Geochemical,mineralogical and magnetic characteristics of vertical dust deposition in urban environment

Studies on composition and distribution of dust deposition are necessary for the risk assessment of dust to atmospheric quality. We studied the vertical distribution pattern of dust and metal (Cu, Fe, Pb, Zn) deposition up to 33 m height in urban environment. Integrated geochemical, mineralogical and magnetic study of the seasonally sampled dust helped to specify our knowledge on the use of magnetic susceptibility for tracking its deposition. Harmful dust and metal deposition may occur even at great heights and at the low-traffic side of buildings. Re-suspension of local surface materials dominates the dust deposition primarily in summer and spring due to weather conditions, and it may overwrite the influence of recent anthropogenic activities on dust composition. The accepted air-flow models should be modified by taking the local conditions (weather, morphology, etc.) into account. All studied metals showed strong enrichment in the dust and could be characterized by similar vertical deposition pattern to dust. The total susceptibility was found to be much more useful proxy for tracking dust and metal deposition than mass-specific susceptibility. Using the former, potential errors arising from sampling practice of settled dust could be eliminated. The most important heavy-metal-bearing phases were iron oxides and clay minerals. Their different behavior during the dust deposition is reflected by the vertical metal distribution patterns. Clay minerals originate primarily from re-suspension and may be one of the most important sources of potentially mobile heavy metals in such materials.     

APEX-SZ first light and instrument status

The apex-sz instrument is designed for the discovery and study of galaxy clusters at mm-wavelengths using the Sunyaev Zel’dovich effect. The receiver consists of 320 superconducting transition edge sensor (TES) bolometers cooled to 250 mK with the combination of a three stage He sorption fridge and mechanical pulse tube cooler. The detectors are instrumented with a frequency domain multiplexing readout system. The receiver is mounted on the 12 m apex telescope located at 5100 m on the Atacama plateau in Chile. For the first light engineering deployment of December 2005, the receiver was configured with a 55 element wedge of the bolometers and operating in the 150 GHz atmospheric window. During the engineering run we achieved significant milestones in our instrumentation development efforts, including celestial observations with a monolithically fabricated TES bolometer array cooled with a mechanical cooler and successful implementation of a SQUID-based MHz AC-biased readout. These technology demonstrations point the way toward future large TES bolometer array instruments. Here we describe the results of this deployment and future plans for the apex-sz instrument.     

Double-mode stellar pulsation

The current observational and theoretical status of the double-mode variables is reviewed. Focusing mostly on the RR Lyrae stars, we address the question of the observational evidence ofmodal stability. The problem of stationarity is a crucial issue in the modelling of these stars.We mention past efforts in hydrodynamical and analytical modelling together with a detailed discussion of some very recent results. It is suggested that stochastic forcing due to turbulent convection may play a crucial role in exciting some marginally stable modes in the limiting pulsation. The latest hydrodynamical results first demonstrate that purelyradiative models are able to showpermanent double-mode behavior in the relevant period regime of RRd stars. The reason for the previous lack of double-mode behavior is attributed to the large dissipation,i.e. artificial viscosity, generally used in the codes to ensure numerical stability and to obtain amplitudes comparable to the observed ones.We think that better models should include some physical dissipation, most probably turbulent convection, and a more accurate numerical treatment of the radiative hydrodynamics.     

Inflation and compactification from Galaxy redshifts?

The distribution of galaxies in the pencil-beam surveys of Broadhurstet al. which proved periodical across 8–10 consecutive steps in a flat dust model withq ₀=0.5 is found to reveal extended periodicity up to 16–17 phase-coherent steps, covering the total sample, in a flat, moderately inflationary model withq ₀=–0.5 (vacuum/dust ratio 2/1). In the latter model the vacuum component helps to reach the critical density and lengthens the expansion time-scale. It is shown that the explanation of the found periodicity as a consequence of space compactification as suggested by G. Paál twenty years ago in connection with apparent quasar periodicities is still possible.     

Cryogenic powderization of Triassic dolostones in the Buda Hills, Hungary

Disintegration of dolostones to dolomite powder (powderization) was a widespread phenomenon in Triassic dolostones of the Buda Hills, where the areal extent of powdered dolostones is large compared to similar occurrences elsewhere in the world. In the Buda Hills, dolostone disintegration proceeded in four stages that correspond to a gradual decrease in particle size, that is, from the parent dolostone to (1) crackle breccia; via (2) mosaic breccia (diameter <2 cm); via (3) mosaic breccia blocks ‘floating’ in dolomite powder; to (4) dolomite powder (diameter 100–300 μm). Stable isotope ratios and trace element compositions of dolomite remained constant throughout these stages, and there are no indications of dissolution in most locations, suggesting that disintegration was predominantly a mechanical process. Combining these findings with the geological history of the region, and supported by a simple freezing/thawing experiment and pertinent experimental studies on weathering of building stones, it appears that powderization in the Buda Hills was caused by repeated freeze–thaw cycles during and/or after the Pleistocene glaciations. Subaerial exposure under cold climate conditions involves multiple freeze–thaw cycles that create mechanical stresses in the rock framework related to the opposing thermal expansion of rock and water that freezes and of ice that liquefies. This process is herewith called ‘cryogenic powderization’. Our data further suggest that the synergy of four factors promoted dolostone powderization in the Buda Hills: (1) tectonics, which created a pervasive fracture network; (2) intercrystalline porosity of the dolostone; (3) relatively high water saturation; and (4) subaerial exposure under cold climate conditions.     

