The impact of solution chemistry on Mytilus edulis calcite and aragonite

Magnesium/calcium, Sr/Ca, and Na/Ca atom ratios were determined in the calcite and aragonite regions of Mytilus edulis shells which were grown in semi-artificial ‘seawater’ solutions having varying Mg/Ca, Sr/Ca, and Na/Ca ratios. These ratios were measured by instrumental neutron activation, atomic absorption, and electron microprobe analytical techniques. Strontium/calcium ratios in both calcite and aragonite were linearly proportional to solution Sr/Ca ratios. Magnesium/calcium ratios in calcite increased exponentially when solution Mg/Ca ratios were raised above the normal seawater ratio; whereas in aragonite, Mg/Ca ratios increased linearly with increases in solution Mg/Ca ratios. Sodium/calcium and sulfur/calcium ratios in calcite covaried with Mg/Ga solution ratios. Conversely, in aragonite, Na/Ca ratios varied linearly with solution Na/Ca ratios.Magnesium is known to inhibit calcite precipitation at its normal seawater concentration. We infer from the results of the work reported here that Mytilus edulis controls the Mg activity of the outer extrapallial fluid, thus facilitating the precipitation of calcitic shell. Increases in sulfur content suggest that changes in shell organic matrix content occur as a result of environmental stress. Certain increases in Mg content may also be correlated to stress. Sodium/calcium variations, and their absolute amounts in calcite and aragonite, are best explained by assuming that a substantial amount of Na is adsorbed on the calcium carbonate crystal surface. Strontium/calcium ratios show more promise than either Mg/Ca or Na/Ca ratios as seawater paleochemistry indicators, because the Sr/Ca distribution coefficients for both aragonite and calcite are independent of seawater Ca and Sr concentrations.     

City size distributions and metropolisation

Many controversial questions about the shape and evolution of city size distributions can be solved if reliable, large and comparable set of data are used for several countries. We provide new empirical evidence by using the large data base Geopolis, which has strictly comparable figures for all towns and cities of the world over 10,000 inhabitants between 1950 and 1990. A Pareto model is used for identifying as metropolises one or a few large cities for each national urban system. From those data, two empirical power laws are established, linking the size of the metropolises to the size of their national urban system. The first is a transversal law: for a set of countries at a given date, the share of population concentrated in metropolises tends to decrease when larger countries are considered. The second law, which is longitudinal, shows that metropolises in the past have grown in a systematic way more rapidly than the rest of their urban system, invalidating Gibrat's urban growth model. Such empirical regularities could help for predicting the future of nowadays observed metropolisation trends.     

Linking the Abundance of Estuarine Fish and Crustaceans in Nearshore Waters to Shoreline Hardening and Land Cover

Human alteration of land cover (e.g., urban and agricultural land use) and shoreline hardening (e.g., bulkheading and rip rap revetment) are intensifying due to increasing human populations and sea level rise. Fishes and crustaceans that are ecologically and economically valuable to coastal systems may be affected by these changes, but direct links between these stressors and faunal populations have been elusive at large spatial scales. We examined nearshore abundance patterns of 15 common taxa across gradients of urban and agricultural land cover as well as wetland and hardened shoreline in tributary subestuaries of the Chesapeake Bay and Delaware Coastal Bays. We used a comprehensive landscape-scale study design that included 587 sites in 39 subestuaries. Our analyses indicate shoreline hardening has predominantly negative effects on estuarine fauna in water directly adjacent to the hardened shoreline and at the larger system-scale as cumulative hardened shoreline increased in the subestuary. In contrast, abundances of 12 of 15 species increased with the proportion of shoreline comprised of wetlands. Abundances of several species were also significantly related to watershed cropland cover, submerged aquatic vegetation, and total nitrogen, suggesting land-use-mediated effects on prey and refuge habitat. Specifically, abundances of four bottom-oriented species were negatively related to cropland cover, which is correlated with elevated nitrogen and reduced submerged and wetland vegetation in the receiving subestuary. These empirical relationships raise important considerations for conservation and management strategies in coastal environments.     

