Calibration of Local Magnitude M<Subscript>L</Subscript> in the Azores Archipelago Based on Recent Digital Recordings

—The development of the digital seismic network in the Azores Archipelago during recent years made it possible to obtain the amplitudes (waveform) of recorded motion in a large set of stations. With this new data, maximum amplitudes of the Wood Anderson seismograph are computed, for each station/component, which, together with epicentral distances, allows for the estimation of local magnitude M _L . We used data recorded in 8 digital permanent three-component stations, with inter-stations distances up to 300 km, in the period June 1998 – June 2000, corresponding to a set of 1315 events with magnitude (M _L or M _D ) 2<M<5.8 and epicenters located in the Azores region, to estimate the coefficients of the equation to compute M _L , as well as to determine the corrections to be applied to each station. The new set of parameters, formed by attenuation coefficients and station corrections, were introduced in the calculations of the M _L , leading to smaller dispersions in the analyzed dataset. We also conclude that the attenuation in the first 150 km is similar to the California values, although higher for longer distances.     

Concentration and subcellular distribution of trace elements in liver of small cetaceans incidentally caught along the Brazilian coast

Concentrations of trace elements (V, Cr, Mn, Fe, Co, Cu, Zn, Ga, As, Se, Rb, Sr, Mo, Ag, Cd, Sb, Cs, Ba, T-Hg, Org-Hg, Tl and Pb) were determined in liver samples of estuarine dolphin (Sotalia guianensis; n = 20), Franciscana dolphin (Pontoporia blainvillei; n = 23), Atlantic spotted dolphin (Stenella frontalis; n = 2), common dolphin (Delphinus capensis; n = 1) and striped dolphin (Stenella coeruleoalba; n = 1) incidentally caught along the coast of Sao Paulo State and Parana State, Brazil, from 1997 to 1999. The hepatic concentrations of trace elements in the Brazilian cetaceans were comparable to the data available in literature on marine mammals from Northern Hemisphere. Concentrations of V, Se, Mo, Cd, T-Hg and Org-Hg increased with increasing age in liver of both estuarine and Franciscana dolphins. Very high concentrations of Cu (range, 262-1970 microg/g dry wt.) and Zn (range, 242-369 microg/g dry wt.) were observed in liver of sucklings of estuarine dolphin. Hepatic concentrations of V, Se, T-Hg, Org-Hg and Pb were significantly higher in estuarine dolphin, whereas Franciscana dolphin showed higher concentrations of Mn, Co, As and Rb. Ratio of Org-Hg to T-Hg in liver was significantly higher in Franciscana dolphin than estuarine dolphin, suggesting that demethylation ability of methyl Hg might be lower in liver of Franciscana than estuarine dolphins. High hepatic concentrations of Ag were found in some specimens of Franciscana dolphin (maximum, 20 microg/g dry wt.), and 17% of Franciscana showed higher concentrations of Ag than Hg. These samples with high Ag concentration also exhibited elevated hepatic Se concentration, implying that Ag might be detoxified by Se in the liver. Higher correlation coefficient between (Hg+0.5 Ag) and Se than between Hg and Se and the large distribution of Ag in non-soluble fraction in nuclear and mitochondrial fraction of the liver also suggests that Ag might be detoxified by Se via formation of Ag2Se in the liver of Franciscana dolphin.     

Characteristics of chaotic pulse trains generated by lightning flashes

Pulse trains of irregular pulse characteristics and erratic amplitudes are observed in lightning flashes. These are termed “chaotic pulse trains” in this study. The average width of the individual pulses of these pulse trains is in the range of a few microseconds, with the lower limit of individual measurements extending into the sub-microsecond region. The typical pulse separation lies in the range of 2–. The pulse duration shows a consistent distribution with the most probable value at 400–. Chaotic pulse trains occur most often immediately prior to subsequent strokes. However, they occur also a few milliseconds to several tens of milliseconds prior to return strokes and sometimes do not precede return strokes at all. Twenty-six percent of the total subsequent strokes recorded in this study were preceded by chaotic pulse trains. A few of these pulse trains have occurred in a sequence of several tens of millisecond intervals in between return strokes. We have also found them to occur within very intense cloud flashes. These chaotic pulse trains have features that are different from those of other known pulse trains reported in the lightning literature. Hence, they may be caused by a physical process that has not yet been identified.     