Waste rock dump investigation at Roşia Montană gold mine (Romania): a geostatistical approach

Ro?ia Montan?, the largest European gold mine, could be re-opened. Environmental problems led to severe pollution of the Ro?ia and Abrud Rivers. The two main potentially toxic element (PTE) sources in mine sites are, in general, the abandoned underground workings and the piles of waste rock. Since the composition of waste rocks is often heterogeneous, this study faces the problem of estimating their mineralogical and chemical features starting from a set of sampling point. Twenty-five samples were collected on the main waste dump of the Ro?ia Montan? mine following a virtual squared grid (knots distance about 25 m). Grain size, color, bulk chemistry, mineralogy, acid mine drainage potential and a set of selected PTE (Ag, As, Cu, Ni, Pb and Zn) concentrations were determined on each sample. In a first approximation two main waste rock groups were identified: WR1 bulk composition is dacite-dominated, while WR2 is andesite-dominated. In both of them the concentrations of PTEs are below the regulatory limits for soils, with the exception of As. In terms of acid mine drainage, WR1 has a net acid-producing potential, while WR2 has a net neutralizing potential. The anisotropy of WR properties were analysed by means of semi-variograms and displayed with contour maps. Application of positive matrix factorization for the analysis of all the data relative to waste rocks allowed defining, in a semi-quantitative way, the factors controlling pollution and their spatial distribution. The processing of score matrix G factor associated with the geostatistical elaboration promises to be a powerful tool to discern the composition of mine dumps and support the exploitation and remediation phases.     

Sampling and mapping of heterogeneous surfaces: multi-resolution tiling adjusted to spatial variability

Abstract

Mapping by sampling and prediction of local and regional values of two-dimensional surfaces is a frequent, complex task in geographical information systems. This article describes a method for the approximation of two-dimensional surfaces by optimizing sample size, arrangement and prediction accuracy simultaneously. First, a grid of an ancillary data set is approximated by a quadtree to determine a predefined number of homogeneous mapping units. This approximation is optimal in the sense of minimizing Kullback-divergence between the quadtree and the grid of ancillary data. Then, samples are taken from each mapping unit. The performance of this sampling has been tested against other sampling strategies (regular and random) and found to be superior in reconstructing the grid using three interpolation techniques (inverse squared Euclidean distance, kriging, and Thiessen-polygonization). Finally, the discrepancy between the ancillary grid and the surface to be mapped is modelled by different levels and spatial structures of noise. Conceptually this method is advantageous in cases when sampling strata cannot be well defined a priori and the spatial structure of the phenomenon to be mapped is not known, but ancillary information (e.g., remotely-sensed data), corresponding to its spatial pattern, is available.     

Regional Geomagnetic Field Model for Croatia at 2009.5

Geomagnetic data of north, east, and vertical components at Croatian repeat stations and ground survey sites, as well as European geomagnetic observatories and repeat stations, were used to obtain a regional geomagnetic model over Croatia at 2009.5 epoch. Different models were derived, depending on input data, and three modelling techniques were used: Taylor Polynomial, Adjusted Spherical Harmonic Analysis, and Spherical Harmonic Analysis. It was derived that the most accurate model over Croatia was the one when only Croatian data were used, and by using the Adjusted Spherical Harmonic Analysis. Based on Croatian repeat stations’ data in the interval 2007.5–2010.5, and a global Enhanced Magnetic Model, it was possible to estimate the crustal field at those sites. It was also done by taking into account the empirical adjustment for long-term external field variations. The higher crustal field values were found at those stations which are on or close to the Adriatic anomaly.     

New Seismic and Tomography Data in the Southern Part of the Harghita Mountains (Romania, Southeastern Carpathians): Connection with Recent Volcanic Activity

The southern part of the southeastern Carpathians represents the site of the most recent volcanic eruptions of the entire Carpathian-Pannonian region. The products of these eruptions range from 42 to 10?Ka radiocarbon ages in the South Harghita Mountains (high K calc-alkaline rocks with adakite-like features), and at 1.2–0.6?Ma?K–Ar ages in the Per?ani Mountains (alkali basalts). They were emplaced in a post-collisional regime. Ciomadul volcano is located at the southernmost part of the NW–SE oriented C?limani-Gurghiu-Harghita range crossing the inner part of the southeastern Carpathians and in the rough proximity of the Vrancea seismic zone (at ca. 60?km toward NW). Its magma generation is attributed to geodynamic events closely related to the seismogenic area. A number of particular geophysical and geochemical features located in the study region, including (1) the abrupt attenuation of the seismic waves originating from the Vrancea intermediate-depth foci, (2) the most intense heat-flow anomaly in Romania, (3) the most prominent ³He/⁴He anomaly measured in natural “postvolcanic” gas emanations, are all in favor of the hypothesis of a still existing hot local magma chamber. Data acquired during recent seismic monitoring of the Vrancea zone and its neighborhoods suggest an enhancement of the local seismicity beneath the southern edge of the South Harghita Mts., both at crustal and subcrustal levels. At the same time, recent tomography images obtained using local earthquake data correlate well with the presence of a vertically extended low-velocity zone coming from the upper mantle to the assumed magmatic chambers located in the crust. The present data, supporting the presence of an active crustal magma chamber beneath Ciomadul, allow us to consider that future volcanic activity at this volcano cannot be discarded.