On the propagation characteristics of tunnel surface‐waves for seismic prediction

To increase the safety and efficiency of tunnel constructions, online seismic exploration ahead of a tunnel has become a valuable tool. One recent successful forward looking approach is based on the excitation and registration of tunnel surface‐waves. For further development and for finding optimal acquisition geometries it is important to study the propagation characteristics of tunnel surface‐waves. 3D seismic finite difference modelling and analytic solutions of the wave equation in cylindrical coordinates reveal that at higher frequencies, i.e., if the tunnel‐diameter is significantly larger than the wavelength of surface‐waves, these surface‐waves can be regarded as Rayleigh‐waves confined to the tunnel wall and following helical paths along the tunnel axis. For lower frequencies, i.e., when the tunnel surface‐wavelength approaches the tunnel‐diameter, the propagation characteristics of these surface‐waves are similar to S‐waves. We define the surface‐wave wavelength‐to‐tunnel diameter ratio w to be a gauge for separating Rayleigh‐ from S‐wave excitation. For w > 1.2 tunnel surface‐waves behave like S‐waves, i.e. their velocity approaches the S‐wave velocity and the particle motion is linear and perpendicular to the ray direction. For w < 0.6 they behave like Rayleigh‐waves, i.e., their velocity approaches the Rayleigh‐wave velocity and they exhibit elliptical particle motion. For 0.6 < w < 1.2 a mixture of both types is observed. Field data from the Gotthard Base Tunnel (Switzerland) show both types of tunnel surface‐waves and S‐waves propagating along the tunnel.     

Using hyperspectral imagery to predict post-wildfire soil water repellency

A principal task of evaluating large wildfires is to assess fire's effect on the soil in order to predict the potential watershed response. Two types of soil water repellency tests, the water drop penetration time (WDPT) test and the mini-disk infiltrometer (MDI) test, were performed after the Hayman Fire in Colorado, in the summer of 2002 to assess the infiltration potential of the soil. Remotely sensed hyperspectral imagery was also collected to map post-wildfire ground cover and soil condition. Detailed ground cover measurements were collected to validate the remotely sensed imagery and to examine the relationship between ground cover and soil water repellency. Percent ash cover measured on the ground was significantly correlated to WDPT (r = 0.42; p-value < 0.0001), and the MDI test (r = − 0.37; p-value < 0.0001). A Mixture Tuned Matched Filter (MTMF) spectral unmixing algorithm was applied to the hyperspectral imagery, which produced fractional cover maps of ash, soil, and scorched and green vegetation. The remotely sensed ash image had significant correlations to the water repellency tests, WDPT (r = 0.24; p-value = 0.001), and the MDI test (r = − 0.21; p-value = 0.005). An iterative threshold analysis was also applied to the ash and water repellency data to evaluate the relationship at increasingly higher levels of ash cover. Regression analysis between the means of grouped data: MDI time vs. ash cover data (R² =0.75) and vs. Ash MTMF scores (R² = 0.63) yielded significantly stronger relationships. From these results we found on-the-ground ash cover greater than 49% and remotely sensed ash cover greater than 33% to be indicative of strongly water repellent soils. Combining these results with geostatistical analyses indicated a spatial autocorrelation range of 15 to 40 m. Image pixels with high ash cover (> 33%), including pixels within 15 m of these pixel patches, were used to create a likelihood map of soil water repellency. This map is a good indicator of areas where soil experienced severe fire effects—areas that likely have strong water repellent soil conditions and higher potential for post-fire erosion.     

