Factors controlling the vegetation distribution and coal‐forming environments in a strike‐slip basin. The Pennsylvanian Peñarroya‐Belmez‐Espiel Basin,southern Spain

Coal‐forming environments require humid to perhumid conditions. Tectonics governs the size, location and availability of coal seams developed in such environments. While large Pennsylvanian paralic basins generated thick and continuous coal seams, many other small coeval basins, which were tectonically active, developed a puzzling succession, with carbonaceous deposits that varied in size, thickness and the nature of the coal‐forming flora. This study, conducted in the Peñarroya‐Belmez‐Espiel coalfield, a Variscan strike‐slip basin in the south of Spain, provides insights into this subject. The coal seams analysed, generated in different depositional environments, have quantitatively different palynological assemblages. Lacustrine coals are dominated by lycopsids; distal alluvial plain/marginal lacustrine coals are dominated by sphenophytes and tree ferns, and middle alluvial fan coals are dominated by sphenophytes, tree ferns and lycopsids. This means that when conditions were favourable for peat accumulation, peat accumulated regardless of the nature of the available flora.     

Spatial multicriteria approach to water scarcity vulnerability and analysis of criteria weighting techniques: a case study in São Francisco River,Brazil

The water availability deficit is a governance crisis and an environmental, social, and economic risk. This study presents a spatial multicriteria approach for mapping Water Scarcity Vulnerability (WSV) and a comparative analysis of criteria weighting techniques to support the management of water resources in semiarid regions. Initially, nine vulnerability indicators were identified from a literature review and spatialized through a Geographic Information System (GIS) for a water donor region and another recipient from the São Francisco River, in the semiarid region of Brazil. Subsequently, one subjective and two objectives weighting techniques were implemented and compared to measure the weights of the indicators. Finally, the Viekriterijumsko Kompromisno Rangiranje (VIKOR) method was combined with GIS to construct WSV maps. The results indicate the conditions of WSV in the transposition water donor region can be more critical than the region receiver, and the choice of the weighting method influences the results of the multicriteria-GIS approaches. The WSV mapping approach can be helpful for water management decision-making to identify priority areas and spatial inequalities. The comparative analysis in this study can provide a valuable reference for choosing weighting methods in spatial multicriteria applications.

     

Land use and land cover dynamics in Leiria City: relation between peri-urbanization processes and hydro-geomorphologic disasters

Natural Hazards - The objective of the present study is to evaluate the relation between the spatial and temporal dynamics of Land Use and Land Cover (LULC) and the hydro-geomorphological processes...     

Dynamics of phosphorus and nitrogen through litter fall and decomposition in a tropical mangrove forest

Distribution, dynamics and mass budget of phosphorus and nitrogen in a red mangrove forest were studied in the Potengi mangrove forest in northern Brazil (lat. 5 degrees 42' and 5 degrees 53'S, long. 35 degrees 5' and 35 degrees 25'W). Tidal hydrology, net primary productivity, leaf litter decomposition rate and standing stock of leaf litter in a red mangrove forest were measured. The results showed that the main reservoir for total P and total N was the sediment with 309 kg ha(-1) and 4619 kg ha(-1) (77% and 95% of the total P and N content in the mangrove forest), respectively, for the two elements. Total P and total N in Rhizophora mangle trees accounted for 145+/-14 kg ha(-1) and 216+/-23 kg ha(-1) (23% and 5% of the total P and N in the mangrove forest). The estimated average export rates for P and N through leaf litter are 0.5 kg ha(-1)yr(-1) and 1.6 kg ha(-1)yr(-1) respectively. Our measurements support previous results in concluding that mangrove forests efficiently retain P and N.     

