transportation sector.     

Geochemistry of a sediment push-core from the Lucky Strike hydrothermal field,Mid-Atlantic Ridge

Hydrothermal sediment mineralogy and geochemistry can provide insights into seafloor mineralization processes and changes through time. We report a geochemical investigation of a short (22 cm) near-vent hydrothermal metalliferous sediment core from the Lucky Strike site (LS), on the Mid-Atlantic Ridge (MAR). The sediment was collected from the base of an active white smoker vent and comprises pure hydrothermal precipitates, mainly chalcopyrite, sphalerite, pyrite and barite, with negligible detrital and biogenic inputs. Geochemically, the core is enriched in elements derived from high-temperature hydrothermalism (Fe, Cu, Zn and Ba) and depleted in elements derived from low-temperature hydrothermalism (Mn), and metasomatism (Mg). The U/Fe content ratio is elevated, particularly in the deeper parts of the core, consistent with uptake from seawater associated with sulphide alteration. Rare earth elements (REE) concentrations are low and chondrite-normalized patterns are characteristic of high-temperature vent fluids with an enrichment in light REE and a pronounced positive Eu anomaly. A stronger positive Eu anomaly associated with higher La_n/Sm_n at the core top is controlled by barite precipitation. The hydrothermal influence on the REE decreases downcore with some evidence for a stronger seawater influence at depth. Nd isotopes also exhibit an increased detrital/seawater influence downcore. Pb isotope ratios are uniform and plot on the Northern Hemisphere Reference Line in a small domain defined by LS basalts and exhibit no detrital or seawater influence. Lucky Strike sediments are derived from high-temperature mineralization and are overprinted by a weak seawater–sediment interaction when compared with other Atlantic hydrothermal sites such as TAG. The larger seawater input and/or a larger detrital contribution in deeper layers can be explained by variable hydrothermal activity during sediment formation, suggesting different pulses in activity of the LS hydrothermal system.     

Spatiotemporal variability of vegetation due to drought dynamics (2012–2017): a case study of the Upper Paraíba River basin,Brazil

Natural Hazards - Vegetation indices have been widely used for monitoring the spatiotemporal variables of vegetation and characterizing droughts, primarily in semiarid regions. Drought is a...     

Evaluation of climate change effects in a coastal aquifer in Morocco using a density-dependent numerical model

A density-dependent numerical groundwater model was applied to study the climate change impact in a shallow aquifer in the Mediterranean coast of Morocco, the Saïdia aquifer. The stresses imposed to the model were derived from the IPCC emission scenarios and included recharge variation and sea level rise. The main effect of the climate change in the Saïdia aquifer will be a decrease in renewable resources, which in the worst-case scenario may decrease to 50–60% of present-day values, due to the decline in recharge and to a reduced inflow from the adjacent Triffa aquifer. The water quality will be affected mostly in the area immediately adjacent to the seashore, where salinity may increase up to 30 g/l. Localised areas may see a decrease in salinity due to the induced freshwater recharge from Oued Moulouya River and diminished inflow from high-salinity springs.     

Induced seismicity in the Castanhão reservoir, NE Brazil — Preliminary results

The Castanhão reservoir was built in the state of Ceará, a dry region in Northeastern Brazil, to regulate the flow of the Jaguaribe River, for irrigation, and for power generation. It is an earth-filled dam, 60 m high, with a water capacity of 4.5 × 10⁹ m³. The seismicity in the area has been monitored since 1998, with a few interruptions, using one analog or one digital station and, during a few periods, a three-station network. The first earthquakes likely to be induced events were detected in 2003, when the water level was about 20 m high. In early 2004 a very heavy rainfall season quickly filled the reservoir. Shortly after, an increase in the seismic activity occurred and many micro-earthquakes were recorded. We suggest that this activity resulted from an increase in pore pressure due to undrained response. Therefore, we may classify this cluster of micro-earthquakes as “initial seismicity.” We deployed a network with four analog stations in the area, following this activity, to determine the epicentral zone. At least three epicentral areas under the reservoir were detected. The spatio-temporal analysis of the available data revealed that the seismicity occurs in clusters and that these were activated at different periods. We identified four sets of faults (N–S-, E–W-, NW–SE-, and NE–SW-oriented), some of which moved in shallow crustal levels and as recently as the Quaternary (1.8 Ma). Under the present-day stress regime, the last two sets moved as strike-slip structures. We suggest a possible correlation between dormant faults and the observed induced seismicity.