Hydrological changes during the Roman Climatic Optimum in northern Tuscany (Central Italy) as evidenced by speleothem records and archaeological data

Study of the climate in the Mediterranean basin during different historical periods has taken on a particular importance, particularly regarding its role (together with other factors) in the evolution of human settlement patterns. Although the Roman age is traditionally considered a period with a favourable climate, recent studies have revealed considerable complexity in terms of regional climate variations. In this paper, we compare the hydrological change from speleothem proxy records with flood reconstructions from archaeological sites for Northern Tuscany (central Italy). We identify a period of oscillating climatic conditions culminating in a multidecadal dry event during the 1st century bc , followed by a century of increased precipitation at the beginning of the Roman Empire and subsequently a return to drier conditions in the 2nd century ad. The period of rainfall increase documented by the speleothems agrees with both the archaeological flood record as well as historical flood data available for the Tiber River, ca. 300 km to the south. These data also suggest a return to wetter conditions following the 3nd and 4rd centuries ad.     

The integration of PESETA sectoral economic impacts into the GEM-E3 Europe model: methodology and results

The PESETA project has estimated the physical effects of climate change in Europe for the following impact categories with a market valuation: agriculture, river floods, coastal systems and tourism. Four alternative scenarios of future climate change have been considered. The computable general equilibrium (CGE) GEM-E3 model for Europe has been used to integrate the PESETA damages under a consistent economic framework. The approach followed has been to assess the effects of future climate (as of 2080s) on today’s economy. This article details the way each sectoral impact has been integrated into the CGE model. The EU welfare loss is estimated to be in a range of 0.2% to 1%, depending on the climate future and the projected sea level rise. Results show that the Southern Europe region appears as the most vulnerable area to climate change. Impacts in coastal systems, agriculture and river floods determine the overall and regional pattern of impacts within Europe.     

The flattening and the orbital structure of early-type galaxies and collisionless N-body binary disc mergers

We use oblate axisymmetric dynamical models including dark haloes to determine the orbital structure of intermediate mass to massive early-type galaxies in the Coma galaxy cluster. We find a large variety of orbital compositions. Averaged over all sample galaxies the unordered stellar kinetic energy in the azimuthal and the radial direction are of the same order, but they can differ by up to 40 per cent in individual systems. In contrast, both for rotating and non-rotating galaxies the vertical kinetic energy is on average smaller than in the other two directions. This implies that even most of the rotating ellipticals are flattened by an anisotropy in the stellar velocity dispersions. Using three-integral axisymmetric toy models, we show that flattening by stellar anisotropy maximizes the entropy for a given density distribution. Collisionless disc merger remnants are radially anisotropic. The apparent lack of strong radial anisotropy in observed early-type galaxies implies that they may not have formed from mergers of discs unless the influence of dissipational processes was significant.     

Provenance and pathways of late Quaternary turbidites in the deep-water Agadir Basin,northwest African margin

A series of individual turbidites, correlated over distances >100 km, are present in the recent fill of the Agadir Basin, offshore northwest Africa. The aim here is to unravel multiple turbidite source areas and flow pathways, and show how turbidite provenance studies contribute to interpretation of flow processes. Agadir Basin turbidites are sourced from four main areas, with the majority originating from the siliciclastic Morocco Shelf; their sand-mud distribution is strongly controlled by flow sediment volume, with relatively low-volume flows dying out within the Agadir Basin and large-volume flows bypassing significant sediment volumes to basins further downslope. Two large-volume volcaniclastic turbidites are attributed to a Canary Islands landslide source, while several small mud-dominated turbidites are interpreted to be locally sourced from hemipelagic-draped seamounts (e.g. Turbidite AB10). Finally, Turbidite AB1 (∼1 ka) is only present in the western Agadir Basin, and is linked to recent “re-activation” of the Sahara Slide headwall. The muddy suspension clouds of three large-volume flows, all linked to large-scale landslides, have covered huge areas of seafloor and flowed along or even slightly upslope for long distances. It is proposed that northeastwards-flowing bottom currents have aided transport of these dilute flow fractions into and across the Agadir Basin.