Sequential melting and fractional crystallization: Granites from Guarda-Sabugal area, central Portugal

Seven distinct phases of Variscan two-mica granite are recognized in the Guarda-Sabugal area. They intruded the Cambrian schist-metagraywacke complex, crystallized in the middle crust, and are syn- to late-D3 (309.2 ± 1.8 Ma), late-D3 (304–300 Ma) and late- to post-D3 (299 ± 3 Ma; ID-TIMS ages on zircon and monazite). Two of the granites, G2 and G5, are close in age and have similar Sr, Nd and O isotope characteristics but contrasting whole rock and mineral features and formed by sequential increasing degree of partial melting of a common metasedimentary protolith. During sequential melting Ti, total Fe, Mg, Ca, Zr, Zn, Sr, Ba and REE contents and (La/Yb)_N increase and Si and Rb contents decrease, plagioclase becomes richer in anorthite and biotite and muscovite richer in Ti and Mg. Each of these granites evolved subsequently by fractional crystallization of quartz, K-feldspar, plagioclase, biotite and ilmenite, defining separate series G2–G3–G7 and G5–G6 containing late Sn-bearing differentiates. Two other granites G1 and G4 represent distinct pulses of magma with individual fractionation trends for major and trace elements and distinct (⁸⁷Sr/⁸⁶Sr)₃₀₀, ?Nd₃₀₀ and δ¹⁸O values.     

Upper Cretaceous marine‐continental transition (Leonese Area,NW Spain) defined from integrated outcrop and seismic stratigraphy

The Upper Cretaceous succession of the Leonese Area (NW Spain) comprises mixed clastic and carbonate sediments. This succession is divided into two lithostratigraphic units, the Voznuevo Member and the Boñar Formation, which represent fluvial, shoreface, intertidal, subtidal and open‐shelf sedimentary environments. Regional seismic interpretation and sequence stratigraphic analysis have allowed the study of lateral and vertical changes in the sedimentary record and the definition of third‐order levels of stratigraphic cyclicity. On the basis of these data, the succession can be divided into two second‐order depositional sequences (DS‐1 and DS‐2), incorporating three system tracts in a lowstand to transgressive to highstand system tract succession (LST–TST–HST). These sequences are composed of fluvial systems at the base with palaeocurrents that flowed westward and south‐westward. The upper part of DS‐1 (Late Albian–Middle Turonian) shows evidence of intertidal to subtidal and offshore deposits. DS‐2 (Late Turonian–Campanian) comprises intertidal to subtidal, tidal flat, shallow marine and lacustrine deposits and interbedded fluvial deposits. Two regressive–transgressive cycles occurred in the area related to eustatic controls. The evolution of the basin can be explained by base‐level changes and associated shifts in depositional trends of successive retrogradational episodes. By using isobath and isopach maps, the main palaeogeographic features of DS‐1 and DS‐2 were constrained, namely coastline positions, the existence and orientation of corridors through which fluvial networks were channelled and the location of the main depocentres of the basin. Sedimentation on the Upper Cretaceous marine platform was mainly controlled by (i) oscillations of sea level and (ii) the orientation of Mesozoic faults, which induced sedimentation along depocentres. Copyright © 2013 John Wiley & Sons, Ltd.     