Brain acetylcholinesterase as a marine pesticide biomarker using Brazilian fishes

Brain acetylcholinesterase (AChE) of some fishes from the coast of Rio de Janeiro State was studied as a possible pesticide biomarker in marine environmental monitoring. AChE specific activity in brain varied from 145 to 530 U/g of proteins and the Michaelis-Menten constant (K(M)) for acetylthiocholine varied from 104 to 291 microM among the 20 species studied. The enzyme sensitivity to methyl paraoxon, evaluated by the inhibition kinetic constants, shows that some species (Paralonchurus brasiliensis and Genidens genidens) are more sensitive (IC50-30 min=455 and 468 nM, respectively). The less sensitive Merluccius hubbsi and Percophis brasiliensis (IC50-30 min=3339 and 3259 nM, respectively) belong to the super-order Paracanthopterygii, which includes the more ancient species. On the other hand, more susceptible species belong to the super-order Acanthopterygii, which includes more recent species. These results suggest a possible evolutionary linkage for AChE sensitivity to methyl paraoxon. The application of inhibition kinetic constants for fish brain AChE in phylogenetic studies is still being investigated. The results have shown that a fish sentinel species should have the highest brain AChE level among the more sensitive ones.     

Depuration dynamics of oysters (Crassostrea gigas) artificially contaminated by Salmonella enterica serovar Typhimurium

The State of Santa Catarina produces the greatest quantity of edible mollusks in Brazil. To guarantee sanitary qualify, mollusk cultures should be monitored for contamination by pathogenic microorganisms. A self-purification or "depuration" system that eliminates Salmonella enterica serovar Typhimurium contamination from oysters has been developed and evaluated. The depuration process occurred within a closed system, in which 1000 L of water was recirculated for 24 h. The water was sterilized with ultraviolet (UV) light, chlorine, or both together. Oysters (Crassostrea gigas) artificially contaminated with S. typhimurium were harvested every 6 h. Samples of oyster tissue were excised and both the presence and numbers of bacteria were determined. Combined UV light and chlorine treatments resulted in total elimination of bacteria within 12 h. Polymerase chain reaction detected bacteria in water exposed to the three treatments. This pioneering study is the first of its kind in Brazil and represents a major contribution to commercial mollusk culture in this country.     

Ray-traced slant factors for mitigating the tropospheric delay at the observation level

Three-dimensional ray tracing through a numerical weather model has been applied to a global precise point positioning (PPP) campaign for modeling both the elevation angle- and azimuth-dependence of the tropospheric delay. Rather than applying the ray-traced slant delays directly, the delay has been parameterized in terms of slant factors, which are applied in a similar manner to traditional mapping functions, but which can account for the azimuthal asymmetry of the delay. Five strategies are considered: (1) Vienna Mapping Functions 1 (VMF1) and estimation of a residual zenith delay parameter; (2) VMF1, estimation of a residual zenith delay and estimation of two tropospheric gradient parameters; (3) three-dimensional ray-traced slant factors and estimation of a residual zenith delay; (4) using only ray-traced slant factors and no estimation of any tropospheric parameters and; (5) using both ray-traced slant factors and estimating a residual zenith delay and two tropospheric gradient parameters. The use of the ray-traced slant factors (solution 3) showed a 3.8% improvement in the repeatability of the up component when compared to the assumption of a symmetric atmosphere (solution 1), while the estimation of two tropospheric gradient parameters gave the best results showing an 7.6% improvement over solution 1 in the up component. Solution 4 performed well in the horizontal domain, allowing for sub-centimeter repeatability but the up component was degraded due to deficiencies in the modeling of the zenith delay, particularly for stations located at equatorial latitudes. The magnitude of the differences in the mean coordinates between solution 2 and solution 3, and the strong correlation with the differences between the north component and the ray-traced gradients (coefficient of correlation of 0.83), as well as the impact of observation geometry on the gradient solution indicate that the use of the ray-traced slant factors could have an implication on the realization of reference frames. The estimated tropospheric products from the PPP solutions were compared to those derived from ray tracing. For the zenith delay, a root mean square (RMS) of 5.4 mm was found, while for the gradient terms, a correlation coefficient of 0.46 for the N–S and 0.42 for the E–W was found for the north–south and east–west components, suggesting that there are still important differences in the gradient parameters which could be due to either errors in the NWM or to non-tropospheric error sources leaking into the PPP-estimated gradients.