The crystal chemistry of lithium and Fe3+ in synthetic orthopyroxene

Lithian ferrian enstatite with Li₂O = 1.39 wt% and Fe₂O₃ 7.54 wt% was synthesised in the (MgO–Li₂O–FeO–SiO₂–H₂O) system at P = 0.3 GPa, T = 1,000°C, fO₂ = +2 Pbca, and a = 18.2113(7), b = 8.8172(3), c = 5.2050(2) Å, V = 835.79(9) Å³. The composition of the orthopyroxene was determined combining EMP, LA-ICP-MS and single-crystal XRD analysis, yielding the unit formula ^M2(Mg_0.59Fe _0.21 ²⁺ Li_0.20) ^M1(Mg_0.74Fe _0.20 ³⁺ Fe _0.06 ²⁺ ) Si₂O₆. Structure refinements done on crystals obtained from synthesis runs with variable Mg-content show that the orthopyroxene is virtually constant in composition and hence in structure, whereas coexisting clinopyroxenes occurring both as individual grains or thin rims around the orthopyroxene crystals have variable amounts of Li, Fe³⁺ and Mg contents. Structure refinement shows that Li is ordered at the M2 site and Fe³⁺ is ordered at the M1 site of the orthopyroxene, whereas Mg (and Fe²⁺) distributes over both octahedral sites. The main geometrical variations observed for Li-rich samples are actually due to the presence of Fe³⁺, which affects significantly the geometry of the M1 site; changes in the geometry of the M2 site due to the lower coordination of Li are likely to affect both the degree and the kinetics of the non-convergent Fe²⁺-Mg ordering process in octahedral sites.     

Putative Meteoritic Craters in Río Cuarto (Central Argentina) Interpreted as Eolian Structures

Ten oblong aligned depressions in the Río Cuarto area (provincia de Córdoba, Argentina) were supposed to be the result of very-low-angle Holocene meteoroid impacts. However, we consider that authors that studied the structures did not demonstrated their extraterrestrial origin. We suggest that an eolian origin for the structures of Río Cuarto is more likely. Actually, these landforms integrate large systems of similar deflation/accumulation geoforms aligned according to predominant winds during different periods.     

Late Cretaceous porphyry copper mineralization in Sonora,Mexico: Implications for the evolution of the Southwest North America porphyry copper province

Two porphyry Cu-Mo prospects in northern Sonora, Mexico (Fortuna del Cobre and Los Humos) located within the southwestern North American porphyry province have been dated in order to constrain the timing of crystallization and mineralization of these ore deposits. In Fortuna del Cobre, the pre-mineralization granodiorite porphyry yielded an U-Pb zircon age of 76.5?±?2.3 Ma, whereas two samples from the ore-bearing quartz feldespathic porphyry were dated at 74.6?±?1.3 and 75.0?±?1.4 Ma. Four molybdenite samples from Los Humos porphyry Cu prospect yielded a weighted average Re-Os age of 73.5?±?0.2 Ma, whereas two samples from the ore-bearing quartz monzonite porphyry gave U-Pb zircon ages of 74.4?±?1.1 and 74.5?±?1.3 Ma, showing a Late Cretaceous age for the emplacement of this ore deposit. The results indicate that Laramide porphyry Cu mineralization of Late Cretaceous age is not restricted to northern Arizona as previously thought and provide evidence for the definition of NS trending metallogenic belts that are parallel to the paleo-trench. Porphyry copper mineralization follows the inland migration trend of the magmatic arc as a result of the Farallon slab flattening during the Laramide orogeny.     

Using time‐domain reflectometry to characterize shallow solute transport in an oak woodland hillslope in northern California,USA

The natural heterogeneity of water and solute movement in hillslope soils makes it difficult to accurately characterize the transport of surface‐applied pollutants without first gathering spatially distributed hydrological data. This study examined the application of time‐domain reflectometry (TDR) to measure solute transport in hillslopes. Three different plot designs were used to examine the transport of a conservative tracer in the first 50 cm of a moderately sloping soil. In the first plot, which was designed to examine spatial variability in vertical transport in a 1·2 m² plot, a single probe per meter was found to adequately characterize vertical solute travel times. In addition, a dye and excavation study in this plot revealed lateral preferential flow in small macropores and a transport pattern where solute is focused vertically into preferential flow pathways. The bypass flow delivers solute deeper in the soil, where lateral flow occurs. The second plot, designed to capture both vertical and lateral flow, provided additional evidence confirming the flow patterns identified in the excavation of the first plot. The third plot was designed to examine lateral flow and once again preferential flow of the tracer was observed. In one instance rapid solute transport in this plot was estimated to occur in as little as 3% of the available pore space. Finally, it was demonstrated that the soil anisotropy, although partially responsible for lateral subsurface transport, may also homogenize the transport response across the hillslope by decreasing vertical solute spreading. Copyright © 2002 John Wiley & Sons, Ltd.